摘要
BaxCe0.8Y0.2O3-α(x=1.03,1,0.98) solid electrolyte samples show a single phase of orthorhombic perovskite of BaCeO3. The oxide ion conduction and transport number were detected in the temperature of 600～1000℃by electrochemical oxygen permeation (oxygen pumping), and compared with the results from the oxygen concentration cell. The relation between the ingredient of Ba and oxide ion conduction was also researched. It was found that these electrolytes exhibited the mixed oxide ionic and electronic hole conduction under the experimental temperature and oxygen gas. The oxide ion transport numbers are 0.1～0.6, which are close to the results of the oxygen concentration cell. They increase as the decrease of Ba content in the samples.
BaxCe0.8Y0.2O3-α(x=1.03,1,0.98) solid electrolyte samples show a single phase of orthorhombic perovskite of BaCeO3. The oxide ion conduction and transport number were detected in the temperature of 600～1000℃by electrochemical oxygen permeation (oxygen pumping), and compared with the results from the oxygen concentration cell. The relation between the ingredient of Ba and oxide ion conduction was also researched. It was found that these electrolytes exhibited the mixed oxide ionic and electronic hole conduction under the experimental temperature and oxygen gas. The oxide ion transport numbers are 0.1～0.6, which are close to the results of the oxygen concentration cell. They increase as the decrease of Ba content in the samples.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2003年第6期665-668,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20171034)
江苏省教育厅自然科学指导性课题资助(No.01KJD150003)。
