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由三核铁构筑成的新型的二维网状超分子化合物的合成、结构与性质(英文) 被引量：1

Synthesis,Structure and Magnetic Properties of a Novel 2-D Supramolecular Network Formed by the Fe3O Building Unit through Three Hydrogen Bonds
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摘要 A novel 2-D supramolecular network formed by the Fe3O building unit through three hydrogen bonds [Fe3O(O2CCH2OC6H5)6(3H2O)]NO3·2H2O (1) are presented. The title complex crystallizes in monoclinic, space group P21/n, with a=1.709 3(2) nm, b=3.152 9(3) nm, c=1.021 2(2) nm, V=5.503 5(14) nm3, Z=4, D(calc)=1.500 g·cm-3, F(000)=2 564. Each Fe3O unit is connected by three NO3-ions and inversely each NO3-ion is surrounded by three Fe3O moieties. It shows that the well-known Fe3O unit is a potential three H-donors and may be able to be a three-connected linker. This complex displays weak anti-ferromagnetic coupling between Fe(Ⅲ) centers. Electrochemical experiments were carried out to obtain the character of its redox reaction. CCDC: 222011. A novel 2-D supramolecular network formed by the Fe30 building unit through three hydrogen bonds [Fe30 (O2CCH2OC6H5)(6)(3H(2)O)]NO3 . 2H(2)O (1) are presented. The title complex crystallizes in monoclinic, space group P2(1)/n, with a=1.709 3(2) nm, b=3.152 9(3) nm, c=1.021 2(2) nm, V=5.503 5(14) nm(3), Z=4, D-(calc)=1.500 g.cm(-3), F (000)=2 564. Each Fe3O unit is connected by three NO3- ions and inversely each NO3- ion is surrounded by three Fe3O moieties. It shows that the well-known Fe3O unit is a potential three H-donors and may be able to be a three-connected linker. This complex displays weak anti-ferromagnetic coupling between Fe(III) centers. Electrochemical experiments were carried out to obtain the character of its redox reaction.
作者 杨玉华 李一志 韦吉崇 游效曾 王天维 白俊峰
机构地区 南京大学配位化学国家重点实验室
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2004年第6期683-687,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.20301010,G2000077500)
关键词 二维网状超分子 Fe3O 氢键 三核铁 超分子化合物 2-D supramolecular network Fe3O H-bonding
分类号 O614.811 [理学—无机化学]
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参考文献9

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同被引文献23

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无机化学学报
2004年 第6期

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