Since the discovery of surface-enhanced Raman spectroscopy(SERS),it has been rapidly applied to the in situ study of electrochemical interfaces.Shell-isolated nanoparticle-enhanced Raman spectroscopy(SHINERS)stands ou...Since the discovery of surface-enhanced Raman spectroscopy(SERS),it has been rapidly applied to the in situ study of electrochemical interfaces.Shell-isolated nanoparticle-enhanced Raman spectroscopy(SHINERS)stands out as one of the most powerful tools for the in situ study of interfacial structures,especially on well-defined single crystal surface.This perspective paper focuses on the study of interfacial structures with the SHINERS technique,including the electronic structure of heterogeneous metal surfaces,and the detection of molecules absorbed on the surface,as well as intermediate species,during electrochemical reactions.Finally,we present an outlook on future research and development of SHINERS for studying interfacial structures.展开更多
基金supported by the National Natural Science Foundation of China(21925404,21775127)Science and Technology Planning Project of Fujian Province(2019Y4001)。
文摘Since the discovery of surface-enhanced Raman spectroscopy(SERS),it has been rapidly applied to the in situ study of electrochemical interfaces.Shell-isolated nanoparticle-enhanced Raman spectroscopy(SHINERS)stands out as one of the most powerful tools for the in situ study of interfacial structures,especially on well-defined single crystal surface.This perspective paper focuses on the study of interfacial structures with the SHINERS technique,including the electronic structure of heterogeneous metal surfaces,and the detection of molecules absorbed on the surface,as well as intermediate species,during electrochemical reactions.Finally,we present an outlook on future research and development of SHINERS for studying interfacial structures.
基金financially supported by the National Natural Science Foundation of China(21525626)the Program of Introducing Talents of Discipline to Universities(B06006)+1 种基金the Program for Professor of Special Appointment(Eastern Scholar) at Shanghai Institutions of Higher Learningthe Startup Fund from Fudan University
