The adductive reaction of Ni[S2P(OCH2CH2Ph)2]2 with pyridine was studied by spectrographic method and the equilibrium constants was found to be β1=(1.12±0.09)×102,β2=(2.40±0.41)×104,R1=0.997,R2=0...The adductive reaction of Ni[S2P(OCH2CH2Ph)2]2 with pyridine was studied by spectrographic method and the equilibrium constants was found to be β1=(1.12±0.09)×102,β2=(2.40±0.41)×104,R1=0.997,R2=0.998.The adduct Ni[S2P(OCH2CH2Ph)2]2·2Py was characterized by elemental analysis,IR spectra,single-crystal X-ray diffraction method.The crystal structure belongs to monoclinic system,space group P 21/c with the following crystallographic parameters:a=9.240(3),b=16.124(8),c=14.148(7),α=90.00°,β=92.07(4)°,γ=90.00°.展开更多
Two novel starburst compounds (star arylamines),4,4′,4″ tris(diphenylamino) triphenylamine (TDATA) and 4,4′,4″ tris[3 methyl (phenyl) amino] triphenylamine (MTDATA),were designed and synthesized as hole transport ...Two novel starburst compounds (star arylamines),4,4′,4″ tris(diphenylamino) triphenylamine (TDATA) and 4,4′,4″ tris[3 methyl (phenyl) amino] triphenylamine (MTDATA),were designed and synthesized as hole transport materials with high glass transition temperature ( t g),good film formation and film stability,excellent hole transporting ability.展开更多
Spirooxazine is one of photochromic materials which find important uses in photochromic lens.optical information storage,and so on.The spirooxazine compound 6cyano1,3,3trimethylspiroindolino2,3naphthaoxazine...Spirooxazine is one of photochromic materials which find important uses in photochromic lens.optical information storage,and so on.The spirooxazine compound 6cyano1,3,3trimethylspiroindolino2,3naphthaoxazine]and 6 piperidino1,3,3trimethylspironaphthaoxazine]were synthesized with microwave irradiation.The reaction proceeded rapidly compared with conventional method and was completed in 4 min and with a high yield.展开更多
文摘The adductive reaction of Ni[S2P(OCH2CH2Ph)2]2 with pyridine was studied by spectrographic method and the equilibrium constants was found to be β1=(1.12±0.09)×102,β2=(2.40±0.41)×104,R1=0.997,R2=0.998.The adduct Ni[S2P(OCH2CH2Ph)2]2·2Py was characterized by elemental analysis,IR spectra,single-crystal X-ray diffraction method.The crystal structure belongs to monoclinic system,space group P 21/c with the following crystallographic parameters:a=9.240(3),b=16.124(8),c=14.148(7),α=90.00°,β=92.07(4)°,γ=90.00°.
文摘Two novel starburst compounds (star arylamines),4,4′,4″ tris(diphenylamino) triphenylamine (TDATA) and 4,4′,4″ tris[3 methyl (phenyl) amino] triphenylamine (MTDATA),were designed and synthesized as hole transport materials with high glass transition temperature ( t g),good film formation and film stability,excellent hole transporting ability.
文摘Spirooxazine is one of photochromic materials which find important uses in photochromic lens.optical information storage,and so on.The spirooxazine compound 6cyano1,3,3trimethylspiroindolino2,3naphthaoxazine]and 6 piperidino1,3,3trimethylspironaphthaoxazine]were synthesized with microwave irradiation.The reaction proceeded rapidly compared with conventional method and was completed in 4 min and with a high yield.
