Three new complexes of N salicylidenamino acid with Zn? have been synthesized. The compositions and structures of the obtained complexes have been characterized by elemental analyses, molar conductance, infrared spect...Three new complexes of N salicylidenamino acid with Zn? have been synthesized. The compositions and structures of the obtained complexes have been characterized by elemental analyses, molar conductance, infrared spectra, TG DTA and X ray powder diffraction. The three complexes have the compositions of Zn(sal β ala)·H2O(1),Zn(sal γ aba)·H2O(2),Zn(sal DL met)·1.5H2O(3)(sal=salicylidene,β ala=β alanine,γ aba=γ aminobutyric acid,DL met=DL methionine) and the molecular formula of ZnC10H11O4N, ZnC11H13O4N, ZnC12H16O4.5NS respectively. Infrared spectra of the complexes indicate that water has been coordinated. The thermal decomposition processes of the complexes show that the first weight losses are in good agreement with the water contents, and the compositions of the final residues are zinc oxide. The results of indexes to the X ray powder diffraction data indicate that the crystal structure of the three complexes belong to triclinic system. The lattice parameters are:a=1.9522nm,b=1.3904nm,c=2.0235nm,α=97.33°,β=98.66°,γ=99.05° for 1;a=1.3944nm,b=2.0880nm,c=2.4455nm,α=92.99°,β=95.48°,γ=96.18° for 2;a=2.1892nm,b=1.9171nm,c=1.4546nm,α=94.76°,β=95.09°,γ=94.12° for 3 respectively.展开更多
The copper complexes of biuret have been synthesized by solid phase react ion with microwave irradiation. The compositions and structures of the complexes are characterized by elemental analysis, molar conductance, in...The copper complexes of biuret have been synthesized by solid phase react ion with microwave irradiation. The compositions and structures of the complexes are characterized by elemental analysis, molar conductance, infrared spectra, e lectronic spectra, magnetic susceptibility, thermogravimetric and differential t hermal analysis, X-ray powder diffraction. The two complexes have the composit ions of Cl2(A) and (NO3)2(B)(bi=NH2CONHCONH2) and the molecula r formulae of CuC4H10O4N6Cl2 and CuC4H10O10N8, respectively. The molar conductan ce data show that the complexes are 1∶2 electrolyte. Infrared spectra of the c omplexes show oxygen atoms have been coordinated with divalent copper ion. The t hermal decomposition processes of the complexes show that the final residues are all cupper oxide. The results of indexes to the X-ray powder diffraction data indicate that the crystal structure of the complexes belong to monoclinic syste m, the lattice parameters are: a=0.6976nm,b=1.1546 nm,c=2.1689nm,a=96.80 1.7346nm3 for A; and a=0.7096nm,b=1.1359 nm,c=2.1002 nm,a=97.05nm3 for B, respectively.展开更多
The novel complex of thioglycolic acid and trivalent antimony ion had been synthesized by liquid phase reaction of thioglycolic acid and antimony trichloride.The structure of the complex was characterized by elemental...The novel complex of thioglycolic acid and trivalent antimony ion had been synthesized by liquid phase reaction of thioglycolic acid and antimony trichloride.The structure of the complex was characterized by elemental analyses and X ray powder diffraction.The complex has the composition of HSb(SCH 2COO) 2 being white crystal,stable in air,non hygroscopicity and decomposed above 208℃.The results of indexes to the X ray powder diffraction data indicate that the crystal structure of the complex belongs to monoclinic system.The lattice parameters are:a=1.4015nm,b=1.2092nm,c=1.2419nm,β=126.68°,V=1.6879nm 3,Z=8,D cal =2.384g·cm -3 ,D exp =2.374g·cm -3 .The calculated lattice parameters are in agreement with those of the single crystal determined by us.展开更多
文摘Three new complexes of N salicylidenamino acid with Zn? have been synthesized. The compositions and structures of the obtained complexes have been characterized by elemental analyses, molar conductance, infrared spectra, TG DTA and X ray powder diffraction. The three complexes have the compositions of Zn(sal β ala)·H2O(1),Zn(sal γ aba)·H2O(2),Zn(sal DL met)·1.5H2O(3)(sal=salicylidene,β ala=β alanine,γ aba=γ aminobutyric acid,DL met=DL methionine) and the molecular formula of ZnC10H11O4N, ZnC11H13O4N, ZnC12H16O4.5NS respectively. Infrared spectra of the complexes indicate that water has been coordinated. The thermal decomposition processes of the complexes show that the first weight losses are in good agreement with the water contents, and the compositions of the final residues are zinc oxide. The results of indexes to the X ray powder diffraction data indicate that the crystal structure of the three complexes belong to triclinic system. The lattice parameters are:a=1.9522nm,b=1.3904nm,c=2.0235nm,α=97.33°,β=98.66°,γ=99.05° for 1;a=1.3944nm,b=2.0880nm,c=2.4455nm,α=92.99°,β=95.48°,γ=96.18° for 2;a=2.1892nm,b=1.9171nm,c=1.4546nm,α=94.76°,β=95.09°,γ=94.12° for 3 respectively.
文摘The copper complexes of biuret have been synthesized by solid phase react ion with microwave irradiation. The compositions and structures of the complexes are characterized by elemental analysis, molar conductance, infrared spectra, e lectronic spectra, magnetic susceptibility, thermogravimetric and differential t hermal analysis, X-ray powder diffraction. The two complexes have the composit ions of Cl2(A) and (NO3)2(B)(bi=NH2CONHCONH2) and the molecula r formulae of CuC4H10O4N6Cl2 and CuC4H10O10N8, respectively. The molar conductan ce data show that the complexes are 1∶2 electrolyte. Infrared spectra of the c omplexes show oxygen atoms have been coordinated with divalent copper ion. The t hermal decomposition processes of the complexes show that the final residues are all cupper oxide. The results of indexes to the X-ray powder diffraction data indicate that the crystal structure of the complexes belong to monoclinic syste m, the lattice parameters are: a=0.6976nm,b=1.1546 nm,c=2.1689nm,a=96.80 1.7346nm3 for A; and a=0.7096nm,b=1.1359 nm,c=2.1002 nm,a=97.05nm3 for B, respectively.
文摘The novel complex of thioglycolic acid and trivalent antimony ion had been synthesized by liquid phase reaction of thioglycolic acid and antimony trichloride.The structure of the complex was characterized by elemental analyses and X ray powder diffraction.The complex has the composition of HSb(SCH 2COO) 2 being white crystal,stable in air,non hygroscopicity and decomposed above 208℃.The results of indexes to the X ray powder diffraction data indicate that the crystal structure of the complex belongs to monoclinic system.The lattice parameters are:a=1.4015nm,b=1.2092nm,c=1.2419nm,β=126.68°,V=1.6879nm 3,Z=8,D cal =2.384g·cm -3 ,D exp =2.374g·cm -3 .The calculated lattice parameters are in agreement with those of the single crystal determined by us.
