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The Selective Reduction of 4-Propylthio-2-nitroaniline with CO Using Ru_3(CO)_(12)/PEDPA Complex as Catalyst

The Selective Reduction of 4-Propylthio-2-nitroaniline with CO Using Ru_3(CO)_(12)/PEDPA Complex as Catalyst
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摘要 The Ru3(CO)12/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-mitroaniline. The effects of reaction temperature, the pressure of CO and concentration of catalyst on the reduction were investigated. Under the optimum conditions of T=140℃, Pco=5.0MPa and substrate/catalyst = 300 (molar ratio), the conversion and selectivity were 70% and 98%, respectively. After simple phase separation, the catalyst could be recycled. The Ru3(CO)12/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-mitroaniline. The effects of reaction temperature, the pressure of CO and concentration of catalyst on the reduction were investigated. Under the optimum conditions of T=140℃, Pco=5.0MPa and substrate/catalyst = 300 (molar ratio), the conversion and selectivity were 70% and 98%, respectively. After simple phase separation, the catalyst could be recycled.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第4期394-396,共3页 中国化学快报(英文版)
关键词 CO selective reduction 4-propylthio-2-nitroaniline Ru3(CO)_(12) phosphine. CO selective reduction, 4-propylthio-2-nitroaniline, Ru3(CO)_(12), phosphine.
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