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铜包裹碳化硅颗粒复合粉体的化学原位沉积制备与表征 被引量:3
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作者 石锦罡 姚辉 +2 位作者 陈名海 刘宁 李清文 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2012年第8期795-799,共5页
以铜氨离子为铜源,水合肼为还原剂,在表面预氧化的SiC表面,采用一步原位化学沉积法制备了均匀包裹Cu颗粒的SiC复合粉体.采用扫描电子显微镜(SEM)、X射线衍射(XRD)、傅立叶红外光谱(FT-IR)、Zeta电位等测试表征手段研究了工艺条件对原位... 以铜氨离子为铜源,水合肼为还原剂,在表面预氧化的SiC表面,采用一步原位化学沉积法制备了均匀包裹Cu颗粒的SiC复合粉体.采用扫描电子显微镜(SEM)、X射线衍射(XRD)、傅立叶红外光谱(FT-IR)、Zeta电位等测试表征手段研究了工艺条件对原位沉积反应的影响.研究发现SiC表面预氧化形成的SiO2层能显著增强对铜氨离子吸附能力,有助于原位还原生成单质Cu,形成近乎连续包裹层.控制反应体系中铜氨离子浓度和反应温度可以影响反应速率,从而控制Cu颗粒的沉积速率和包裹效果.对比研究表明,在0.2 mol/L铜氨离子溶液中70℃反应,在预氧化的SiC表面能够获得最佳包裹层. 展开更多
关键词 SIC Cu 金属陶瓷复合材料 原位化学沉积
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真空搅拌铸造制备SiC颗粒增强ADC12铝基复合材料及其力学性能表征 被引量:16
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作者 吴星平 石锦罡 +3 位作者 吴昊 陈名海 刘宁 李清文 《材料工程》 EI CAS CSCD 北大核心 2014年第1期6-11,共6页
以SiC/Cu复合包裹粉体为增强相,采用真空搅拌铸造技术制备SiC/ADC12铝基复合材料,研究制备工艺条件对复合材料力学性能的影响,同时借助X射线衍射(XRD)和扫描电子显微镜(SEM)等测试分析手段对其物相结构进行表征。结果表明:SiC/Cu复合粉... 以SiC/Cu复合包裹粉体为增强相,采用真空搅拌铸造技术制备SiC/ADC12铝基复合材料,研究制备工艺条件对复合材料力学性能的影响,同时借助X射线衍射(XRD)和扫描电子显微镜(SEM)等测试分析手段对其物相结构进行表征。结果表明:SiC/Cu复合粉体显著改善了SiC颗粒在熔融铝合金基体中的润湿性和分散性。当搅拌温度为580℃,搅拌时间为30min,复合粉体添加量为4%(质量分数)时,复合材料获得最佳的力学性能,拉伸强度283MPa,硬度HB133,较基体合金分别提高24.1%和77.3%,较普通SiC增强复合材料提高15.5%和26.7%。 展开更多
关键词 SIC Cu复合包裹粉体 真空搅拌铸造 力学性能
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Effect of VC/Cr_3C_2 on microstructure and mechanical properties of Ti(C,N)-based cermets 被引量:6
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作者 詹斌 刘宁 +2 位作者 金之铂 李其龙 石锦罡 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第5期1096-1105,共10页
Effects of VC/Cr3C2 on the microstructure and mechanical properties of Ti(C,N)-based cermets were studied. The microstructure was investigated by means of optical microscopy, X-ray diffractometry as well as scanning... Effects of VC/Cr3C2 on the microstructure and mechanical properties of Ti(C,N)-based cermets were studied. The microstructure was investigated by means of optical microscopy, X-ray diffractometry as well as scanning electron microscopy in combination with energy dispersive spectrometry. Mechanical properties, such as transverse rupture strength, hardness and fracture toughness, were measured. The results show that there are black core-grey rim structure and white core-grey rim structure in the microstructure. The grains become fine due to the VC/Cr3C2, and the grains of cermet added with 0.75VC/0.25Cr3C2 are refined most remarkably. The black core becomes finer with the increase of VC addition and rim phase becomes thicker with the decrease of Cr3C2 addition. The porosity increases with the increase of VC addition in VC/Cr3C2. Compared with the cermet free of VC/Cr3C2, the transverse rupture strength and hardness of cermets with VC/Cr3C2 are both improved, and the maximum values are both found for the cermet with 0.25VC/0.75Cr3C2. The fracture toughness can be effectively promoted by adding VC/Cr3C2 with an appropriate ratio of VC to Cr3C2, and the maximum value is found for the cermet with 0.5VC/0.5Cr3C2. 展开更多
关键词 Ti(C N)-based cermet VC CR3C2 microstructure mechanical properties
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