The surface flashover of epoxy resin(EP) composites is a pivotal problem in the field of highvoltage insulation.The regulation of the interface between the filler and matrix is an effective means to suppress flashover...The surface flashover of epoxy resin(EP) composites is a pivotal problem in the field of highvoltage insulation.The regulation of the interface between the filler and matrix is an effective means to suppress flashover.In this work,nano ZnO was fluorinated and grafted using lowtemperature plasma technology,and the fluorinated filler was doped into EP to study the DC surface flashover performance of the composite.The results show that plasma fluorination can effectively inhibit the agglomeration by grafting –CFxgroups onto the surface of nano-ZnO particles.The fluorine-containing groups at the interface provide higher charge binding traps and enhance the insulation strength at the interface.At the same time,the interface bond cooperation caused by plasma treatment also promoted the accelerating effect of nano ZnO on charge dissipation.The two effects synergistically improve the surface flashover performance of epoxy composites.When the concentration of fluorinated ZnO filler is 20%,the flashover voltage has the highest increase,which is 31.52% higher than that of pure EP.In addition,fluorinated ZnO can effectively reduce the dielectric constant and dielectric loss of epoxy composites.The interface interaction mechanism was further analyzed using molecular dynamics simulation and density functional theory simulation.展开更多
This work treats the Al_(2)O_(3)-ER sample surface using dielectric barrier discharge fluorination(DBDF),DBD silicon deposition(DBD-Si),atmospheric-pressure plasma jet fluorination(APPJ-F)and APPJ silicon deposition(A...This work treats the Al_(2)O_(3)-ER sample surface using dielectric barrier discharge fluorination(DBDF),DBD silicon deposition(DBD-Si),atmospheric-pressure plasma jet fluorination(APPJ-F)and APPJ silicon deposition(APPJ-Si).By comparing the surface morphology,chemical components and electrical parameters,the diverse mechanisms of different plasma modification methods used to improve flashover performance are revealed.The results show that the flashover voltage of the DBDF samples is the largest(increased by 21.2%at most),while the APPJ-F method has the worst promotion effect.The flashover voltage of the APPJ-Si samples decreases sharply when treatment time exceeds 180 s,but the promotion effect outperforms the DBD-Si method during a short modified time.For the mechanism explanation,firstly,plasma fluorination improves the surface roughness and introduces shallow traps by etching the surface and grafting fluorine-containing groups,while plasma silicon deposition reduces the surface roughness and introduces a large number of shallow traps by coating Si Oxfilm.Furthermore,the reaction of the DBD method is more violent,while the homogeneity of the APPJ modification is better.These characteristics influence the effects of fluorination and silicon deposition.Finally,increasing the surface roughness and introducing shallow traps accelerates surface charge dissipation and inhibits flashover,but too many shallow traps greatly increase the dissipated rate and facilitate surface flashover instead.展开更多
基金supported by Beijing Natural Science Foundation (No. 3222057)National Natural Science Foundation of China (Nos. 52277147 and 52007065)。
文摘The surface flashover of epoxy resin(EP) composites is a pivotal problem in the field of highvoltage insulation.The regulation of the interface between the filler and matrix is an effective means to suppress flashover.In this work,nano ZnO was fluorinated and grafted using lowtemperature plasma technology,and the fluorinated filler was doped into EP to study the DC surface flashover performance of the composite.The results show that plasma fluorination can effectively inhibit the agglomeration by grafting –CFxgroups onto the surface of nano-ZnO particles.The fluorine-containing groups at the interface provide higher charge binding traps and enhance the insulation strength at the interface.At the same time,the interface bond cooperation caused by plasma treatment also promoted the accelerating effect of nano ZnO on charge dissipation.The two effects synergistically improve the surface flashover performance of epoxy composites.When the concentration of fluorinated ZnO filler is 20%,the flashover voltage has the highest increase,which is 31.52% higher than that of pure EP.In addition,fluorinated ZnO can effectively reduce the dielectric constant and dielectric loss of epoxy composites.The interface interaction mechanism was further analyzed using molecular dynamics simulation and density functional theory simulation.
基金supported by National Natural Science Foundation of China (No. 51777076)the Self-topic Fund of the State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources (No. LAPS2019-21)
文摘This work treats the Al_(2)O_(3)-ER sample surface using dielectric barrier discharge fluorination(DBDF),DBD silicon deposition(DBD-Si),atmospheric-pressure plasma jet fluorination(APPJ-F)and APPJ silicon deposition(APPJ-Si).By comparing the surface morphology,chemical components and electrical parameters,the diverse mechanisms of different plasma modification methods used to improve flashover performance are revealed.The results show that the flashover voltage of the DBDF samples is the largest(increased by 21.2%at most),while the APPJ-F method has the worst promotion effect.The flashover voltage of the APPJ-Si samples decreases sharply when treatment time exceeds 180 s,but the promotion effect outperforms the DBD-Si method during a short modified time.For the mechanism explanation,firstly,plasma fluorination improves the surface roughness and introduces shallow traps by etching the surface and grafting fluorine-containing groups,while plasma silicon deposition reduces the surface roughness and introduces a large number of shallow traps by coating Si Oxfilm.Furthermore,the reaction of the DBD method is more violent,while the homogeneity of the APPJ modification is better.These characteristics influence the effects of fluorination and silicon deposition.Finally,increasing the surface roughness and introducing shallow traps accelerates surface charge dissipation and inhibits flashover,but too many shallow traps greatly increase the dissipated rate and facilitate surface flashover instead.
