This paper investigates the single-molecule magnets of pure and Cr/Fe-doped Mn12-Ac. The components of the mixed crystals are identified by AC susceptibility technique. The ground-state spin and anisotropy parameters ...This paper investigates the single-molecule magnets of pure and Cr/Fe-doped Mn12-Ac. The components of the mixed crystals are identified by AC susceptibility technique. The ground-state spin and anisotropy parameters of doped Mn12-Ac are obtained： （i） MnllCr-Ac （S=19/2, D=0.62K, B=0.0009K, A=63K）, and （ii） Mn11Fe-Ac （S=21/2, D=0.39 K, B=0.001 K, △=55 K）. The single-ion origin of the magnetic anisotropy is discussed.展开更多
Magnetic structure of Pr6Fe13Ge at room temperature has been investigated by magnetic measurement, Mossbauer effect and neutron diffraction. Magnetic atoms are closely packed up and down the mirror planes at z = 0 and...Magnetic structure of Pr6Fe13Ge at room temperature has been investigated by magnetic measurement, Mossbauer effect and neutron diffraction. Magnetic atoms are closely packed up and down the mirror planes at z = 0 and 1/2 and separated by the non-magnetic atoms located on the planes at z= 1/4 and 3/4, which constructs an M/NM/M sandwich structure (M: magnetic, NM: non-magnetic). The intralayer magnetic moments couple ferromagnetically and are out of ab plane at a small angle so as to form a component along c-axis. The interlayer coupling is antiferromagnetic for the ab component while ferromagnetic for the c component.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant Nos 10505029 and 10375088)
文摘This paper investigates the single-molecule magnets of pure and Cr/Fe-doped Mn12-Ac. The components of the mixed crystals are identified by AC susceptibility technique. The ground-state spin and anisotropy parameters of doped Mn12-Ac are obtained： （i） MnllCr-Ac （S=19/2, D=0.62K, B=0.0009K, A=63K）, and （ii） Mn11Fe-Ac （S=21/2, D=0.39 K, B=0.001 K, △=55 K）. The single-ion origin of the magnetic anisotropy is discussed.
文摘Magnetic structure of Pr6Fe13Ge at room temperature has been investigated by magnetic measurement, Mossbauer effect and neutron diffraction. Magnetic atoms are closely packed up and down the mirror planes at z = 0 and 1/2 and separated by the non-magnetic atoms located on the planes at z= 1/4 and 3/4, which constructs an M/NM/M sandwich structure (M: magnetic, NM: non-magnetic). The intralayer magnetic moments couple ferromagnetically and are out of ab plane at a small angle so as to form a component along c-axis. The interlayer coupling is antiferromagnetic for the ab component while ferromagnetic for the c component.
