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Stability analysis of a liquid crystal elastomer self-oscillator under a linear temperature field
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作者 Haiyang WU Jiangfeng LOU +2 位作者 biao zhang Yuntong DAI Kai LI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第2期337-354,共18页
Self-oscillating systems abound in the natural world and offer substantial potential for applications in controllers,micro-motors,medical equipments,and so on.Currently,numerical methods have been widely utilized for ... Self-oscillating systems abound in the natural world and offer substantial potential for applications in controllers,micro-motors,medical equipments,and so on.Currently,numerical methods have been widely utilized for obtaining the characteristics of self-oscillation including amplitude and frequency.However,numerical methods are burdened by intricate computations and limited precision,hindering comprehensive investigations into self-oscillating systems.In this paper,the stability of a liquid crystal elastomer fiber self-oscillating system under a linear temperature field is studied,and analytical solutions for the amplitude and frequency are determined.Initially,we establish the governing equations of self-oscillation,elucidate two motion regimes,and reveal the underlying mechanism.Subsequently,we conduct a stability analysis and employ a multi-scale method to obtain the analytical solutions for the amplitude and frequency.The results show agreement between the multi-scale and numerical methods.This research contributes to the examination of diverse self-oscillating systems and advances the theoretical analysis of self-oscillating systems rooted in active materials. 展开更多
关键词 SELF-OSCILLATION stability analysis multi-scale method liquid crystal elastomer linear temperature field
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Proof of Aerobically Autoxidized Self-Charge Concept Based on Single Catechol-Enriched Carbon Cathode Material
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作者 Junyan Wang Wanchun Guo +12 位作者 Kesong Tian Xinta Li Xinyu Wang Panhua Li Yu zhang Bosen zhang biao zhang Shuhu Liu Xueai Li Zhaopeng Xu Junjie Xu Haiyan Wang Yanglong Hou 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期1-13,共13页
The self-charging concept has drawn considerable attention due to its excellent ability to achieve environmental energy harvesting,conversion and storage without an external power supply.However,most self-charging des... The self-charging concept has drawn considerable attention due to its excellent ability to achieve environmental energy harvesting,conversion and storage without an external power supply.However,most self-charging designs assembled by multiple energy harvesting,conversion and storage materials increase the energy transfer loss;the environmental energy supply is generally limited by climate and meteorological conditions,hindering the potential application of these selfpowered devices to be available at all times.Based on aerobic autoxidation of catechol,which is similar to the electrochemical oxidation of the catechol groups on the carbon materials under an electrical charge,we proposed an air-breathing chemical self-charge concept based on the aerobic autoxidation of catechol groups on oxygen-enriched carbon materials to ortho-quinone groups.Energy harvesting,conversion and storage functions could be integrated on a single carbon material to avoid the energy transfer loss among the different materials.Moreover,the assembled Cu/oxygen-enriched carbon battery confirmed the feasibility of the air-oxidation self-charging/electrical discharging mechanism for potential applications.This air-breathing chemical self-charge concept could facilitate the exploration of high-efficiency sustainable air self-charging devices. 展开更多
关键词 Carbon material Oxygen functionality Air oxidation self-charge
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Event plane determination from the zero degree calorimeter at the cooling storage ring external-target experiment
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作者 Li-Ke Liu Hua Pei +3 位作者 Ya-Ping Wang biao zhang Nu Xu Shu-Su Shi 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第7期113-121,共9页
The Cooling Storage Ring external-target experiment(CEE)spectrometer is used to study the nuclear matter created in heavy-ion collisions at√sNN=2.1-2.4 GeV with the aim to reveal the quantum chromodynamics phase stru... The Cooling Storage Ring external-target experiment(CEE)spectrometer is used to study the nuclear matter created in heavy-ion collisions at√sNN=2.1-2.4 GeV with the aim to reveal the quantum chromodynamics phase structure in the high-baryon-density region.Collective flow is considered an effective probe for evaluating the properties of media during high-energy nuclear collisions.One of the main functions of the zero-degree calorimeter(ZDC),a subdetector system in the CEE,is to determine the reaction plane in heavy-ion collisions.This step is crucial for measuring the collective flow and other reaction-plane-related analyses.In this paper,we illustrate the procedures for event plane determination using the ZDC.Finally,isospin-dependent quantum molecular dynamics model-based predictions of the rapidity dependence of the directed and elliptical flows for p,d,t,3He,and 4He,produced in 2.1 GeV U+U collisions,are presented. 展开更多
关键词 QCD phase structure Heavy-ion collisions Collective flow Reaction plane Zero-degree calorimeter
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Classifier for centrality determination with zero-degree calorimeter at the cooling-storage-ring external-target experiment
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作者 biao zhang Li‑Ke Liu +3 位作者 Hua Pei Shu‑Su Shi Nu Xu Ya‑Ping Wang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第11期168-173,共6页
The zero-degree calorimeter(ZDC)plays a crucial role toward determining the centrality in the Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou.A boosted decision tree(B... The zero-degree calorimeter(ZDC)plays a crucial role toward determining the centrality in the Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou.A boosted decision tree(BDT)multi-classification algorithm was employed to classify the centrality of the collision events based on the raw features from ZDC such as the number of fired channels and deposited energy.The data from simulated^(238)U+^(238)U collisions at 500 MeV∕u,generated by the IQMD event generator and subsequently modeled using the GEANT4 package,were employed to train and test the BDT model.The results showed the high accuracy of the multi-classification model adopted in ZDC for centrality determination,which is robust against variations in different factors of detector geometry and response.This study demon-strates the good performance of CEE-ZDC in determining the centrality in nucleus-nucleus collisions. 展开更多
关键词 ZDC Boosted decision trees MULTI-CLASSIFICATION IQMD Centrality determination
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High‑Performance Silicon‑Rich Microparticle Anodes for Lithium‑Ion Batteries Enabled by Internal Stress Mitigation
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作者 Yao Gao Lei Fan +3 位作者 Rui Zhou Xiaoqiong Du Zengbao Jiao biao zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第12期99-114,共16页
Si is a promising anode material for Li ion batteries because of its high specific capacity,abundant reserve,and low cost.However,its rate performance and cycling stability are poor due to the severe particle pulveriz... Si is a promising anode material for Li ion batteries because of its high specific capacity,abundant reserve,and low cost.However,its rate performance and cycling stability are poor due to the severe particle pulverization during the lithiation/delithiation process.The high stress induced by the Li concentration gradient and anisotropic deformation is the main reason for the fracture of Si particles.Here we present a new stress mitigation strategy by uniformly distributing small amounts of Sn and Sb in Si micron-sized particles,which reduces the Li concentration gradient and realizes an isotropic lithiation/delithiation process.The Si8.5Sn0.5Sb microparticles(mean particle size:8.22μm)show over 6000-fold and tenfold improvements in electronic conductivity and Li diffusivity than Si particles,respectively.The discharge capacities of the Si_(8.5)Sn_(0.5)Sb microparticle anode after 100 cycles at 1.0 and 3.0 A g^(-1)are 1.62 and 1.19 Ah g^(-1),respectively,corresponding to a retention rate of 94.2%and 99.6%,respectively,relative to the capacity of the first cycle after activation.Multicomponent microparticle anodes containing Si,Sn,Sb,Ge and Ag prepared using the same method yields an ultra-low capacity decay rate of 0.02%per cycle for 1000 cycles at 1 A g^(-1),corroborating the proposed mechanism.The stress regulation mechanism enabled by the industry-compatible fabrication methods opens up enormous opportunities for low-cost and high-energy-density Li-ion batteries. 展开更多
关键词 Silicon anodes Silicon microparticles Lithium-ion batteries Internal stress
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Bushen Yizhi Formula regulates the IRE1αpathway to alleviate endoplasmic reticulum stress in an Alzheimer’s disease rat model
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作者 XIRU XU YUAN FANG +5 位作者 biao zhang SHICHAO TENG XIANG WU JING zhang XIAOQUN GU MEIXIA MA 《BIOCELL》 SCIE 2023年第7期1595-1609,共15页
While the Bushen Yizhi Formula can treat Alzheimer’s disease(AD),the yet to be ascertained specific mechanism of action was explored in this work.Methods:Different concentrations of the Bushen Yizhi Formula and amylo... While the Bushen Yizhi Formula can treat Alzheimer’s disease(AD),the yet to be ascertained specific mechanism of action was explored in this work.Methods:Different concentrations of the Bushen Yizhi Formula and amyloid-beta peptide(Aβ)were used to treat rat pheochromocytoma cells(P12)and human neuroblastoma cells(SH-SY5Y).Cell morphological changes were observed to determine the in vitro cell damage.Cell Counting Kit(CCK)-8 assay and flow cytometry were employed to identify cell viability and apoptosis/cell cycle,respectively.Western blotting and immunohistochemistry were employed to measure the expressions of endoplasmic reticulum stress(ERS)-related proteins(GRP78 and CHOP),p-IRE1α,IRE1α,ASK1,p-JNK,JNK,Bax,Bcl-2,XBP-1,and Bim.Fura 2-acetoxymethyl ester(Fura-2/AM)was used to determine the intracellular calcium(Ca^(2+))concentration.Also,an AD model was constructed by injecting Aβinto the CA1 area of the hippocampus in Sprague Dawley rats.AD model rats were gavaged with different concentrations of Bushen Yizhi Formula for 14 consecutive days.The Morris water maze experiment was conducted to test the learning and memory of rats.Hematoxylin&Eosin(H&E)and Terminal-deoxynucleotidyl Transferase(TdT)-mediated dUTP Nick-End Labeling(TUNEL)staining were done to determine histopathological changes in the brain.Results:Bushen Yizhi Formula relieved the Aβ-induced effects including cell injury,decreased viability,increased apoptosis,G0/G1 phase cell cycle arrest,upregulation of GRP78,CHOP,p-IRE1α,p-JNK,Bax,XBP-1 and Bim,as well as down-regulation of Bcl-2.These results were also seen with IRE1αsilencing.While Aβsuppressed the learning and memory abilities of rats,the Bushen Yizhi Formula alleviated these effects of Aβ.Brain nerve cell injury induced by Aβcould also be treated with Bushen Yizhi Formula.Conclusion:Bushen Yizhi Formula could influence ERS through the IRE1αsignaling pathway to achieve its therapeutic effects on AD. 展开更多
关键词 Bushen Yizhi Formula Alzheimer’s disease Endoplasmic reticulum stress IRE1α
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Nomogram for predicting early complications after distal gastrectomy
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作者 biao zhang Qing Zhu Zhi-Peng Ji 《World Journal of Gastrointestinal Surgery》 SCIE 2023年第11期2500-2512,共13页
BACKGROUND Reducing or preventing postoperative morbidity in patients with gastric cancer(GC)is particularly important in perioperative treatment plans.AIM To identify risk factors for early postoperative complication... BACKGROUND Reducing or preventing postoperative morbidity in patients with gastric cancer(GC)is particularly important in perioperative treatment plans.AIM To identify risk factors for early postoperative complications of GC post-distal gastrectomy and to establish a nomogram prediction model.METHODS This retrospective study included 131 patients with GC who underwent distal gastrectomy at the Second Hospital of Shandong University between January 2019 and February 2023.The factors influencing the development of complications after distal gastrectomy in these patients were evaluated using univariate and multivariate logistic regression analysis.Based on the results obtained,a predictive nomogram was established.The nomogram was validated using internal and external(n=45)datasets.Its sensitivity and specificity were established by receiver operating characteristic curve analysis.Decision curve(DCA)analysis was used to determine its clinical benefit and ten-fold overfitting was used to establish its accuracy and stability.RESULTS Multivariate logistic regression analysis showed that hypertension,diabetes,history of abdominal surgery,and perioperative blood transfusion were independent predictors of postoperative complications of distal gastrectomy.The modeling and validation sets showed that the area under the curve was 0.843[95%confidence interval(CI):0.746-0.940]and 0.877(95%CI:0.719-1.000),the sensitivity was 0.762 and 0.778,respectively,and the specificity was 0.809 and 0.944,respectively,indicating that the model had good sensitivity and specificity.The C-indexes of the modeling and validation datasets were 0.843(95%CI:0.746-0.940)and 0.877(95%CI:0.719-1.000),respectively.The calibration curve(Hosmer Lemeshow test:χ^(2)=7.33)showed that the model had good consistency.The results of the DCA analysis indicated that this model offered good clinical benefits.The accuracy of 10-fold cross-validation was 0.878,indicating that the model had good accuracy and stability.CONCLUSION The nomogram prediction model based on independent risk factors related to postoperative complications of distal gastrectomy can facilitate perioperative intervention for high-risk populations and reduce the incidence of postoperative complications. 展开更多
关键词 Blood transfusion GASTROENTEROSTOMY NOMOGRAMS Postoperative complications Stomach neoplasms Risk factors
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光固化3D打印教学实验设计与研究
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作者 张彪 刘福康 +1 位作者 毛志杰 徐溢 《大学化学》 CAS 2023年第5期163-171,共9页
光固化3D打印技术作为目前较为成熟的一类增材制造技术,在打印成型过程中包括三维建模、光敏树脂制备、打印参数调控、后处理等步骤,内容涉及机械、光学、高分子化学、软件工程学等相关知识。为提升本科生的实验兴趣和实验技能,进一步... 光固化3D打印技术作为目前较为成熟的一类增材制造技术,在打印成型过程中包括三维建模、光敏树脂制备、打印参数调控、后处理等步骤,内容涉及机械、光学、高分子化学、软件工程学等相关知识。为提升本科生的实验兴趣和实验技能,进一步培养其科研和创新意识,我们面向本科生设计了基于光固化3D打印技术的创新实验。实验采用基于光引发自由基聚合的数字光处理(DLP)3D打印技术,通过对打印过程全流程的参与实践,达到让学生了解3D打印的原理、打印材料的合成和打印技术的过程等相关知识,从而达到可以自主操作完成光固化3D打印的实验教学目的。最后,通过对实验结果的分析,进一步培养学生分析问题和解决问题的能力。 展开更多
关键词 光固化 自由基聚合 3D打印 数字光处理
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电子喉镜在咽喉部肿物活检中的临床应用及病理分析 被引量:9
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作者 林川耀 陆玲 +3 位作者 张标 张思思 刘丁丁 高下 《中国内镜杂志》 2018年第9期1-6,共6页
目的探讨电子喉镜下对咽喉部肿物活检的临床应用,并分析病理结果。方法回顾性分析声带白斑、喉部肿瘤、下咽部肿瘤3类咽喉部常见肿物的患者资料共199例,均在门诊电子喉镜下表面麻醉后进行组织活检,送病理检查。分析3类病变患者的性别、... 目的探讨电子喉镜下对咽喉部肿物活检的临床应用,并分析病理结果。方法回顾性分析声带白斑、喉部肿瘤、下咽部肿瘤3类咽喉部常见肿物的患者资料共199例,均在门诊电子喉镜下表面麻醉后进行组织活检,送病理检查。分析3类病变患者的性别、年龄分布及病理意义。评价电子喉镜下活检咽喉部肿物的价值和意义。结果 3类病变的男性患者均明显多于女性,声带白斑患者年龄段分布明显比喉部和下咽部肿瘤患者年轻化(P<0.05)。67例声带白斑病理:慢性炎伴鳞状上皮增生35例(52.24%),低度上皮内瘤变17例(25.37%),高度上皮内瘤变12例(17.91%),可疑浸润癌2例(2.99%),浸润癌1例(1.49%)。97例喉部肿瘤病理:高度上皮内瘤变/原位癌35例(36.08%),可疑浸润癌14例(14.43%),浸润癌48例(49.48%)。35例下咽部肿瘤病理:高度上皮内瘤变/原位癌6例(17.14%,),可疑浸润癌4例(11.43%),浸润癌25例(71.43%)。结论电子喉镜下表面麻醉活检咽喉部肿物,麻醉风险低,操作灵活,明显减少了患者经济成本,为后续治疗提供了病理学依据,是方便、快捷、有效的活检方法。 展开更多
关键词 电子喉镜 声带白斑 咽喉部肿瘤 活检 病理
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食管癌组织中VEGF-C表达量与淋巴管新生及肿瘤组织生长的相关性 被引量:6
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作者 李永辉 李婷婷 +4 位作者 郭强 王瑞尧 张标 刘芳 王坤 《中国现代医学杂志》 CAS 2018年第22期44-48,共5页
目的研究食管癌组织中血管内皮生长因子C(VEGF-C)表达量与淋巴管新生、肿瘤组织生长的相关性。方法选取2012年4月-2015年10月在河北大学附属医院手术切除的食管癌组织作为临床标本,采用免疫组织化学试剂盒对食管癌组织中VEGF-C、D2-40... 目的研究食管癌组织中血管内皮生长因子C(VEGF-C)表达量与淋巴管新生、肿瘤组织生长的相关性。方法选取2012年4月-2015年10月在河北大学附属医院手术切除的食管癌组织作为临床标本,采用免疫组织化学试剂盒对食管癌组织中VEGF-C、D2-40进行染色,判读VEGF-C的阳性表达率以及D2-40阳性表达的淋巴管密度(LVD);采用荧光定量聚合酶联反应试剂盒测定Ki-67、Cyclin B1的mRNA含量。结果低未分化、TNMⅢ、Ⅳ、有淋巴结转移的食管癌组织中VEGF-C阳性率、LVD以及Ki-67、Cyclin B1的mRNA含量均高于中高分化、TNMⅠ、Ⅱ期、无淋巴结转移的食管癌组织;VEGF-C阳性表达的食管癌组织中LVD以及Ki-67、Cyclin B1的mRNA含量均高于VEGF-C阴性表达的食管癌组织。结论食管癌组织中高表达的VEGF-C与淋巴管新生以及肿瘤组织生长密切相关。 展开更多
关键词 食管癌 血管内皮生长因子C 淋巴管新生 增殖
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Application of Solution-Focused Approach in Nursing Care of Advanced Schistosomiasis
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作者 Ning Li Yuhong Zhao +2 位作者 Meiling Qi biao zhang Zhimei Wang 《Journal of Clinical and Nursing Research》 2023年第5期55-60,共6页
Objective:To analyze the effect of solution-focused approach on advanced schistosomiasis(AS).Methods:10 cases of patients with AS that were treated with a solution-focused approach were included in our study.The indic... Objective:To analyze the effect of solution-focused approach on advanced schistosomiasis(AS).Methods:10 cases of patients with AS that were treated with a solution-focused approach were included in our study.The indicators before and after the intervention were measured(knowledge mastery,prevention and treatment compliance,personal behavior,self-care ability,management satisfaction,complication rate).Results:After analyzing pre-and post-intervention indicators,statistical significance was found(P<0.05).The intervention received a satisfaction rate of 80.00%,with a complication rate of 10.00%.Conclusion:Using a solution-focused approach for ankylosing spondylitis(AS)patients can enhance their understanding and attitude toward disease prevention and treatment,improve their behaviors and self-care ability,resulting in high satisfaction and reduced complications. 展开更多
关键词 Solution-focused approach Advanced schistosomiasis Knowledge mastery Prevention and treatment attitude
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通过调整润湿性开发具有高抗损伤性能的仿珍珠贝壳层状2024Al/B4C复合材料 被引量:1
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作者 汪洋 刘强 +7 位作者 张标 张浩谦 金义程 钟兆新 叶健 任宇涵 叶枫 王文 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第4期1105-1118,共14页
为了解决复合材料中B_(4)C陶瓷相难以被金属铝润湿的问题,利用TiH_(2)和B_(4)C的原位反应引入TiB_(2),进而调节其润湿性和界面结合。通过将熔融合金压力浸渗到冷冻铸造法制备的多孔陶瓷支架中,制备具有层状结构的2024Al/B4C-TiB_(2)复... 为了解决复合材料中B_(4)C陶瓷相难以被金属铝润湿的问题,利用TiH_(2)和B_(4)C的原位反应引入TiB_(2),进而调节其润湿性和界面结合。通过将熔融合金压力浸渗到冷冻铸造法制备的多孔陶瓷支架中,制备具有层状结构的2024Al/B4C-TiB_(2)复合材料。与2024Al/B_(4)C复合材料相比,加入TiH_(2)后复合材料的抗弯强度和裂纹扩展韧性分别由(484±27)MPa提高到(665±30)MPa和由(19.3±1.5)MPa·m^(1/2)提高到(32.7±1.8)MPa·m^(1/2)。这种优异的抗损伤能力来自于多重外在增韧机制,包括未开裂韧带的桥接、裂纹分叉、裂纹扩展和裂纹钝化,更重要的是,断裂模式从单一裂纹扩展转变为多裂纹扩展。这一策略为改善Al/B_(4)C复合材料的润湿性和界面黏结性开辟了一条道路,从而生产出具有优良耐损伤性能的仿珍珠贝壳状材料。 展开更多
关键词 生物启发复合材料 冷冻铸造 氢化钛 力学性能 耐损伤性
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An improved artificial bee colony algorithm for steelmaking–refining–continuous casting scheduling problem 被引量:11
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作者 Kunkun Peng Quanke Pan biao zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第8期1727-1735,共9页
Steelmaking–refining–Continuous Casting(SCC) scheduling is a worldwide problem, which is NP-hard. Effective SCC scheduling algorithms can help to enhance productivity, and thus make significant monetary savings. Thi... Steelmaking–refining–Continuous Casting(SCC) scheduling is a worldwide problem, which is NP-hard. Effective SCC scheduling algorithms can help to enhance productivity, and thus make significant monetary savings. This paper develops an Improved Artificial Bee Colony(IABC) algorithm for the SCC scheduling. In the proposed IABC, charge permutation is employed to represent the solutions. In the population initialization, several solutions with certain quality are produced by a heuristic while others are generated randomly. Two variable neighborhood search neighborhood operators are devised to generate new high-quality solutions for the employed bee and onlooker bee phases, respectively. Meanwhile, in order to enhance the exploitation ability, a control parameter is introduced to conduct the search of onlooker bee phase. Moreover, to enhance the exploration ability,the new generated solutions are accepted with a control acceptance criterion. In the scout bee phase, the solution corresponding to a scout bee is updated by performing three swap operators and three insert operators with equal probability. Computational comparisons against several recent algorithms and a state-of-the-art SCC scheduling algorithm have demonstrated the strength and superiority of the IABC. 展开更多
关键词 殖民地 蜜蜂 算法 精制 人工 高生产率 控制参数 SCC
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高稳定性的氮掺杂氧化钽光催化甲醇C-H活化和直接C-C偶联制乙二醇
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作者 王力梅 杜大学 +4 位作者 张彪 谢顺吉 张庆红 王海燕 王野 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第9期1459-1467,共9页
乙二醇是非常重要的基础化学品,不仅可以作为合成聚合物(如聚对苯二甲酸乙二醇酯)的重要单体,也可以用作防冻剂和燃料添加剂等,具有广泛的用途.乙二醇的年产量超过2500万吨,目前主要的工业合成路线是由石油衍生的乙烯通过环氧化制环氧乙... 乙二醇是非常重要的基础化学品,不仅可以作为合成聚合物(如聚对苯二甲酸乙二醇酯)的重要单体,也可以用作防冻剂和燃料添加剂等,具有广泛的用途.乙二醇的年产量超过2500万吨,目前主要的工业合成路线是由石油衍生的乙烯通过环氧化制环氧乙烷,环氧乙烷再水解制乙二醇.甲醇是一种清洁的平台化合物,不仅可以由天然气和煤炭通过传统的合成气过程生产,也可以由生物质和CO_(2)直接合成.直接以甲醇为原料是合成乙二醇的理想过程,但目前热催化还未实现该过程.通过太阳能驱动的C−H活化和C−C偶联过程,可以实现甲醇直接偶联制乙二醇的理想反应过程.光催化甲醇制乙二醇可以在十分温和的条件下进行,目前已报道的甲醇制乙二醇光催化剂均为硫化物半导体材料,如CdS,ZnS和Zn_(2)In_(2)S_(5),但硫化物存在的光腐蚀和毒性等问题迫使我们去发展一种更加稳定和环境友好的光催化剂.氧化物基半导体材料,如Ta_(2)O_(5),TiO2,ZnO和WO_(3)等,是一类相对硫化物半导体材料更加稳定的光催化材料,然而目前还没有氧化物基半导体光催化剂用于光催化甲醇制乙二醇的报道.本文率先将金属氧化物光催化剂Ta_(2)O_(5),用于甲醇制乙二醇的光催化反应,实现了乙二醇的选择性合成.在单纯的Ta_(2)O_(5)催化剂上,乙二醇选择性可达73%.Ta_(2)O_(5)十分独特,可以实现甲醇的光催化C−C偶联制乙二醇,而其他金属氧化物光催化剂(如TiO2,ZnO,WO_(3)和Nb_(2)O_(5))光催化转化甲醇只生成甲醛和甲酸等C1产物.进一步通过简单、方便的氨气焙烧法,制备了一系列不同氮掺杂量的氧化钽(N-Ta_(2)O_(5))催化剂.在未经助催化剂修饰的氮含量为2.3%的2%N-Ta_(2)O_(5)光催化剂上,乙二醇选择性为71%,生成速率可达4.0 mmol g_(cat)^(−1)h^(−1),约为Ta_(2)O_(5)的9倍,同时显著高于已报道的未经助催化剂修饰的CdS催化剂性能.通过光电流、表面光电压谱和理论计算等方法系统地研究了氮掺杂氧化钽具有高的光催化甲醇制乙二醇性能的重要原因,发现氮掺杂氧化钽高的电荷分离能力是决定其具有高活性的关键因素.另一方面,氮掺杂氧化钽表现出了非常高的反应稳定性,在超过160 h的循环测试过程中,乙二醇的生成速率基本保持不变,这是目前已报道的金属硫化物光催化剂所未能实现的.在长达60 h的反应过程中,未经助催化剂修饰的2%N-Ta_(2)O_(5)催化剂上乙二醇生成量基本随时间线性增长,收率可达3.6%.进一步研究发现,钽基半导体材料(Ta_(2)O_(5)和N-Ta_(2)O_(5))可以在保持甲醇羟基不变的情况下优先活化甲醇C−H键,生成羟甲基自由基(•CH_(2)OH),随后羟甲基自由基经C−C偶联生成乙二醇.钽基半导体光催化剂是一种环境友好且十分稳定的甲醇光催化偶联制乙二醇的优异催化剂,未来基于该类催化剂不仅有希望发展出更加高效、稳定的甲醇制乙二醇光催化剂,还有希望为更广的羟基存在下的C−H键选择性活化反应过程设计高效稳定的催化剂提供借鉴和指导. 展开更多
关键词 甲醇 C−H活化 C−C偶联 乙二醇 钽基光催化剂
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Prediction of chlorophyll a concentration using HJ-1 satellite imagery for Xiangxi Bay in Three Gorges Reservoir 被引量:6
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作者 Dong-xing FAN Yu-ling HUANG +3 位作者 Lin-xu SONG De-fu LIU Ge zhang biao zhang 《Water Science and Engineering》 EI CAS CSCD 2014年第1期70-80,共11页
Since the impoundment of the Three Gorges Reservoir in 2003,algal blooms have frequently been observed in it.The chlorophyll a concentration is an important parameter for evaluating algal blooms.In this study,the chlo... Since the impoundment of the Three Gorges Reservoir in 2003,algal blooms have frequently been observed in it.The chlorophyll a concentration is an important parameter for evaluating algal blooms.In this study,the chlorophyll a concentration in Xiangxi Bay,in the Three Gorges Reservoir,was predicted using HJ-1 satellite imagery.Several models were established based on a correlation analysis between in situ measurements of the chlorophyll a concentration and the values obtained from satellite images of the study area from January 2010 to December 2011.Chlorophyll a concentrations in Xiangxi Bay were predicted based on the established models.The results show that the maximum correlation is between the reflectance of the band combination of B4/(B2+B3) and in situ measurements of chlorophyll a concentration.The root mean square errors of the predicted values using the linear and quadratic models are 18.49 mg/m3 and 18.52 mg/m3,respectively,and the average relative errors are 37.79% and 36.79%,respectively.The results provide a reference for water bloom prediction in typical tributaries of the Three Gorges Reservoir and contribute to large-scale remote sensing monitoring and water quality management. 展开更多
关键词 叶绿素A浓度 三峡库区 卫星图像 预测值 香溪河 库湾 平均相对误差 二次模型
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Investigation and optimization of sampling characteristics of light field camera for flame temperature measurement 被引量:4
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作者 刘煜东 Md.Moinul Hossain +2 位作者 孙俊 张彪 许传龙 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第3期202-217,共16页
It is essential to investigate the light field camera parameters for the accurate flame temperature measurement because the sampling characteristics of the flame radiation can be varied with them. In this study, novel... It is essential to investigate the light field camera parameters for the accurate flame temperature measurement because the sampling characteristics of the flame radiation can be varied with them. In this study, novel indices of the light field camera were proposed to investigate the directional and spatial sampling characteristics of the flame radiation. Effects of light field camera parameters such as focal length and magnification of the main lens, focal length and magnification of the microlens were investigated. It was observed that the sampling characteristics of the flame are varied with the different parameters of the light field camera. The optimized parameters of the light field camera were then proposed for the flame radiation sampling. The larger sampling angle(23 times larger) is achieved by the optimized parameters compared to the commercial light field camera parameters. A non-negative least square(NNLS) algorithm was used to reconstruct the flame temperature. The reconstruction accuracy was also evaluated by the optimized parameters. The results suggested that the optimized parameters can provide higher reconstruction accuracy for axisymmetric and non-symmetric flame conditions in comparison to the commercial light field camera. 展开更多
关键词 LIGHT field CAMERA FLAME RADIATION sampling PARAMETER optimization temperature RECONSTRUCTION
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Hard carbon derived from coconut shells,walnut shells,and corn silk biomass waste exhibiting high capacity for Na-ion batteries 被引量:4
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作者 Cristina Nita biao zhang +1 位作者 Joseph Dentzer Camélia Matei Ghimbeu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第7期207-218,共12页
In recent years,hard carbon materials have gained significant interest as anode materials for Na-ion batteries.Biomass waste is considered one of the most interesting,renewable,available,and cost-effective precursor t... In recent years,hard carbon materials have gained significant interest as anode materials for Na-ion batteries.Biomass waste is considered one of the most interesting,renewable,available,and cost-effective precursor to obtain hard carbon(HC);however,HC properties must be finely tuned to achieve performance comparable to those provided by Li-ion batteries.In this work,three biomass wastes(coconut shells,walnut shells,and corn silk) were evaluated as potential precursors for HC preparation involving a pyrolysis process and subsequent acid washing to remove the inorganic impurities.All obtained materials exhibited low and similar specific surface areas(<10 m^(2)·g^(-1)), but they presented different structures and surface functionalities.The walnut shell HC possessed a lower amount of inorganic impurities and oxygen-based functional groups compared to the coconut shell and corn silk HCs,leading to higher initial coulombic efficiency(iCE).The structural organization was higher in the case of the walnut shell HC,while the corn silk HC revealed a heterogeneous structure combining both highly disordered carbon and localized graphitized domains.All HCs delivered high initial reversible capacities between 293 and 315 mAh g^(-1) at 50 mA g^(-1) current rate,which remained rather stable during long-term cycling.The best capacity(293 mAh g^(-1) after 100 charge/discharge cycles) and highest capacity retention(93%) was achieved in walnut HCs in half-cells,which could be associated with its higher sp2 C content,better organized structure,and fewer impurities.An "adsorption-insertion" Na storage mechanism is suggested based on several techniques.The walnut HCs exhibited an attractive energy density of 279 Wh/kg when tested in full cells. 展开更多
关键词 BIOMASS PYROLYSIS Hard carbon ANODE Na-ion batteries Energy storage
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高压下富含晶界的铋纳米片高效电还原CO_(2)制甲酸盐
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作者 阮孙红 张彪 +6 位作者 邹金含 钟万福 何潇洋 卢进海 张庆红 王野 谢顺吉 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第12期3161-3169,共9页
可再生能源驱动的电催化还原CO_(2)制化学品和燃料是实现碳中和目标十分具有吸引力的技术.在电催化还原CO_(2)产物中,综合考虑产物的经济价值和还原所需能量,甲酸是最可行的产物之一.甲酸用途十分广泛,不仅可以用于生产各种高值化学品,... 可再生能源驱动的电催化还原CO_(2)制化学品和燃料是实现碳中和目标十分具有吸引力的技术.在电催化还原CO_(2)产物中,综合考虑产物的经济价值和还原所需能量,甲酸是最可行的产物之一.甲酸用途十分广泛,不仅可以用于生产各种高值化学品,还可作为氢的载体用于燃料电池.目前发展的电催化还原CO_(2)制甲酸或甲酸盐的催化剂主要有Pd,Cd,Hg,Sn,In,Tl,Pb和Bi等,其中Bi基催化剂具有价廉、环境友好和选择性高等特点.此外,电解器的结构也是影响反应性能的关键因素.传统的常压H池中,由于CO_(2)溶解度低和扩散限制,反应电流密度很难超过100 mA cm^(−2).流动池和膜电极反应器体系由于使用气体扩散电极,可以避免CO_(2)溶解度低的问题,获得较高的反应电流密度,但依然存在反应器结构复杂难控等问题.高压H池操控简单,而且可以使大量的CO_(2)溶解于溶液中,已有研究证明在高压H池中可以获得超过100 mA cm^(−2)的反应电流密度.同时,有研究发现,CO_(2)的压力会显著影响铜基催化剂上产物的选择性.然而,目前对高压H池中电催化还原CO_(2)的研究较少.因此,进一步设计高压条件下电催化还原CO_(2)制甲酸的高效催化剂,并研究其独特规律,具有重要意义.本文通过简单的一步水热方法合成了BiPO_(4)纳米多面体,并在高压H池中系统研究了其电催化还原CO_(2)制甲酸盐的性能.实验发现,BiPO_(4)纳米多面体衍生的催化剂(BiPO_(4)-derived)在高压H池中具有很高的活性.在CO_(2)压力为3.0 MPa的KHCO_(3)溶液中,控制阴极电位为−0.81 V vs.RHE,电催化还原CO_(2)制甲酸盐的法拉第效率为90%,甲酸盐部分电流密度可达534 mA cm^(−2),甲酸盐生成速率为9.9 mmol h^(−1) cm^(−2).X射线衍射、扫描电子显微镜、高分辨透射电子显微镜、循环伏安等表征结果表明,BiPO_(4)纳米多面体在高压CO_(2)还原反应条件下会演变成具有丰富晶界的金属铋纳米片;而在常压或低压条件下,BiPO_(4)纳米多面体演变生成的金属铋纳米片则几乎没有晶界.对比发现,丰富晶界的BiPO_(4)-derived催化剂具有更高的电催化还原CO_(2)制甲酸盐的活性和选择性.理论计算结果表明,在金属铋的晶界表面,电荷分布会发生明显变化,从而显著促进CO_(2)的活化以及反应中间HCOO^(*)的稳定性,使得电催化还原CO_(2)制甲酸的反应路径从能量上看更加有利,从而提高了反应的选择性和活性.本文展示了在高压H池中,BiPO_(4)纳米多面体在高压下衍生的催化剂在电催化还原CO_(2)制甲酸盐反应中具有较好的活性和选择性.研究发现,在高压CO_(2)还原条件下,催化剂前驱体可以衍生成具有丰富晶界的高活性催化剂,是一种构筑高效催化剂的方法.综上,本文将为电催化还原CO_(2)领域,尤其是面向CO_(2)工业应用的高效催化剂设计制备提供一些有用的参考. 展开更多
关键词 电催化还原CO_(2) 甲酸盐 高压H池 铋纳米片 晶界
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Forest soil conservation based on eco-service provision unit method and its value in Anji County,Huzhou,Zhejiang,China 被引量:2
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作者 biao zhang Ji-xi Gao +1 位作者 Gao-di Xie Chun-xia Lu 《Journal of Forestry Research》 SCIE CAS CSCD 2015年第2期405-415,共11页
We propose an eco-service provision unit method for estimating the benefit and spatial differences of forests in controlling soil erosion.A total of 197 eco-service provision units were grouped on 1424.43 km2 of fores... We propose an eco-service provision unit method for estimating the benefit and spatial differences of forests in controlling soil erosion.A total of 197 eco-service provision units were grouped on 1424.43 km2 of forest according to differences in vegetation,slope,soil,and rainfall.The amount of soil conservation and its economic value were estimated.The forests in Anji County prevent4.08 9 105 tons of soil from eroding annually,thereby avoiding 1.36 9 104 tons of nutrient loss(on-site cost) and preventing 149 tons of nutritive elements from entering water systems(off-site cost).From an economic perspective,the soil nutrient conservation in the forests of Anji County generated an annual benefit of 43.37 million RMB(Chinese Currency,6.20 RMB = US$1).On average,each hectare of ecological forest contributed up to 436 RMB annually because of soil conservation.Ecological complexes with higher rainfall intensity,such as broadleaf forest and red soil on slope gradients [25°,contributed the highest soil conservation benefits.This study identified and quantified the dominant contributors and magnitudes of soil conservation provided by forests.This information can benefit decision making regarding differentiated ecological compensation policies. 展开更多
关键词 森林水土保持 生态服务 经济价值 安吉县 单位 中国 土壤侵蚀 湖州
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Robust model-reference control for descriptor linear systems subject to parameter uncertainties 被引量:1
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作者 Guangren DUAN biao zhang 《控制理论与应用(英文版)》 EI 2007年第3期213-220,共8页
Robust model-reference control for descriptor linear systems with structural parameter uncertainties is investigated. A sufficient condition for existing a model-reference zero-error asymptotic tracking controller is ... Robust model-reference control for descriptor linear systems with structural parameter uncertainties is investigated. A sufficient condition for existing a model-reference zero-error asymptotic tracking controller is given. It is shown that the robust model reference control problem can be decomposed into two subproblems: a robust state feedback stabilization problem for descriptor systems subject to parameter uncertainties and a robust compensation problem. The latter aims to find three coefficient matrices which satisfy four matrix equations and simultaneously minimize the effect of the uncertainties to the tracking error. Based on a complete parametric solution to a class of generalized Sylvester matrix equations, the robust compensation problem is converted into a minimization problem with quadratic cost and linear constraints. A numerical example shows the effect of the proposed approach. 展开更多
关键词 线性系统 鲁棒控制 参考模型 参数不确定 鲁棒稳定性
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