The discovery of superconductivity in Sr/Ca-doped infinite-layer nickelates Nd(La)NiO_(2)thin films inspired extensive experimental and theoretical research.However,research on the possibilities of enhanced critical t...The discovery of superconductivity in Sr/Ca-doped infinite-layer nickelates Nd(La)NiO_(2)thin films inspired extensive experimental and theoretical research.However,research on the possibilities of enhanced critical temperature by interface heterostructure is still lacking.Due to the similarities of the crystal structure and band structure of infinite-layer nickelate La NiO_(2)and cuprate CaCuO_(2),we investigate the crystal,electronic and magnetic properties of La NiO_(2):CaCuO_(2)heterostructure using density functional theory and dynamical mean-field theory.Our theoretical results demonstrate that,even a very weak inter-layer z-direction bond is formed,an intrinsic charge transfer between Cu-3d_(x^(2)-y^(2))and Ni-3d_((x^(2)-y^(2)))orbitals is obtained.The weak interlayer hopping between Cu and Ni leaves a parallel band contributed by Ni/Cu-3d_((x^(2)-y^(2)))orbitals near the Fermi energy.Such an infinite-layer heterostructure with negligible interlayer interaction and robust charge transfer opens a new way for interface engineering and nickelate superconductors.展开更多
Geothermal energy with abundance and large quantity can partially cover building heating/cooling loads and promote the carbon-neutrality transitions.Shallow geothermal ventilation(SGV)system,with a little initial in-v...Geothermal energy with abundance and large quantity can partially cover building heating/cooling loads and promote the carbon-neutrality transitions.Shallow geothermal ventilation(SGV)system,with a little initial in-vestment cost,is one of promising technologies to partly replace the conventional air-conditioning system for air pre-cooling/pre-heating.This paper reviews applications of SGV system for improving thermal performance over latest two decades,which mainly includes the reclassification of SGV system,coupling with other advanced energy-saving technologies,application potentials for building cooling/heating under various weather conditions.Heat transfer mechanism and mathematical modelling techniques have been reviewed,together with in-depth analysis on current research trends,existing limitations,and recommendations of SGV system.Phase change materials,with considerable latent energy density,can stabilize the thermal performance with high reliability.The review identifies that optimization designs and advanced approaches need to be investigated to address the existing urgent issues of SGV system(e.g.,large land occupation,difficulty in centralized collection of condensate water timely for horizontal buried pipe,bacteria growth,polluted supply air,and high construction cost for ver-tical buried pipe).A plenty of studies show that the SGV system could greatly expand the application scope and improve system energy efficiency by combining with other energy-saving technologies.This paper will provide some guidelines for the scientific researchers and engineers to keep track on recent advancements and research trends of SGV system for the building thermal performance enhancement and pave path for future research works.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2021YFA0718900and 2022YFA1403000)the Key Research Program of Frontier Sciences of CAS(Grant No.ZDBS-LY-SLH008)+2 种基金the National Natural Science Foundation of China(Grant Nos.11974365,12004400,and 51931011)the Science Center of the National Natural Science Foundation of China(Grant No.52088101)the K.C.Wong Education Foundation(Grant No.GJTD-2020-11)。
文摘The discovery of superconductivity in Sr/Ca-doped infinite-layer nickelates Nd(La)NiO_(2)thin films inspired extensive experimental and theoretical research.However,research on the possibilities of enhanced critical temperature by interface heterostructure is still lacking.Due to the similarities of the crystal structure and band structure of infinite-layer nickelate La NiO_(2)and cuprate CaCuO_(2),we investigate the crystal,electronic and magnetic properties of La NiO_(2):CaCuO_(2)heterostructure using density functional theory and dynamical mean-field theory.Our theoretical results demonstrate that,even a very weak inter-layer z-direction bond is formed,an intrinsic charge transfer between Cu-3d_(x^(2)-y^(2))and Ni-3d_((x^(2)-y^(2)))orbitals is obtained.The weak interlayer hopping between Cu and Ni leaves a parallel band contributed by Ni/Cu-3d_((x^(2)-y^(2)))orbitals near the Fermi energy.Such an infinite-layer heterostructure with negligible interlayer interaction and robust charge transfer opens a new way for interface engineering and nickelate superconductors.
基金The authors will be very thankful for the support from the Hunan University,Central South UniversityThe Hong Kong University of Science and Technology,and University of California.All copyright licenses of have been successfully applied for all cited graphics,images,tables and/or figures。
文摘Geothermal energy with abundance and large quantity can partially cover building heating/cooling loads and promote the carbon-neutrality transitions.Shallow geothermal ventilation(SGV)system,with a little initial in-vestment cost,is one of promising technologies to partly replace the conventional air-conditioning system for air pre-cooling/pre-heating.This paper reviews applications of SGV system for improving thermal performance over latest two decades,which mainly includes the reclassification of SGV system,coupling with other advanced energy-saving technologies,application potentials for building cooling/heating under various weather conditions.Heat transfer mechanism and mathematical modelling techniques have been reviewed,together with in-depth analysis on current research trends,existing limitations,and recommendations of SGV system.Phase change materials,with considerable latent energy density,can stabilize the thermal performance with high reliability.The review identifies that optimization designs and advanced approaches need to be investigated to address the existing urgent issues of SGV system(e.g.,large land occupation,difficulty in centralized collection of condensate water timely for horizontal buried pipe,bacteria growth,polluted supply air,and high construction cost for ver-tical buried pipe).A plenty of studies show that the SGV system could greatly expand the application scope and improve system energy efficiency by combining with other energy-saving technologies.This paper will provide some guidelines for the scientific researchers and engineers to keep track on recent advancements and research trends of SGV system for the building thermal performance enhancement and pave path for future research works.
