Based on the results from, studies of minerals belonging to these two systems ,and by reference to pertinent data available, the authors are of thc following opinious: The system RiS2-Os4S2-IrS2 is a complete isomorph...Based on the results from, studies of minerals belonging to these two systems ,and by reference to pertinent data available, the authors are of thc following opinious: The system RiS2-Os4S2-IrS2 is a complete isomorphous series. Unit cell parameters and physical properties of the mincrals vary with chemical compositions in a systematic manner. PdS-FtS is a limited isomorphous series. Two groups, cooperite [including(Pd0-0.113Pt1-0.387)1.00S1.00] platinum.bearing palladium sulfides [chemical formula(Pd0.86-0.39Pt0.14-0.61)1.00S1.00] can be distinguished within this system. Beeause of differences in crystal structures between the two groups, which is also responsible for the significant differences in physical properties of these minerals, the system PdS-PtS is discontinuous, but each group itself constitutes a complete isomorphous series.展开更多
文摘Based on the results from, studies of minerals belonging to these two systems ,and by reference to pertinent data available, the authors are of thc following opinious: The system RiS2-Os4S2-IrS2 is a complete isomorphous series. Unit cell parameters and physical properties of the mincrals vary with chemical compositions in a systematic manner. PdS-FtS is a limited isomorphous series. Two groups, cooperite [including(Pd0-0.113Pt1-0.387)1.00S1.00] platinum.bearing palladium sulfides [chemical formula(Pd0.86-0.39Pt0.14-0.61)1.00S1.00] can be distinguished within this system. Beeause of differences in crystal structures between the two groups, which is also responsible for the significant differences in physical properties of these minerals, the system PdS-PtS is discontinuous, but each group itself constitutes a complete isomorphous series.