Considering that thermodynarmic irreversibility and hydrodynamic equations can not be derived rigorously and unifiedly from the Liouville equations, the anomalous Langevin equation in the Liouville space is proposed a...Considering that thermodynarmic irreversibility and hydrodynamic equations can not be derived rigorously and unifiedly from the Liouville equations, the anomalous Langevin equation in the Liouville space is proposed as a fundamental equation of statistical physics. This equation reflects that the law of motion of particles obeying reversible, deterministic laws in dynamics becomes irreversible and stochastic in thermodynamics. From this the fundamental equations of nonequilibrium thermodynamics, the principle of entropy increase and the theorem of minimum entropy production have been derived. The hydrodynamic equations, such as the generalized Navier-Stokes equation and the mass drift-diffusion equation etc. have been derived rigorously from the kinetic kinetic equation which is reduced from the anomalous Langevin equation in Liouville space. All these are unified and self consistent. But it is difficult to prove that entropy production density σ can never be negative everywhere for all the isolated inhomogeneous systems far from equilibrium.展开更多
Nonequilibrium statistical theory of fracture is a theory of fracture that macromechanical quantities can be derived from the microscopic atomic mechanism of microcrack(or microvoid)evolution kinetcs by means of noneq...Nonequilibrium statistical theory of fracture is a theory of fracture that macromechanical quantities can be derived from the microscopic atomic mechanism of microcrack(or microvoid)evolution kinetcs by means of nonequilibrium statistical physical concepts and methods. The microcrack evolution equation is the central equation in the theory.The coefficents of the equation, the microcrack growth rate and the microcrack nucleation rate,come from microscopic atomic mechanism.The solution of the equation connects with macromechanical quantities by the model of the weakest chain. All the other formulas and quantities, for instance, distribution function,fracture probability, reliability, failure rate and macromechanical quantities such as strength, toughness, life etc. and their statistical distribution function and statistical fluctuation are derived in a unified fashion and expressed by a few physical parameters. This theory can be widely applied to various kinds of fracture, such as the brittle, fatigue, delayed and environmental fracture of metals and structural ceramics. The theoretical framework of this theory is given in this paper.展开更多
文摘Considering that thermodynarmic irreversibility and hydrodynamic equations can not be derived rigorously and unifiedly from the Liouville equations, the anomalous Langevin equation in the Liouville space is proposed as a fundamental equation of statistical physics. This equation reflects that the law of motion of particles obeying reversible, deterministic laws in dynamics becomes irreversible and stochastic in thermodynamics. From this the fundamental equations of nonequilibrium thermodynamics, the principle of entropy increase and the theorem of minimum entropy production have been derived. The hydrodynamic equations, such as the generalized Navier-Stokes equation and the mass drift-diffusion equation etc. have been derived rigorously from the kinetic kinetic equation which is reduced from the anomalous Langevin equation in Liouville space. All these are unified and self consistent. But it is difficult to prove that entropy production density σ can never be negative everywhere for all the isolated inhomogeneous systems far from equilibrium.
文摘Nonequilibrium statistical theory of fracture is a theory of fracture that macromechanical quantities can be derived from the microscopic atomic mechanism of microcrack(or microvoid)evolution kinetcs by means of nonequilibrium statistical physical concepts and methods. The microcrack evolution equation is the central equation in the theory.The coefficents of the equation, the microcrack growth rate and the microcrack nucleation rate,come from microscopic atomic mechanism.The solution of the equation connects with macromechanical quantities by the model of the weakest chain. All the other formulas and quantities, for instance, distribution function,fracture probability, reliability, failure rate and macromechanical quantities such as strength, toughness, life etc. and their statistical distribution function and statistical fluctuation are derived in a unified fashion and expressed by a few physical parameters. This theory can be widely applied to various kinds of fracture, such as the brittle, fatigue, delayed and environmental fracture of metals and structural ceramics. The theoretical framework of this theory is given in this paper.
