Sixty-five new vibronic levels of the Na2 4^3∑g^＋ state have been observed in the 33900-35200 cm^-1 energy region above the potential minimum of the ground state by pulsed perturbation facilitated optical-optical do...Sixty-five new vibronic levels of the Na2 4^3∑g^＋ state have been observed in the 33900-35200 cm^-1 energy region above the potential minimum of the ground state by pulsed perturbation facilitated optical-optical double resonance （PFOODR） fluorescence excitation spectroscopy. These new data fill the gap between the low-v levels mainly observed by continuous wave （CW） PFOODR spectroscopy and the high-v levels above the 3s＋3d limit observed by pulsed PFOODR with predissociation detection, Molecular constants are fitted below potential shelf around the 3s＋3d atomic limit with previously published data （mainly observed by CW PFOODR） and these new data. RKR potential curve has been calculated with the new constants. The constants are： Te= 32127.090 cm^-1,ωe=121.4099（0.20720） cm^-1, Be = 0.116287（0.0002300） cm^-1, Re=3.551 A, An error of the RKR potential curve of J. Chem. Phys. 108, 7707 （1998） is corrected.展开更多
基金This work was supported by the National Natural Science Foundation of China（NSFC No. 20473042, N0. 20173029 and 10174042）, NKBRSF, and SRFDP of China and by RFBR（grant 05-03-39012） of Russia.
文摘Sixty-five new vibronic levels of the Na2 4^3∑g^＋ state have been observed in the 33900-35200 cm^-1 energy region above the potential minimum of the ground state by pulsed perturbation facilitated optical-optical double resonance （PFOODR） fluorescence excitation spectroscopy. These new data fill the gap between the low-v levels mainly observed by continuous wave （CW） PFOODR spectroscopy and the high-v levels above the 3s＋3d limit observed by pulsed PFOODR with predissociation detection, Molecular constants are fitted below potential shelf around the 3s＋3d atomic limit with previously published data （mainly observed by CW PFOODR） and these new data. RKR potential curve has been calculated with the new constants. The constants are： Te= 32127.090 cm^-1,ωe=121.4099（0.20720） cm^-1, Be = 0.116287（0.0002300） cm^-1, Re=3.551 A, An error of the RKR potential curve of J. Chem. Phys. 108, 7707 （1998） is corrected.
