A new electrodeposition system, with a thin nickel wire as the anode, was used to deposit the CN x thin film on Si(100) substrate from a dicyandiamide-saturated solution in acetonitrile at a high potential. During the...A new electrodeposition system, with a thin nickel wire as the anode, was used to deposit the CN x thin film on Si(100) substrate from a dicyandiamide-saturated solution in acetonitrile at a high potential. During the experiment, when a certain high potential was applied, spark occurred between the Ni wire anode and the Si(100) substrate. The films were characterized by X-ray photoelectron spectroscopy(XPS), Fourier-transform infrared spectroscopy(FTIR), scaning electron microscopy(SEM) and X-ray diffraction(XRD). It was indicated that multiphase of α-C 3N 4, β-C 3N 4 and g-C 3N 4 was obtained in the films. This work is the first attempt to deposit carbon nitride material through a thin nickel wire anode and might provide a new route for preparing pure crystalline C 3N 4.展开更多
以无水CH3CN·BCl3和Li3N为原料,以苯为溶剂,在温度为330℃,压力为8～9MPa条件下,利用溶剂热合成方法成功地制备出了BCN三元化合物。X射线粉末衍射(XRD)分析表明,产物为类石墨态结构,透射电子显微镜(TEM)观测到产物中含有B C N纳米...以无水CH3CN·BCl3和Li3N为原料,以苯为溶剂,在温度为330℃,压力为8～9MPa条件下,利用溶剂热合成方法成功地制备出了BCN三元化合物。X射线粉末衍射(XRD)分析表明,产物为类石墨态结构,透射电子显微镜(TEM)观测到产物中含有B C N纳米管。X射线能谱(XPS)和Fourier变换红外光谱(FTIR)分析表明硼碳氮是以原子级化合的形式存在。展开更多
文摘A new electrodeposition system, with a thin nickel wire as the anode, was used to deposit the CN x thin film on Si(100) substrate from a dicyandiamide-saturated solution in acetonitrile at a high potential. During the experiment, when a certain high potential was applied, spark occurred between the Ni wire anode and the Si(100) substrate. The films were characterized by X-ray photoelectron spectroscopy(XPS), Fourier-transform infrared spectroscopy(FTIR), scaning electron microscopy(SEM) and X-ray diffraction(XRD). It was indicated that multiphase of α-C 3N 4, β-C 3N 4 and g-C 3N 4 was obtained in the films. This work is the first attempt to deposit carbon nitride material through a thin nickel wire anode and might provide a new route for preparing pure crystalline C 3N 4.
文摘以无水CH3CN·BCl3和Li3N为原料,以苯为溶剂,在温度为330℃,压力为8～9MPa条件下,利用溶剂热合成方法成功地制备出了BCN三元化合物。X射线粉末衍射(XRD)分析表明,产物为类石墨态结构,透射电子显微镜(TEM)观测到产物中含有B C N纳米管。X射线能谱(XPS)和Fourier变换红外光谱(FTIR)分析表明硼碳氮是以原子级化合的形式存在。
