The carbon dioxide corrosion behavior of low alloy pipeline steel was investigated by immersion experiment. Optical microscopy （OM）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, an...The carbon dioxide corrosion behavior of low alloy pipeline steel was investigated by immersion experiment. Optical microscopy （OM）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, and X-ray diffraction （XRD） were used to reflect the microstructure of the tested material and the corrosion morphology characterization. Results show that precipitate particles may accelerate the iron cabonate crystal formation process of the nucleation growth and promote the formation of compact layer. The major corrosion phases are FeCO3 and complexity compound containing Fe and Cr. The corrosion behavior consists of three stages. At the first stage, a thin inner layer and an inhomogeneous outer layer have appeared. At the second stage, the outer layer becomes homogeneous and compact, which prevents corroding the steel substrate further. At the third stage, iron carbonate crystal tends to nucleate and grow locally. The corrosion rate obtained by weight loss method increases abruptly first and then decreases quickly with increasing corrosion time. The mutual relation among microstructure, corrosion surface morphology, corrosion phases and corrosion kinetics is discussed.展开更多
For refining grain and obtaining excellent properties, the experiments of asymmetric and symmetric monotonic hot rolling were carried out to investigate the role of shear strain on the microstructures and mechanical p...For refining grain and obtaining excellent properties, the experiments of asymmetric and symmetric monotonic hot rolling were carried out to investigate the role of shear strain on the microstructures and mechanical properties of V-microalloyed steel. The study demonstrates that the gradient ferrite distribution and dispersive pearlite through the sheet thickness are observed in asymmetric rolled specimen, and the homogeneous microstructure with ferrite and large pearlite is found in symmetric rolled specimen. The average grain size in asymmetric rolled specimen is smaller than the one in symmetric rolled specimen. The styles of precipitate morphology in asymmetric rolled specimen are random precipitate and obvious interphase precipitate, while the ones in symmetric rolled specimen are random precipitate and unobvious interphase precipitate. The additional shear strain results in the microstructure difference between asymmetric rolled specimen and symmetric rolled specimen. The impact energy of asymmetric rolled specimen, 58 J, is more than the one of symmetric rolled specimen, 48 J. Both deflection-energy curve and fracture morphology show that the fracture style of asymmetric rolled specimen is ductile, and the ones of symmetric rolled specimen are brittle and ductile.展开更多
镀锌高强钢因具有高强度、耐腐蚀以及延展性优良等特点被应用于汽车构件领域,在实现减重的同时,提高汽车安全性能。电阻点焊作为材料连接的重要技术之一,因具有焊接过程简单、热影响区小、焊接变形与应力小及焊接速度快等优点,被广泛应...镀锌高强钢因具有高强度、耐腐蚀以及延展性优良等特点被应用于汽车构件领域,在实现减重的同时,提高汽车安全性能。电阻点焊作为材料连接的重要技术之一,因具有焊接过程简单、热影响区小、焊接变形与应力小及焊接速度快等优点,被广泛应用于连接镀锌高强汽车用钢。但在焊接过程中锌镀层会在电阻热的作用下熔化并渗入至焊点内部,从而在焊接接头形成液态金属脆化裂纹(Liquid metal embrittlement cracks, LME),液态金属脆化裂纹会使焊接接头在拉伸过程中发生脆性断裂,严重恶化焊接接头的力学性能。从液态金属脆化裂纹形成机理、表征手段和母材显微组织的影响等方面详细总结了国内外在此方面的研究,并归纳出改善镀锌高强钢焊接接头液态金属脆化裂纹的措施,为后续的研究工作提供一定的参考与借鉴。展开更多
基金Supported by National Key Technology Research and Development Program of the Ministry of Science and Technology of China during the“12th Five-Year Plan”(No.2011BAE25B03)National High Technology Research and Development Program of China(No.2015AA03A501)the National Natural Science Foundation of China(No.51274063)
文摘The carbon dioxide corrosion behavior of low alloy pipeline steel was investigated by immersion experiment. Optical microscopy （OM）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, and X-ray diffraction （XRD） were used to reflect the microstructure of the tested material and the corrosion morphology characterization. Results show that precipitate particles may accelerate the iron cabonate crystal formation process of the nucleation growth and promote the formation of compact layer. The major corrosion phases are FeCO3 and complexity compound containing Fe and Cr. The corrosion behavior consists of three stages. At the first stage, a thin inner layer and an inhomogeneous outer layer have appeared. At the second stage, the outer layer becomes homogeneous and compact, which prevents corroding the steel substrate further. At the third stage, iron carbonate crystal tends to nucleate and grow locally. The corrosion rate obtained by weight loss method increases abruptly first and then decreases quickly with increasing corrosion time. The mutual relation among microstructure, corrosion surface morphology, corrosion phases and corrosion kinetics is discussed.
基金Funded by the National Key Technology Research and Development Program of the Ministry of Science and Technology of China during the“12th Five-Year Plan”(No.2011BAE25B03)the National Natural Science Foundation of China(No.51274063)the National High Technology Research and Development Program of China(No.2015AA03A501)
文摘For refining grain and obtaining excellent properties, the experiments of asymmetric and symmetric monotonic hot rolling were carried out to investigate the role of shear strain on the microstructures and mechanical properties of V-microalloyed steel. The study demonstrates that the gradient ferrite distribution and dispersive pearlite through the sheet thickness are observed in asymmetric rolled specimen, and the homogeneous microstructure with ferrite and large pearlite is found in symmetric rolled specimen. The average grain size in asymmetric rolled specimen is smaller than the one in symmetric rolled specimen. The styles of precipitate morphology in asymmetric rolled specimen are random precipitate and obvious interphase precipitate, while the ones in symmetric rolled specimen are random precipitate and unobvious interphase precipitate. The additional shear strain results in the microstructure difference between asymmetric rolled specimen and symmetric rolled specimen. The impact energy of asymmetric rolled specimen, 58 J, is more than the one of symmetric rolled specimen, 48 J. Both deflection-energy curve and fracture morphology show that the fracture style of asymmetric rolled specimen is ductile, and the ones of symmetric rolled specimen are brittle and ductile.
文摘镀锌高强钢因具有高强度、耐腐蚀以及延展性优良等特点被应用于汽车构件领域,在实现减重的同时,提高汽车安全性能。电阻点焊作为材料连接的重要技术之一,因具有焊接过程简单、热影响区小、焊接变形与应力小及焊接速度快等优点,被广泛应用于连接镀锌高强汽车用钢。但在焊接过程中锌镀层会在电阻热的作用下熔化并渗入至焊点内部,从而在焊接接头形成液态金属脆化裂纹(Liquid metal embrittlement cracks, LME),液态金属脆化裂纹会使焊接接头在拉伸过程中发生脆性断裂,严重恶化焊接接头的力学性能。从液态金属脆化裂纹形成机理、表征手段和母材显微组织的影响等方面详细总结了国内外在此方面的研究,并归纳出改善镀锌高强钢焊接接头液态金属脆化裂纹的措施,为后续的研究工作提供一定的参考与借鉴。
