The unique cellular microstructure of Fe-rich Sm_(2)Co_(17)-type permanent magnets is closely associated with the structure of the solid solution precursor.We investigate the phase structure,magnetic properties,and me...The unique cellular microstructure of Fe-rich Sm_(2)Co_(17)-type permanent magnets is closely associated with the structure of the solid solution precursor.We investigate the phase structure,magnetic properties,and mechanical behavior of B-doped Sm_(2)Co_(17)-type magnets with high Fe content.The doped B atoms can diffuse into the interstitial vacancy,resulting in lattice expansion and promote the homogenization of the phase organizational structure during the solid solution treatment in theory.However,the resulting second phase plays a dominant role to result in more microtwin structures and highly ordered 2:17R phases in the solid solution stage,which inhibits the ordering transformation of 1:7H phase during aging and affects the generation of the cellular structure,and to result in a decrease in magnetic properties,yet the interface formed between it and the matrix phase hinders the movement of dislocations and enhances the mechanical properties.Hence,the precipitation of high flexural strain grain boundary phase induced by B element doping is also a new and effective way to improve the flexural strain of Sm_(2)Co_(17)-type magnets.Our study provides a new understanding of the phase structure evolution and its effect on the magnetic and mechanical properties of Sm_(2)Co_(17)-type magnets with high Fe content.展开更多
为解决乌鄯线哈萨克斯坦原油外输量增加问题,开展了乌鄯线减阻增输试验。文中介绍了乌鲁木齐首站加剂流程和现场加剂试验方案,对乌鄯线减阻增输试验进行分析研究,降低沿程摩阻,提高管输效率。根据试验结果可知:最优加剂量为10 ppm,在此...为解决乌鄯线哈萨克斯坦原油外输量增加问题,开展了乌鄯线减阻增输试验。文中介绍了乌鲁木齐首站加剂流程和现场加剂试验方案,对乌鄯线减阻增输试验进行分析研究,降低沿程摩阻,提高管输效率。根据试验结果可知:最优加剂量为10 ppm,在此加剂量下,乌鄯线2台主泵运行情况下加剂增输率为9.52%,3台主泵运行工况下加剂增输率达到28%,最大输量达到1600 m 3/h,为乌鄯线增输提供了试验数据和依据,解决了乌鄯线哈萨克斯坦原油外输问题。展开更多
The structure and the migration mechanisms of {10 12} twin boundaries（TBs） of pure zinc deformed by rolling were studied using high-resolution transmission electron microscopy（HRTEM） at atomic scale. We found the ...The structure and the migration mechanisms of {10 12} twin boundaries（TBs） of pure zinc deformed by rolling were studied using high-resolution transmission electron microscopy（HRTEM） at atomic scale. We found the presence of basal/prismatic（BP/PB） planes serrations on {10 12} TBs and the coexistence of two kinds of TBs with different structures in the same {10 12} twin： TBs composed of {10 12} coherent twin boundaries（CTBs） plus short BP/PB serrations, and TBs composed of successive BP/PB segments without {10 12} CTBs. The formation of BP/PB serrations has no relation to the c/a ratio of hexagonal-closepacked（HCP） metals because the BP/PB serrations are energetically preferred and geometrically favored. Based on dislocation theory, we proposed the migration mechanisms of the TBs to be the glide of twinning dislocations（TDs） on the CTBs and the climb of interface dislocations（IDs） on the BP/PB segments.展开更多
In order to counteract the demagnetization caused by eddy current loss,widespread attention has been devoted to increasing the resistivity of permanent magnets.We prepared 2:17-type Sm Co magnets doped with different ...In order to counteract the demagnetization caused by eddy current loss,widespread attention has been devoted to increasing the resistivity of permanent magnets.We prepared 2:17-type Sm Co magnets doped with different ZrO_(2)contents and investigated the influence of the ZrO_(2)content on the magnetic properties and resistive anisotropism.The results showed that not only was the resistivity of the magnet improved,but,in addition,the coercivity of the magnet was significantly increased.The microstructure was studied with TEM,which showed that ZrO_(2)doping was able to cause a decrease in the lamellar phase density and the growth of cellular structures.The increased grain boundaries and Sm_(2)O_(3)phases were favorable to the improvement of resistivity.The decrease of the lamellar phases caused a narrowing of the resistive anisotropism.The additional Cu in the center of the cellular boundaries was the main reason for the enhancement of Hcj.However,an excessive amount caused an increase of the Zr_6(Fe Co)_(23)phase and a deterioration of the cellular structure,thereby leading to a decrease in coercivity.展开更多
基金the NationalKey R&D Program of China (Grant Nos. 2021YFB3503102and 2022YFB3505301)Science and Technology Innovation2025 Major Project of Ningbo (Grant No. 2022Z204)+2 种基金ZhejiangProvincial Natural Science Foundation Youth OriginalProject (Grant No. LDQ24E010001)the Key R&D Programof Shanxi Province (Grant No. 202302050201014)Ningbo Natural Science Foundation (Grant No. 2021J216).
文摘The unique cellular microstructure of Fe-rich Sm_(2)Co_(17)-type permanent magnets is closely associated with the structure of the solid solution precursor.We investigate the phase structure,magnetic properties,and mechanical behavior of B-doped Sm_(2)Co_(17)-type magnets with high Fe content.The doped B atoms can diffuse into the interstitial vacancy,resulting in lattice expansion and promote the homogenization of the phase organizational structure during the solid solution treatment in theory.However,the resulting second phase plays a dominant role to result in more microtwin structures and highly ordered 2:17R phases in the solid solution stage,which inhibits the ordering transformation of 1:7H phase during aging and affects the generation of the cellular structure,and to result in a decrease in magnetic properties,yet the interface formed between it and the matrix phase hinders the movement of dislocations and enhances the mechanical properties.Hence,the precipitation of high flexural strain grain boundary phase induced by B element doping is also a new and effective way to improve the flexural strain of Sm_(2)Co_(17)-type magnets.Our study provides a new understanding of the phase structure evolution and its effect on the magnetic and mechanical properties of Sm_(2)Co_(17)-type magnets with high Fe content.
文摘为解决乌鄯线哈萨克斯坦原油外输量增加问题,开展了乌鄯线减阻增输试验。文中介绍了乌鲁木齐首站加剂流程和现场加剂试验方案,对乌鄯线减阻增输试验进行分析研究,降低沿程摩阻,提高管输效率。根据试验结果可知:最优加剂量为10 ppm,在此加剂量下,乌鄯线2台主泵运行情况下加剂增输率为9.52%,3台主泵运行工况下加剂增输率达到28%,最大输量达到1600 m 3/h,为乌鄯线增输提供了试验数据和依据,解决了乌鄯线哈萨克斯坦原油外输问题。
文摘The structure and the migration mechanisms of {10 12} twin boundaries（TBs） of pure zinc deformed by rolling were studied using high-resolution transmission electron microscopy（HRTEM） at atomic scale. We found the presence of basal/prismatic（BP/PB） planes serrations on {10 12} TBs and the coexistence of two kinds of TBs with different structures in the same {10 12} twin： TBs composed of {10 12} coherent twin boundaries（CTBs） plus short BP/PB serrations, and TBs composed of successive BP/PB segments without {10 12} CTBs. The formation of BP/PB serrations has no relation to the c/a ratio of hexagonal-closepacked（HCP） metals because the BP/PB serrations are energetically preferred and geometrically favored. Based on dislocation theory, we proposed the migration mechanisms of the TBs to be the glide of twinning dislocations（TDs） on the CTBs and the climb of interface dislocations（IDs） on the BP/PB segments.
基金the National Natural Science Foundation of China(Grant No.51877094)Ningbo Science and Technology Project(Grant No.2014B11009)。
文摘In order to counteract the demagnetization caused by eddy current loss,widespread attention has been devoted to increasing the resistivity of permanent magnets.We prepared 2:17-type Sm Co magnets doped with different ZrO_(2)contents and investigated the influence of the ZrO_(2)content on the magnetic properties and resistive anisotropism.The results showed that not only was the resistivity of the magnet improved,but,in addition,the coercivity of the magnet was significantly increased.The microstructure was studied with TEM,which showed that ZrO_(2)doping was able to cause a decrease in the lamellar phase density and the growth of cellular structures.The increased grain boundaries and Sm_(2)O_(3)phases were favorable to the improvement of resistivity.The decrease of the lamellar phases caused a narrowing of the resistive anisotropism.The additional Cu in the center of the cellular boundaries was the main reason for the enhancement of Hcj.However,an excessive amount caused an increase of the Zr_6(Fe Co)_(23)phase and a deterioration of the cellular structure,thereby leading to a decrease in coercivity.
