In the present study,the Cu-(1 wt%-6 wt%)Ag alloys were prepared by melting,forging and wire drawing.The effects of plastic deformation on microstructure evolution and properties of the alloys were investigated.The re...In the present study,the Cu-(1 wt%-6 wt%)Ag alloys were prepared by melting,forging and wire drawing.The effects of plastic deformation on microstructure evolution and properties of the alloys were investigated.The results show that non-equilibrium eutectic colonies exist in the Cu-(3 wt%-6 wt%)Ag alloy and no eutectic colonies in the 1 wt%-2 wt%Ag containing alloys.These eutectic colonies are aligned along the drawing direction and refined with the increase of draw ratio.Attributed to the refinement of eutectic colonies,the Cu-Ag alloy exhibits higher strength with the increase of draw ratio.The Cu-6Ag alloy exhibits excellent comprehensive properties with a strength of 930 MPa and a conductivity of 82%IACS when the draw ratio reaches 5.7.展开更多
Based on seawater immersion,drying-wetting cycles,carbonation and drying-wetting cycles for coral aggregate sea-water concrete(CASC)with different strength grades,the effect of carbonation and drying-wetting cycles on...Based on seawater immersion,drying-wetting cycles,carbonation and drying-wetting cycles for coral aggregate sea-water concrete(CASC)with different strength grades,the effect of carbonation and drying-wetting cycles on chloride diffusion be-havior of CASC is studied.The results show that the free surface chloride concentration(Cs),free chloride diffusion coefficient(Df)and time-dependent index(m)of CASC in the drying-wetting cycles is obviously higher than that in seawater immersion.The Df and m of CASC of carbonation and drying-wetting cycles is higher than that in the drying-wetting cycles.Carbonation increases the Df and m of CASC,which is against CASC to resist chloride corrosion.The corrosion possibility of CASC structures in different ex-posed areas is as follows:splash zone(carbonation and drying-wetting cycles)>tidal zone(drying-wetting cycles)>underwater zone(seawater immersion).Besides,the chloride diffusion rate of C65-CASC is 17.8%-63.4%higher than that of C65-ordinary aggre-gate concrete(OAC)in seawater immersion(underwater zone).Therefore,anti-corrosion measures should be adopted to improve the service life of CASC structure in the oceanic environment.展开更多
Based on the drying-wetting cycles experiment and the carbonation-drying-wetting cycles experiment for coral aggregate seawater concrete(CASC)with different strength grades,the effects of carbonation-drying-wetting on...Based on the drying-wetting cycles experiment and the carbonation-drying-wetting cycles experiment for coral aggregate seawater concrete(CASC)with different strength grades,the effects of carbonation-drying-wetting on the durability of CASC are studied with the surface state,mass loss rate,relative dynamic elastic modulus,ultrasonic wave velocity and cube compressive strength as indices.Results show that the mass loss rate of CASC increases gradually with the increase in cycle times in the drying-wetting and carbonation-drying-wetting cycles.The mass loss rate increases relatively slowly at the initial stage but it increases remarkably after 10 cycles.The relative dynamic elastic modulus and ultrasonic wave velocity decrease gradually with the increase in cycle times.After 6 cycles,the decrease rate of the relative dynamic elastic modulus and ultrasonic wave velocity of CASC tends to be flat and the surface is slightly damaged.Compared with the initial 28 d cube compressive strength,the cube compressive strength of CASC decreases by 8.8%to 11.0%.Drying-wetting cycles and carbonation can accelerate seawater erosion on CASC,and drying-wetting cycles result in salting-out and accelerate the destruction of concrete.Therefore,the carbonation-drying-wetting accelerates the destruction of CASC.展开更多
基金Funded by the National Key R&D Program of China(Nos.2021YFB2500600 and 2017YFE0301405)the Institute of Electrical Engineering,CAS(Nos.E155710301 and E155710201)+1 种基金the Fundamental Research Funds for the Central Universities of China(No.2020CDJDPT001)the Youth Innovation Promotion Association CAS(No.2022138)。
文摘In the present study,the Cu-(1 wt%-6 wt%)Ag alloys were prepared by melting,forging and wire drawing.The effects of plastic deformation on microstructure evolution and properties of the alloys were investigated.The results show that non-equilibrium eutectic colonies exist in the Cu-(3 wt%-6 wt%)Ag alloy and no eutectic colonies in the 1 wt%-2 wt%Ag containing alloys.These eutectic colonies are aligned along the drawing direction and refined with the increase of draw ratio.Attributed to the refinement of eutectic colonies,the Cu-Ag alloy exhibits higher strength with the increase of draw ratio.The Cu-6Ag alloy exhibits excellent comprehensive properties with a strength of 930 MPa and a conductivity of 82%IACS when the draw ratio reaches 5.7.
基金sup-ports from the National Natural Science Foundation of China(Nos.11832013 and 51878350)the Fundamental Research Funds for the Central Universities(No.B210202023)+5 种基金the Young Scientific and Technological Talents to Support Project of Jiangsu Association for Science and Technology(No.027)the Water Conservancy Science and Technology Project of Jiangsu Province(No.2020017)the Postdoctoral Research Funding Program of Ji-angsu Province(No.2021K133B)the Ningbo Science and Technology Innovation Project(No.2020Z040)the Nantong Science and Technology Plan Project(No.JC 2020120)the Open Research Fund of Changjiang River Research Institute of Changjiang Water Resources Com-mittee(No.CKWV2021879/KY).
文摘Based on seawater immersion,drying-wetting cycles,carbonation and drying-wetting cycles for coral aggregate sea-water concrete(CASC)with different strength grades,the effect of carbonation and drying-wetting cycles on chloride diffusion be-havior of CASC is studied.The results show that the free surface chloride concentration(Cs),free chloride diffusion coefficient(Df)and time-dependent index(m)of CASC in the drying-wetting cycles is obviously higher than that in seawater immersion.The Df and m of CASC of carbonation and drying-wetting cycles is higher than that in the drying-wetting cycles.Carbonation increases the Df and m of CASC,which is against CASC to resist chloride corrosion.The corrosion possibility of CASC structures in different ex-posed areas is as follows:splash zone(carbonation and drying-wetting cycles)>tidal zone(drying-wetting cycles)>underwater zone(seawater immersion).Besides,the chloride diffusion rate of C65-CASC is 17.8%-63.4%higher than that of C65-ordinary aggre-gate concrete(OAC)in seawater immersion(underwater zone).Therefore,anti-corrosion measures should be adopted to improve the service life of CASC structure in the oceanic environment.
基金The National Natural Science Foundation of China(No.11832013,51878350)the Fundamental Research Funds for the Central Universities(No.B210202023)+3 种基金the Natural Science Foundation of Jiangsu Province(No.BK20180433)the Water Resources Science and Technology Project of Jiangsu Province(No.2020017)the Basic Science Research Project of Nantong(No.JC2020120)the Key Laboratory of Coastal Disaster and Defence of Ministry of Education(Hohai University)(No.202006).
文摘Based on the drying-wetting cycles experiment and the carbonation-drying-wetting cycles experiment for coral aggregate seawater concrete(CASC)with different strength grades,the effects of carbonation-drying-wetting on the durability of CASC are studied with the surface state,mass loss rate,relative dynamic elastic modulus,ultrasonic wave velocity and cube compressive strength as indices.Results show that the mass loss rate of CASC increases gradually with the increase in cycle times in the drying-wetting and carbonation-drying-wetting cycles.The mass loss rate increases relatively slowly at the initial stage but it increases remarkably after 10 cycles.The relative dynamic elastic modulus and ultrasonic wave velocity decrease gradually with the increase in cycle times.After 6 cycles,the decrease rate of the relative dynamic elastic modulus and ultrasonic wave velocity of CASC tends to be flat and the surface is slightly damaged.Compared with the initial 28 d cube compressive strength,the cube compressive strength of CASC decreases by 8.8%to 11.0%.Drying-wetting cycles and carbonation can accelerate seawater erosion on CASC,and drying-wetting cycles result in salting-out and accelerate the destruction of concrete.Therefore,the carbonation-drying-wetting accelerates the destruction of CASC.
