随着GOA(Gate On Array)技术的不断发展,在小尺寸TFT-LCD窄边框显示屏上的应用也越来越频繁,但是由于GOA电路的复杂性和TFT器件自身的稳定性,以及外界温度、湿度的影响,显示屏还存在显示不稳定的问题。本文针对小尺寸TFT-LCD GOA显示屏...随着GOA(Gate On Array)技术的不断发展,在小尺寸TFT-LCD窄边框显示屏上的应用也越来越频繁,但是由于GOA电路的复杂性和TFT器件自身的稳定性,以及外界温度、湿度的影响,显示屏还存在显示不稳定的问题。本文针对小尺寸TFT-LCD GOA显示屏在高温高湿环境下产生的异常显示横纹,进行了深入分析与改善研究。通过对GOA区域ITO过孔电阻测试、显微镜检查以及修复实验验证,找出了不良产生的直接原因为ITO发生腐蚀,过孔电阻增大,导致GOA驱动信号无法上下导通。接着进一步研究ITO腐蚀发生的条件、ITO腐蚀情况、驱动信号对应关系以及腐蚀成分,证明了ITO发生腐蚀原因为产品长期工作(200h左右)在高温高湿环境下,由于水汽的不断渗入,使GOA区域ITO发生了电化学腐蚀效应。最后根据电化学腐蚀原理,通过采用隔水性强的封框胶、增加ITO膜厚以及降低ITO电位差等措施对工艺进行了改善,结果表明改善后的显示屏超过1 000h,未发生ITO腐蚀。展开更多
The effects of axial ligand on the oxygen atom transfer(OAT)reaction from 5,10,15-tris(pentafluorophenyl)corrole((tpfc)MnVO)to dimethyl sulfide(DMS)have been investigated by density functional theory(DFT)calculations....The effects of axial ligand on the oxygen atom transfer(OAT)reaction from 5,10,15-tris(pentafluorophenyl)corrole((tpfc)MnVO)to dimethyl sulfide(DMS)have been investigated by density functional theory(DFT)calculations.Imidazole(Im),4-methylimidazole(4-MI)and pyridine(Py)were selected as the axial ligands.The results revealed that the axial ligand can form coordinate bond with(tpfc)MnVO in the transition state(TS)of the OAT reaction.The axial coordination favored charge transferring from(tpfc)MnVO to DMS,and weakened the Mn≡O bond in both singlet and triplet states.Furthermore,axial coordination can reduce the energy barrier of neutral(tpfc)MnVO from 23.62 kJ·mol^-1 to less than 3 kJ·mol^-1 in the triplet state,which is significantly lower than in the singlet state.This makes(tpfc)MnVO tend to direct the OAT reaction via triplet state pathway.On the other hand,the energy barriers of[(tpfc)MnVIO]+species from disproportionation pathway increased from 1.26 to 33.95 kJ·mol^-1 in a doublet state.This suggests axial ligands were conducive for direct(tpfc)MnVO OAT reaction pathway.展开更多
文摘随着GOA(Gate On Array)技术的不断发展,在小尺寸TFT-LCD窄边框显示屏上的应用也越来越频繁,但是由于GOA电路的复杂性和TFT器件自身的稳定性,以及外界温度、湿度的影响,显示屏还存在显示不稳定的问题。本文针对小尺寸TFT-LCD GOA显示屏在高温高湿环境下产生的异常显示横纹,进行了深入分析与改善研究。通过对GOA区域ITO过孔电阻测试、显微镜检查以及修复实验验证,找出了不良产生的直接原因为ITO发生腐蚀,过孔电阻增大,导致GOA驱动信号无法上下导通。接着进一步研究ITO腐蚀发生的条件、ITO腐蚀情况、驱动信号对应关系以及腐蚀成分,证明了ITO发生腐蚀原因为产品长期工作(200h左右)在高温高湿环境下,由于水汽的不断渗入,使GOA区域ITO发生了电化学腐蚀效应。最后根据电化学腐蚀原理,通过采用隔水性强的封框胶、增加ITO膜厚以及降低ITO电位差等措施对工艺进行了改善,结果表明改善后的显示屏超过1 000h,未发生ITO腐蚀。
基金supported by the National Natural Science Foundation of China(21275057,21671068)Natural Science Foundation of Guangdong Province(S2012010008763,2017A050506048)
文摘The effects of axial ligand on the oxygen atom transfer(OAT)reaction from 5,10,15-tris(pentafluorophenyl)corrole((tpfc)MnVO)to dimethyl sulfide(DMS)have been investigated by density functional theory(DFT)calculations.Imidazole(Im),4-methylimidazole(4-MI)and pyridine(Py)were selected as the axial ligands.The results revealed that the axial ligand can form coordinate bond with(tpfc)MnVO in the transition state(TS)of the OAT reaction.The axial coordination favored charge transferring from(tpfc)MnVO to DMS,and weakened the Mn≡O bond in both singlet and triplet states.Furthermore,axial coordination can reduce the energy barrier of neutral(tpfc)MnVO from 23.62 kJ·mol^-1 to less than 3 kJ·mol^-1 in the triplet state,which is significantly lower than in the singlet state.This makes(tpfc)MnVO tend to direct the OAT reaction via triplet state pathway.On the other hand,the energy barriers of[(tpfc)MnVIO]+species from disproportionation pathway increased from 1.26 to 33.95 kJ·mol^-1 in a doublet state.This suggests axial ligands were conducive for direct(tpfc)MnVO OAT reaction pathway.
