Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been ...Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that （i） CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V （vs. RHE）; （ii） at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; （iii） MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; （iv） at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/（site sec）. Suggestions for further improving of PtRu catalysts for MOR are provided.展开更多
现有的在线估计一次调频能力的指标没有考虑调频死区对电网一次调频能力的影响。为了表征调频死区对电网一次调频能力的影响,提出利用均方差定义电网一次调频能力(Primary Frequency Modulation Ability,PFMA)指标。根据一次调频模型给...现有的在线估计一次调频能力的指标没有考虑调频死区对电网一次调频能力的影响。为了表征调频死区对电网一次调频能力的影响,提出利用均方差定义电网一次调频能力(Primary Frequency Modulation Ability,PFMA)指标。根据一次调频模型给出了其静态和动态表达式。最后通过计算仿真,对比了不考虑死区和不同死区大小情况下的评价指标曲线。结果表明,所提的指标同时兼顾了一次调频能力的动态特性和死区,实现了一次调频能力的在线全面评估。展开更多
文摘Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that （i） CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V （vs. RHE）; （ii） at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; （iii） MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; （iv） at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/（site sec）. Suggestions for further improving of PtRu catalysts for MOR are provided.
文摘现有的在线估计一次调频能力的指标没有考虑调频死区对电网一次调频能力的影响。为了表征调频死区对电网一次调频能力的影响,提出利用均方差定义电网一次调频能力(Primary Frequency Modulation Ability,PFMA)指标。根据一次调频模型给出了其静态和动态表达式。最后通过计算仿真,对比了不考虑死区和不同死区大小情况下的评价指标曲线。结果表明,所提的指标同时兼顾了一次调频能力的动态特性和死区,实现了一次调频能力的在线全面评估。
