为了测试充放电过程中锂离子电池膨胀力及膨胀位移,拟开发相应的测试试验台。该实验台由充放电系统、环境控制系统、测试系统、数据采集系统等四部分组成。为了模拟电池对测试装置响应,提出了一种表征充放电过程中锂电池热-机-电耦合作...为了测试充放电过程中锂离子电池膨胀力及膨胀位移,拟开发相应的测试试验台。该实验台由充放电系统、环境控制系统、测试系统、数据采集系统等四部分组成。为了模拟电池对测试装置响应,提出了一种表征充放电过程中锂电池热-机-电耦合作用的等效方法。基于开发的试验台,测试不同放电倍率下电池膨胀位移-荷电状态(state of charge,SOC)曲线及电池膨胀力-荷电状态曲线,使基于温度-电流电压-力的电池管理系统的开发成为可能。展开更多
Graphite‐like carbon nitride(g‐C3N4)‐based compounds have attracted considerable attention because of their excellent photocatalytic performance.In this work,a novel direct Z‐scheme system constructed from two‐di...Graphite‐like carbon nitride(g‐C3N4)‐based compounds have attracted considerable attention because of their excellent photocatalytic performance.In this work,a novel direct Z‐scheme system constructed from two‐dimensional(2D)g‐C3N4nanoplates and zero‐dimensional(0D)MoS2quantum dots(QDs)was prepared through the combination of a hydrothermal process and microemulsion preparation.The morphologies,structures,and optical properties of the as‐prepared photocatalysts were characterized by X‐ray diffraction,X‐ray photoelectron spectroscopy,atomic force microscopy,transmission electron microscopy,and UV‐vis diffuse reflectance spectroscopy.In addition,the photocatalytic performances of the prepared2D/0D hybrid composites were evaluated based on the photodegradation of rhodamine B under visible‐light irradiation.The results demonstrated that the introduction of MoS2QDs to g‐C3N4greatly enhanced the photocatalytic efficiency.For the optimum7%MoS2QD/g‐C3N4photocatalyst,the degradation rate constant was8.8times greater than that of pure g‐C3N4under visible‐light irradiation.Photocurrent and electrochemical impedance spectroscopy results further demonstrated that the MoS2QD/g‐C3N4composites exhibited higher photocurrent density and lower chargetransfer resistance than those of the pure g‐C3N4or MoS2QDs.Active species trapping,terephthalic acid photoluminescence,and nitro blue tetrazolium transformation experiments were performed to investigate the evolution of reactive oxygen species,including hydroxyl radicals and superoxide radicals.The possible enhanced photocatalytic mechanism was attributed to a direct Z‐scheme system,which not only can increase the separation efficiency of photogenerated electron‐hole pairs but also possesses excellent oxidation and reduction ability for high photocatalytic performances.This work provides an effective synthesis approach and insight to help develop other C3N4‐based direct Z‐scheme photocatalytic systems for environmental purification and energy conversion.展开更多
文摘为了测试充放电过程中锂离子电池膨胀力及膨胀位移,拟开发相应的测试试验台。该实验台由充放电系统、环境控制系统、测试系统、数据采集系统等四部分组成。为了模拟电池对测试装置响应,提出了一种表征充放电过程中锂电池热-机-电耦合作用的等效方法。基于开发的试验台,测试不同放电倍率下电池膨胀位移-荷电状态(state of charge,SOC)曲线及电池膨胀力-荷电状态曲线,使基于温度-电流电压-力的电池管理系统的开发成为可能。
基金supported by National Natural Science Foundation of China(51672113)Six Talent Peaks Project in Jiangsu Province(2015-XCL-026)+3 种基金Natural Science Foundation of Jiangsu Province(BK20171299)State Key Laboratory of Photocatalysis on Energy and Environment(SKLPEE-KF201705),Fuzhou UniversityState Key Laboratory of Advanced Technology for Materials Synthesis and Processing(2016-KF-10),Wuhan University of Technologythe Qing Lan Project Foundation of Jiangsu Province~~
文摘Graphite‐like carbon nitride(g‐C3N4)‐based compounds have attracted considerable attention because of their excellent photocatalytic performance.In this work,a novel direct Z‐scheme system constructed from two‐dimensional(2D)g‐C3N4nanoplates and zero‐dimensional(0D)MoS2quantum dots(QDs)was prepared through the combination of a hydrothermal process and microemulsion preparation.The morphologies,structures,and optical properties of the as‐prepared photocatalysts were characterized by X‐ray diffraction,X‐ray photoelectron spectroscopy,atomic force microscopy,transmission electron microscopy,and UV‐vis diffuse reflectance spectroscopy.In addition,the photocatalytic performances of the prepared2D/0D hybrid composites were evaluated based on the photodegradation of rhodamine B under visible‐light irradiation.The results demonstrated that the introduction of MoS2QDs to g‐C3N4greatly enhanced the photocatalytic efficiency.For the optimum7%MoS2QD/g‐C3N4photocatalyst,the degradation rate constant was8.8times greater than that of pure g‐C3N4under visible‐light irradiation.Photocurrent and electrochemical impedance spectroscopy results further demonstrated that the MoS2QD/g‐C3N4composites exhibited higher photocurrent density and lower chargetransfer resistance than those of the pure g‐C3N4or MoS2QDs.Active species trapping,terephthalic acid photoluminescence,and nitro blue tetrazolium transformation experiments were performed to investigate the evolution of reactive oxygen species,including hydroxyl radicals and superoxide radicals.The possible enhanced photocatalytic mechanism was attributed to a direct Z‐scheme system,which not only can increase the separation efficiency of photogenerated electron‐hole pairs but also possesses excellent oxidation and reduction ability for high photocatalytic performances.This work provides an effective synthesis approach and insight to help develop other C3N4‐based direct Z‐scheme photocatalytic systems for environmental purification and energy conversion.
