Epitaxial YBCO films were deposited on （100） LaAlO3 single-crystal substrates by metalorganic deposition of metal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and...Epitaxial YBCO films were deposited on （100） LaAlO3 single-crystal substrates by metalorganic deposition of metal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and Jc excess 2 MA/cm^2 at 77 K in zero field. XRD θ-2θscans show all the films have c-axis normal orientation. The FWHM （full width at half-maximum intensity） values of X-ray ω-scans of （005） reflection are 0.379°, 0.283°, and 0.543° for the YBCO thin films deposited with precursor solution concentrations of 1.52, 1.0, and 0.75 mol/L, respectively. With the concentration of the precursors decreasing, the thickness of the films decreases linearly. SEM micrographs show that porosities in the films become bigger with the precursor solution concentration decreasing. The big porosities in the film with the lowest concentration precursor deteriorate the superconducting property and make it have a wider superconducting transition and a lower Jc.展开更多
研究了导电剂种类和导电剂含量对磷酸钒锂电化学性能的影响。以Li_3V_2(PO_4)_3为正极材料,研究了石墨烯、乙炔黑和Super P Li三种导电剂对磷酸钒锂电化学性能的影响。恒电流充放电和电化学阻抗测试结果表明,不同的导电剂对电极的电化...研究了导电剂种类和导电剂含量对磷酸钒锂电化学性能的影响。以Li_3V_2(PO_4)_3为正极材料,研究了石墨烯、乙炔黑和Super P Li三种导电剂对磷酸钒锂电化学性能的影响。恒电流充放电和电化学阻抗测试结果表明,不同的导电剂对电极的电化学性能有显著的影响。以Super P Li为导电剂的磷酸钒锂正极材料表现出最高的放电比容量和最优异的倍率性能,交流阻抗值小。在此基础上探究了Super P Li含量对磷酸钒锂电化学性能的影响,结果表明添加质量分数10%Super P Li的电池具有较小的阻抗和较高的放电比容量、循环性能和倍率性能。展开更多
文摘Epitaxial YBCO films were deposited on （100） LaAlO3 single-crystal substrates by metalorganic deposition of metal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and Jc excess 2 MA/cm^2 at 77 K in zero field. XRD θ-2θscans show all the films have c-axis normal orientation. The FWHM （full width at half-maximum intensity） values of X-ray ω-scans of （005） reflection are 0.379°, 0.283°, and 0.543° for the YBCO thin films deposited with precursor solution concentrations of 1.52, 1.0, and 0.75 mol/L, respectively. With the concentration of the precursors decreasing, the thickness of the films decreases linearly. SEM micrographs show that porosities in the films become bigger with the precursor solution concentration decreasing. The big porosities in the film with the lowest concentration precursor deteriorate the superconducting property and make it have a wider superconducting transition and a lower Jc.
文摘研究了导电剂种类和导电剂含量对磷酸钒锂电化学性能的影响。以Li_3V_2(PO_4)_3为正极材料,研究了石墨烯、乙炔黑和Super P Li三种导电剂对磷酸钒锂电化学性能的影响。恒电流充放电和电化学阻抗测试结果表明,不同的导电剂对电极的电化学性能有显著的影响。以Super P Li为导电剂的磷酸钒锂正极材料表现出最高的放电比容量和最优异的倍率性能,交流阻抗值小。在此基础上探究了Super P Li含量对磷酸钒锂电化学性能的影响,结果表明添加质量分数10%Super P Li的电池具有较小的阻抗和较高的放电比容量、循环性能和倍率性能。
