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硫化铅在19520~22900 cm^(-1)范围内振转光谱的研究
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作者 陈旖旎 陈森 +1 位作者 印建平 汪海玲 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2023年第1期35-40,I0001,共7页
本文采用了激光消-激光诱导荧光的方法研究了硫化铅在19520~22900 cm^(-1)范围内的振转光谱.基于对测量得到的实验光谱数据分析的基础,本文确认此段光谱为硫化铅的A-X和B-X振转跃迁光谱.通过分析和讨论19520~21090 cm^(-1)范围内的光谱... 本文采用了激光消-激光诱导荧光的方法研究了硫化铅在19520~22900 cm^(-1)范围内的振转光谱.基于对测量得到的实验光谱数据分析的基础,本文确认此段光谱为硫化铅的A-X和B-X振转跃迁光谱.通过分析和讨论19520~21090 cm^(-1)范围内的光谱数据,确认该段光谱的上电子态是_(3)Π_(0+)和_(3)Σ_(0+)^(-)态的混合态.其中,^(3)Π_(0+)在该混合态中占主导地位.在22025~22900 cm^(-1)范围内的光谱属于B^(3)Π_(1)−X^(1)Σ^(+)跃迁谱.通过分析实验数据获得了这两个电子跃迁光谱的上下电子态的光谱常数.在理论方面,本文RKR/LEVEL的方法计算了这两个跃迁的振动态之间的弗兰克-康登因子.本文中对实验和计算的结果与已报道的实验和理论结果进行了对比和分析,实验确定了硫化铅的A态是一个混合态,这和Balasubramanian的相对论组态相互作用计算的结果一致,计算得到的弗兰克-康登因子和实验光谱相应跃迁的谱线强度吻合. 展开更多
关键词 振转光谱 分子常数 势能曲线 混合态
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Research and Application Progress of Straw 被引量:1
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作者 ben chen Sarah Mohrmann +6 位作者 Haitao Li Milan Gaff Rodolfo Lorenzo Ileana Corbi Ottavia Corbi Kaidong Fang Min Li 《Journal of Renewable Materials》 SCIE EI 2023年第2期599-623,共25页
Straw is a general term for the stem and leaf parts of mature crops,and is a multi-purpose renewable biomass energy resource in the agricultural ecosystem.The prospect of comprehensive utilization of straw has become ... Straw is a general term for the stem and leaf parts of mature crops,and is a multi-purpose renewable biomass energy resource in the agricultural ecosystem.The prospect of comprehensive utilization of straw has become broad with the development of agricultural production,the advancement of science and technology,and the improvement of the level of agricultural mechanization.The comprehensive utilization of straw plays an important role in enhancing the sustainable development ability of agricultural economy and improving the current situation of comprehensive utilization of agricultural resources in my country.This paper briefly combs the development history of straw and the prospect and current situation of comprehensive utilization,and expounds the separation technology of straw components,straw man-made panels,straw concrete,straw returning technology and oyster mushroom cultivation.It focuses on the description of the component separation technology of straw and the manufacturing process of straw-based panels.The different separation methods and separation effects of cellulose,hemicellulose and lignin were introduced in detail,and the static yield strength(MOR),internal bonding strength(IB)and water absorption thickness of several common straw-based panels were compared and studied(TS).Finally,it summarizes the benefit analysis of the comprehensive utilization of straw by scholars from the perspective of economics,and summarizes the corresponding measures based on their own views. 展开更多
关键词 STRAW comprehensive utilization component separation technology straw-based panel straw concrete
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Effects of various rare earth oxides on morphology and size of oxide dispersion strengthening(ODS)-W and ODS-Mo alloy powders 被引量:3
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作者 He ZHANG Zhi-bo LI +3 位作者 Xiao-chun DENG ben chen Guo-hua ZHANG Kuo-Chih CHOU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第8期2665-2680,共16页
Ultrafine oxide dispersion strengthening(ODS)-Mo and ODS-W alloy powders containing different types of oxide nanoparticles were successfully synthesized by spraying method(solid−liquid mixing method)combined with the ... Ultrafine oxide dispersion strengthening(ODS)-Mo and ODS-W alloy powders containing different types of oxide nanoparticles were successfully synthesized by spraying method(solid−liquid mixing method)combined with the reductions with carbon black and hydrogen in sequence.It is concluded that the solution concentration and type of rare earth oxide have no effect on the grain size of ODS-Mo alloy powder,but have obvious effect on that of ODS-W alloy powder.The higher the concentration of rare earth solution is,the smaller the average grain size of ODS-W alloy powder is.Furthermore,compared with doping with CeO_(2),the grain sizes of reduction products of La_(2)O_(3) and Y_(2)O_(3) doped WO_(3) are relatively larger.Compared with the undoped case,there is almost no change for grain size of ODS-Mo alloy powder,while the grain size of ODS-W alloy powder becomes much larger.This is probably due to the appearance of the composite oxide(such as La_(2)WO_(6))formed by the reaction between tungsten oxide and rare earth oxides,which promotes the heterogeneous nucleation and growth of tungsten grains during the reduction process of ODS-W,while there is no complex oxide composed of molybdenum and rare earth oxides in the reduction process of ODS-Mo. 展开更多
关键词 grain size rare earth oxide oxide dispersion strengthened alloy W MO
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Auricular cartilage versus donor sclera as a wrapping of hydroxyapatite orbital implants 被引量:1
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作者 Ying-Jie Ma Xiu-Ying Zhu +3 位作者 ben chen Yan-Yan Lin Jia Liu Xi chen 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2021年第3期436-441,共6页
AIM: To retrospectively compare postoperative outcomes after primary enucleation and placement of a hydroxyapatite(HA) implant without wrapping, wrapped with auricular cartilage or donor sclera. METHODS: Medical recor... AIM: To retrospectively compare postoperative outcomes after primary enucleation and placement of a hydroxyapatite(HA) implant without wrapping, wrapped with auricular cartilage or donor sclera. METHODS: Medical records of patients presented as intraocular tumor or severe ocular injury were identified from the electronic medical record system. Cases underwent enucleation and HA orbital implantation were enrolled in this study and were divided into 3 groups according to the wrapping material of HA implant. Cases with autogenous cartilage caps were enrolled in group A(n=11), with donor sclera caps in group B(n=12), and without any wrapping material in group C(n=9). Follow-ups were set at 1, 2 wk, 1, 3, 6, and 12 mo after surgery.RESULTS: Altogether 32 cases finished the followup and were enrolled in this study. Three cases(27.27%) in group A, 4 cases(33.33%) in group B, and 4 cases(44.44%) in group C developed one complication each after surgery. In group A, no HA exposure occurred, but conjunctival inclusion cyst occurred in one and severe conjunctive chemosis in two cases. In group B, one HA exposure occurred, conjunctive inclusion cysts occurred in one, severe conjunctive chemosis occurred in one, and conjunctival granuloma occurred in one case. In group C, one HA exposure occurred, severe conjunctive chemosis occurred in two cases, and conjunctival granuloma occurred in one case. The case of exposure of none-wrapped implant was noted in the first 6 mo after placement of the orbital implant. The case of exposure of donor sclerawrapped implant was noted at the 12 mo after placement of the orbital implant. Both exposure cases were treated successfully with conservative treatment.CONCLUSION: With low incidence of implant exposure and mild complications, auricular cartilage can be a good choice of alternative wrapping material of orbit implant with satisfied outcome. 展开更多
关键词 hydroxyapatite orbital implants WRAPPING auricular cartilage donor sclera COMPLICATION
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Dental management of a patient with Moebius syndrome:A case report 被引量:1
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作者 ben chen Ling-Xia Li Li-Li Zhou 《World Journal of Clinical Cases》 SCIE 2021年第24期7269-7278,共10页
BACKGROUND Moebius syndrome(MBS)is a nonprogressive and rare congenital neuromuscular disorder involving the facial nerve and abductor nerve;it mainly manifests as facial paralysis and eye strabismus paralytic symptom... BACKGROUND Moebius syndrome(MBS)is a nonprogressive and rare congenital neuromuscular disorder involving the facial nerve and abductor nerve;it mainly manifests as facial paralysis and eye strabismus paralytic symptoms.Tissues in the oral cavity are also compromised,characterized by microstomia,micrognathia,tongue malformation,cleft lip,high arched palate or cleft palate,bifid uvula,and dental malocclusion.Therefore,dentistry plays a fundamental and crucial role in caring for these individuals.However,there is limited available data on MBS treatment,particularly regarding dental management.CASE SUMMARY This case report presents dental treatment of a 21-year-old man with MBS and discusses crucial interactions among oral complications of MBS.In this case,the patient was clinically characterized by congenital neuromuscular disorder,occlusal disorders,and tooth and gum problems.It is noteworthy that the patient presented early eruption of deciduous teeth 2 mo after birth,which has not been reported in other MBS cases and suggests a potentially new clinical manifestation of this syndrome.It is important to note that MBS cannot be cured,and oral manifestations of this syndrome can be managed by a multidisciplinary health care team that helps the patient maintain oral hygiene and dental health.After a series of oral treatments,no obvious poor oral hygiene,swollen gums,or abnormal imaging results were observed after 2 years of follow-up.CONCLUSION This case addressed the oral clinical manifestations of MBS and difficulties experienced during dental management,and suggested early tooth eruption as a potentially new clinical manifestation of this syndrome.Knowledge of the loopmediated association among oral complications of this syndrome is essential to perfecting treatments. 展开更多
关键词 Dental treatment Moebius syndrome Oral complications Oral anomalies Early tooth eruption Case report
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Conjunctival flap with auricular cartilage grafting: a modified Hughes procedure for large full thickness upper and lower eyelid defect reconstruction 被引量:1
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作者 ben chen David Meng-da Woo +4 位作者 Jia Liu Xiu-Ying Zhu Yan-Yan Lin Ying-Jie Ma Xi chen 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2021年第8期1168-1173,共6页
AIM:To investigate the suitability of a modified Hughes procedure,which consists of conjunctival flap with auricular cartilage grafting in reconstructing large full thickness upper and lower eyelid defect.METHODS:Pati... AIM:To investigate the suitability of a modified Hughes procedure,which consists of conjunctival flap with auricular cartilage grafting in reconstructing large full thickness upper and lower eyelid defect.METHODS:Patients with full thickness eyelid carcinoma involving more than 50%margin length who underwent surgical resection were retrospectively reviewed in the study.The defects were reconstructed using conjunctival flap with auricular cartilage grafting,covered with myocutaneous flap above.Followed-up time ranged from 12 to 24 mo.Outcomes were classified as“good”,“fair”,and“poor”by evaluating the margin appearance,eyelid appearance,and complications.RESULTS:A total of 42 patients were enrolled in the study(26 males,16 females,mean age,68.6±7.7 y,range:53 to 82 y).The mean defect widths measured 23.2±2.9 mm(range,17 to 28 mm).The mean posterior lamellar defect height was 5.5±1.3 mm(4 to 8 mm).Thirty-seven patients had a“good”outcome(88.1%),5 patients had a“fair”outcome(11.9%),and no one had a“poor”outcome.CONCLUSION:Conjunctival flap with auricular cartilage grafting and myocutaneous flap grafting is an effective procedure in reconstructing large full thickness upper and lower eyelid defect.It can not only achieve satisfied reconstruction,but also preserve intact tarsal plate of the opposite eyelid,avoiding retraction or entropion. 展开更多
关键词 auricular cartilage grafting conjunctival flap full thickness eyelid defect Hughes procedure
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Spectroscopic study of B^(2)Σ^(+)-X_(1)^(2)Π_(1/2) transition of electron electric dipole moment candidate PbF
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作者 ben chen Yi-Ni chen +2 位作者 Jia-Nuan Pan Jian-Ping Yin Hai-Ling Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第9期281-285,共5页
PbF,a valuable candidate for measuring the electron electric dipole moment(eEDM),is of great significance in measuring its spectrum and deriving its molecular constants in experiment.In the present work,the rovibronic... PbF,a valuable candidate for measuring the electron electric dipole moment(eEDM),is of great significance in measuring its spectrum and deriving its molecular constants in experiment.In the present work,the rovibronic spectrum of the B^(2)Σ^(+)-X_(1)^(2)Π_(1/2) transition of PbF in a wavelength range of 260 nm-285 nm is studied by the laser ablation/laser induced fluorescence method.The molecular parameters of the X_(1)^(2)Π_(1/2)(v"=0)and B^(2)Σ+(v'=0,1)states are derived from the recorded spectra of the(0,0)and(1,0)bands of the B^(2)Σ+-X_(1)^(2)Π_(1/2) transition.Also,the Franck-Condon factors(FCFs)of the transitions between the B^(2)Σ+and X_(1)^(2)Π_(1/2)states are calculated by the RKR/LEVEL method and the Morse potential method,respectively. 展开更多
关键词 spectroscopic parameters Franck-Condon factors an eEDM candidate LIFETIME
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夜空中闪亮的“象牙彗星” 华裔Builder引爆美国订制摩托车圈的开山之作
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作者 Paddy ben chen 《摩托车》 2014年第10期82-83,共2页
在连续斩获美国2104 Born Free Motorcycle Show Best CaféRacer(2014"生而自由"定制车展最佳铸造师)以及2014 Los Angels Calendar Motorcycle Show"First Place"at Pro Builder(2014洛杉矶摩托车展首席专业铸造师)两项... 在连续斩获美国2104 Born Free Motorcycle Show Best CaféRacer(2014"生而自由"定制车展最佳铸造师)以及2014 Los Angels Calendar Motorcycle Show"First Place"at Pro Builder(2014洛杉矶摩托车展首席专业铸造师)两项重量级大奖之后,洛杉矶华裔Builder高荣衫携以哈雷SPORTETER为基础车订制而成的Ivory Come(中文译为"象牙彗星")再次获得Venice Vintage Motorcycle Custom的best Café大奖。高荣衫的作品为近年逐渐走向瓶颈的美国定制车行业吹来了一股新风,下面我们就来一起了解这台"象牙彗星"。 展开更多
关键词 BUILDER CALENDAR 哈雷 车身线条 工业造型设计 帕萨迪纳 复古主义 新元素 科技感 原型车
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BenChen脑洞略大的搞笑插画
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作者 ben chen 《意林文汇》 2016年第21期35-35,共1页
Ben Chen的插画作品常常透着一股幽默,他充满想象力的恶搞趣味受到网友的欢迎。充满童趣,又带些黑色幽默的画风是他偏爱的,而他最喜欢的,是将漫画、游戏人物改头换面或者相互窖串,从而让人会心一笑。
关键词 插画作品 黑色幽默 想象力 童趣
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红景天苷激活自噬促进肺癌细胞株A549凋亡的作用及机制
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作者 贲晨 杨大彬 赵伟 《中国临床药理学杂志》 CAS CSCD 北大核心 2023年第21期3102-3105,共4页
目的观察红景天苷对肺癌细胞株A549自噬及凋亡行为的影响,并探究其作用机制。方法将肺癌细胞A549分为对照组(细胞正常培养),低剂量实验组和高剂量实验组(细胞分别给予40和80μmol·L^(-1)红景天苷处理),3-MA组(细胞给予5 mmol·... 目的观察红景天苷对肺癌细胞株A549自噬及凋亡行为的影响,并探究其作用机制。方法将肺癌细胞A549分为对照组(细胞正常培养),低剂量实验组和高剂量实验组(细胞分别给予40和80μmol·L^(-1)红景天苷处理),3-MA组(细胞给予5 mmol·L^(-1)3-MA进行处理),3-MA+高剂量实验组(细胞给予5 mmol·L^(-1)3-MA和80μmol·L^(-1)红景天苷共同处理)。给药24 h后,以噻唑蓝(MTT)法检测细胞增殖水平,以流式细胞术检测细胞凋亡水平,以免疫荧光染色观察A549中自噬相关蛋白轻链3(LC3)荧光强度变化,以蛋白质印迹(Western Blot)实验分别检测细胞中磷酸化磷酸肌醇3激酶(p-PI3K)、蛋白激酶B(Akt)、雷帕霉素靶蛋白(mTOR)蛋白的表达水平。结果对照组和低、高剂量实验组A549细胞相对存活率分别为100.00%、(61.17±3.16)%和(44.39±2.19)%,细胞凋亡率分别为(3.91±0.67)%、(11.45±0.85)%和(18.09±1.21)%,p-PI3K蛋白相对表达水平分别为1.11±0.08、0.78±0.04和0.40±0.05,p-Akt蛋白相对表达水平分别为0.94±0.03、0.62±0.07和0.32±0.04,p-mTOR蛋白相对表达水平分别为1.16±0.05、0.59±0.06和0.19±0.03,LC3平均荧光强度分别为(51.36±3.02)%、(76.04±3.62)%和(119.88±4.03)%。低、高剂量实验组的上述指标与对照组比较,差异均有统计学意义(均P<0.05)。结论红景天苷可激活肺癌细胞A549自噬,抑制增殖并诱导其凋亡,其机制可能与下调PI3K/Akt/mTOR通路相关。 展开更多
关键词 红景天苷 肺癌 自噬 凋亡 磷脂酰肌醇-3-激酶
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Differences in olfactory functional connectivity in early-onset depression and late-onset depression
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作者 ben chen Mingfeng Yang +9 位作者 Meiling Liu Qiang Wang Huarong Zhou Min Zhang Le Hou Zhangying Wu Si Zhang Gaohong Lin Xiaomei Zhong Yuping Ning 《Psychoradiology》 2023年第1期285-294,共10页
Background:Late-onset depression(LOD)and early-onset depression(EOD)exhibit different pathological mechanisms and clinical phenotypes,including different extents of olfactory dysfunction.However,the brain abnormalitie... Background:Late-onset depression(LOD)and early-onset depression(EOD)exhibit different pathological mechanisms and clinical phenotypes,including different extents of olfactory dysfunction.However,the brain abnormalities underlying the differences in ol-factory dysfunction between EOD and LOD remain unclear.Objective:The aim of this study was to compare the functional connectivity(FC)patterns of olfactory regions between EOD patients and LOD patients and examine their relationship with cognitive function.Methods:One hundred and five patients with EOD,101 patients with LOD and 160 normal controls(NCs)were recruited for the present study.Participants underwent clinical assessment,olfactory testing,cognitive assessments,and magnetic resonance imaging.Eight regions of the primary and secondary olfactory regions were selected to investigate olfactory FC.Results:Patients with LOD exhibited decreased odor identification(OI)compared with patients with EOD and NCs.The LOD group exhibited decreased FC compared with the EOD and NC groups when primary and secondary olfactory regions were selected as the regions of interest(the piriform cortex,lateral entorhinal cortex,and orbital-frontal cortex).Additionally,these abnormal olfactory FCs were associated with decreased cognitive function scores and OI,and the FC between the left orbital-frontal cortex and left amygdala was a partial mediator of the relationship between global cognitive scores and OI.Conclusion:Overall,patients with LOD exhibited decreased FC in both the primary and secondary olfactory cortices compared with patients with EOD,and abnormal olfactory FC was associated with OI dysfunction and cognitive impairment.The FC between the orbital-frontal cortex and amygdala mediated the relationship between global cognitive function and OI. 展开更多
关键词 late-life depression olfactory dysfunction MRI functional connectivity late-onset depression RESTING-STATE
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累及弓部的复杂B型主动脉夹层的外科治疗 被引量:1
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作者 贲晨 陈雷 +1 位作者 杨大彬 施超 《中华全科医学》 2022年第1期59-61,133,共4页
目的对应用术中支架联合左锁骨下动脉-左颈总动脉转流术治疗累及远端主动脉弓的复杂B型主动脉夹层的效果进行评估。方法2018年11月-2020年4月,淮北矿工总医院心胸外科对6例Stanford B型主动脉夹层累及远端主动脉弓的患者施行了术中支架... 目的对应用术中支架联合左锁骨下动脉-左颈总动脉转流术治疗累及远端主动脉弓的复杂B型主动脉夹层的效果进行评估。方法2018年11月-2020年4月,淮北矿工总医院心胸外科对6例Stanford B型主动脉夹层累及远端主动脉弓的患者施行了术中支架联合左锁骨下动脉-左颈总动脉转流术,患者均为男性,平均年龄为51岁。6例患者均有高血压病史。弓部最大直径>40 mm,破口均位于远端主动脉弓,距离左锁骨下动脉开口距离<1.5 cm。统计体外循环时间、术中阻断时间、停循环选择性脑灌注时间、呼吸机辅助时间、围术期病死率,术后脑梗死、截瘫、二次开胸止血发生率。术后通过门诊及电话随访。分别于患者术后1周、3个月、12个月复查主动脉CT血管造影(CTA)。结果体外循环时间为80~207(145±37)min,术中阻断时间平均为34.5 min,停循环选择性脑灌注时间平均为12 min。3例患者术后呼吸机辅助时间超过24 h(分别为41、44、26 h)。平均呼吸机辅助时间为16.48 h。术后均无头晕症状,神志及精神恢复良好,未出现脑梗死、截瘫、二次开胸止血,未发生围手术期死亡,患者均顺利出院。随访时间为3~18个月不等。随访期间,患者生活状况良好。术后复查主动脉CTA,支架远端水平假腔闭塞率为100.0%(6/6)。结论对于具有手术适应证的复杂型Stanford B型夹层患者采用外科手术,手术效果和术后近期随访结果令人满意。但本组患者例数较少,且随访时间较短,远期的临床效果仍需通过长期随访进一步判断。 展开更多
关键词 累及弓部 B型主动脉夹层 术中支架
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Three-dimensional ordered macroporous g-C_(3)N_(4)-Cu_(2)O-TiO_(2) heterojunction for enhanced hydrogen production 被引量:4
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作者 ben chen Jing Yu +5 位作者 Rui Wang Xianggong Zhang Beibei He Jun Jin Huanwen Wang Yansheng Gong 《Science China Materials》 SCIE EI CAS CSCD 2022年第1期139-146,共8页
In this study,a g-C_(3)N_(4)-Cu_(2)O-TiO_(2) photocatalyst with a novel three-dimensional ordered macroporous(3DOM)structure was successfully prepared using a sacrificial template strategy and a photodeposition method... In this study,a g-C_(3)N_(4)-Cu_(2)O-TiO_(2) photocatalyst with a novel three-dimensional ordered macroporous(3DOM)structure was successfully prepared using a sacrificial template strategy and a photodeposition method.The influence of the special porous structure with cross pore channels on the photocatalytic properties of the as-prepared sample was studied in detail.Compared with the original photocatalyst(TiO_(2) with 3 wt%Pt),g-C_(3)N_(4)-Cu_(2)O-TiO_(2) exhibited a higher specific surface area and more active sites,thus accelerating the separation efficiency of the photogenerated electron-hole pair.Consequently,the as-prepared photocatalyst showed good photocatalytic performance,reaching a maximum hydrogen production rate of 12,108μmol g^(-1) h^(-1) and approximately five times higher than that of the pristine comparison sample.The enhanced photoactivity of the g-C_(3)N_(4)-Cu_(2)O-TiO_(2) heterojunction can be ascribed to its double p-n heterojunction and robust porous structure,where the photodeposited Cu_(2)O plays a synergistic catalytic role in the photocatalytic process and the outer clad g-C_(3)N_(4) layer prevents Cu_(2)O oxidation.Additionally,the possible photocatalytic mechanism was briefly discussed based on the experimental results.This work identifies viable pathways for developing low-cost heterojunction photocatalysts with highly efficient photocatalytic activity toward improved solar energy conversion. 展开更多
关键词 noble metal-free cocatalyst cross pore channels 3DOM structure photocatalytic hydrogen evolution
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