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四苯骈卟啉金属配合物轴向配位反应的热力学性质研究 被引量:1

Study on properties of axial coordination reaction on tetrabenzoporphyrine metal complexes
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摘要 The determinations of rate constant ,activation energy and equilibrium constant of complexation reaction between CuTBP,CoTBP and imidazole ,pyridine ,2-methyprdine and 2,4-dimethypridine with spectrophotography were studied in this paper.The influences of basicity of ligand and space sterically hindered on the complexation reaction were discussed and the changes of ultraviolet-visible spectra of complexation reaction were given. The determinations of rate constant ,activation energy and equilibrium constant of complexation reaction between CuTBP,CoTBP and imidazole ,pyridine ,2-methyprdine and 2,4-dimethypridine with spectrophotography were studied in this paper.The influences of basicity of ligand and space sterically hindered on the complexation reaction were discussed and the changes of ultraviolet-visible spectra of complexation reaction were given.
出处 《化学研究与应用》 CAS CSCD 北大核心 2004年第2期259-260,共2页 Chemical Research and Application
关键词 四苯骈卟啉金属配合物 轴向配位反应 热力学性质 速率常数 平衡常数 活化能 金属卟啉 CuTBP CoTBP axial coordination ultraviolet-visible spectra physical and chemical properties
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