A new coordination polymer, {[Cd(OPY)_2(tdc)(H_2O)]·H2 O}n(OPY = 4,4?-(oxybis(4,1-phenylene))dipyridine, H2 tdc = thiophene-2,5-dicarboxylic acid), has been synthesized hydrothermally based on a V-shaped ligand O...A new coordination polymer, {[Cd(OPY)_2(tdc)(H_2O)]·H2 O}n(OPY = 4,4?-(oxybis(4,1-phenylene))dipyridine, H2 tdc = thiophene-2,5-dicarboxylic acid), has been synthesized hydrothermally based on a V-shaped ligand OPY. The structure was fully characterized by elemental analysis, FT-IR spectroscopy, and X-ray single-crystal diffraction analysis. In1, two OPY ligands and one water molecule acted as terminal ligands coordinating to Cd^(2+) cation to form [Cd(OPY)_2 H_2O]^(2+) units, which are then linked by tdc2-ligands to generate a one-dimensional chain. Every two adjacent chains linked by extensive O–H···O hydrogen bonds constitute one-dimensional double-chains, and such chains are extended into two-dimensional layers via O–H···N hydrogen bonds. These layers are further connected to form a three-dimensional supramolecular architecture via π-π stacking interactions. In addition, the thermal stability and solid state fluorescence property of 1 were also investigated.展开更多
Hydrothermal assembly of Co^(2+) ion, a bis-imidazole ligand BIMB(BIMB = 1,4-bis(imidazol-1-yl)benzene) and a rigid bidentate linker 2,6-naphthalenedicarboxylic acid(H_2ndc), yields a novel three-dimensional(3D) self-...Hydrothermal assembly of Co^(2+) ion, a bis-imidazole ligand BIMB(BIMB = 1,4-bis(imidazol-1-yl)benzene) and a rigid bidentate linker 2,6-naphthalenedicarboxylic acid(H_2ndc), yields a novel three-dimensional(3D) self-penetrating coordination polymer {[Co(BIMB)(ndc)]·H_2O}_n(1). Complex 1 exhibits {6~5.8} topology and contains a 2D → 3D parallel polycatenated substructure. In addition, solid-state UV-vis absorption spectra of 1 were also investigated.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.21361023 and 21461023)
文摘A new coordination polymer, {[Cd(OPY)_2(tdc)(H_2O)]·H2 O}n(OPY = 4,4?-(oxybis(4,1-phenylene))dipyridine, H2 tdc = thiophene-2,5-dicarboxylic acid), has been synthesized hydrothermally based on a V-shaped ligand OPY. The structure was fully characterized by elemental analysis, FT-IR spectroscopy, and X-ray single-crystal diffraction analysis. In1, two OPY ligands and one water molecule acted as terminal ligands coordinating to Cd^(2+) cation to form [Cd(OPY)_2 H_2O]^(2+) units, which are then linked by tdc2-ligands to generate a one-dimensional chain. Every two adjacent chains linked by extensive O–H···O hydrogen bonds constitute one-dimensional double-chains, and such chains are extended into two-dimensional layers via O–H···N hydrogen bonds. These layers are further connected to form a three-dimensional supramolecular architecture via π-π stacking interactions. In addition, the thermal stability and solid state fluorescence property of 1 were also investigated.
基金Supported by the National Natural Science Foundation of China(Nos.21361023 and 21461023)
文摘Hydrothermal assembly of Co^(2+) ion, a bis-imidazole ligand BIMB(BIMB = 1,4-bis(imidazol-1-yl)benzene) and a rigid bidentate linker 2,6-naphthalenedicarboxylic acid(H_2ndc), yields a novel three-dimensional(3D) self-penetrating coordination polymer {[Co(BIMB)(ndc)]·H_2O}_n(1). Complex 1 exhibits {6~5.8} topology and contains a 2D → 3D parallel polycatenated substructure. In addition, solid-state UV-vis absorption spectra of 1 were also investigated.
