The paper chiefly compares the catalytic activity and stability of nano-sized nickel and Raney nickel in the catalytic hydrogenation of p-nitrophenol.The experimental results show that the catalytic activity and stabi...The paper chiefly compares the catalytic activity and stability of nano-sized nickel and Raney nickel in the catalytic hydrogenation of p-nitrophenol.The experimental results show that the catalytic activity and stability of nano-sized nickel are superior to those of Raney nickel under the same reaction conditions. The fresh and used nickel samples are characterized by nitrogen sorption and particle analyzer. The results suggest that particle size,surface structure,etc. may play a key role in determining the catalytic activity of nickel samples.The aggregation of nano-particles would lead to the deactivation of nano-sized nickel,while the jamming of pores would be one of the reasons for the deactivation of Raney nickel.展开更多
Ceramic membranes were used to recover nanometer nickel catalyst in the preparation of p-aminophenol.In order to resolve the problem of adsorption loss of nanometer nickel in the pilot plant, inert particles were adde...Ceramic membranes were used to recover nanometer nickel catalyst in the preparation of p-aminophenol.In order to resolve the problem of adsorption loss of nanometer nickel in the pilot plant, inert particles were added to the suspension. As a result, adding inert particles such as micro or submicro oxides was proven to be effective.They could alleviate the adsorption loss of nanometer nickel particles and shorten the time of reaching steady state of nickel concentration without affecting the activity of the catalyst and permeate flux.展开更多
文摘The paper chiefly compares the catalytic activity and stability of nano-sized nickel and Raney nickel in the catalytic hydrogenation of p-nitrophenol.The experimental results show that the catalytic activity and stability of nano-sized nickel are superior to those of Raney nickel under the same reaction conditions. The fresh and used nickel samples are characterized by nitrogen sorption and particle analyzer. The results suggest that particle size,surface structure,etc. may play a key role in determining the catalytic activity of nickel samples.The aggregation of nano-particles would lead to the deactivation of nano-sized nickel,while the jamming of pores would be one of the reasons for the deactivation of Raney nickel.
基金supported by the National Key Technology R&D Program (2011BAE07B05)the National High Technology Research and Development Program of China (863 Program+2 种基金 2012AA03A606)the National Natural Science Foundation of China (20990222 21106061)~~
文摘Ceramic membranes were used to recover nanometer nickel catalyst in the preparation of p-aminophenol.In order to resolve the problem of adsorption loss of nanometer nickel in the pilot plant, inert particles were added to the suspension. As a result, adding inert particles such as micro or submicro oxides was proven to be effective.They could alleviate the adsorption loss of nanometer nickel particles and shorten the time of reaching steady state of nickel concentration without affecting the activity of the catalyst and permeate flux.
