Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by...Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support interaction.It is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active sites.The exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile dominated.Therefore,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ratio.Ni/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),respectively.These rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with anatase.This study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction.展开更多
Artificial fish reef is a kind of artificial structure in water,which provides a necessary and safe place for aquatic life such as fish to inhabit,grow,and breed,and creates an environment suitable for fish growth,so ...Artificial fish reef is a kind of artificial structure in water,which provides a necessary and safe place for aquatic life such as fish to inhabit,grow,and breed,and creates an environment suitable for fish growth,so as to protect and multiply fishery resources.In a large time scale,the physical process of sea area can deeply affect the chemical process and biological process,so the structure characteristics of artificial reef are the key factors affecting the flow field effect around the reef.In this study,through the hydrodynamic experiments of four kinds of reef models,including big windows box reef,big and small windows box reef,"(卐)"shaped reef and double-layer shellfish breeding reef,the influence of single reef structure on the flow field effect is analyzed,and the force conditions of different reefs under the same incoming current velocity are obtained.According to the simulation results,the safety research and calculation of five kinds of reef models are carried out,and the volumes of vortex area and upwelling area behind four kinds of reef are obtained.Using hydrodynamic model to simulate the flow field effect of reef area,optimizing the reef structure design,improving the maximum biological trapping and proliferation effect of reef,can provide theoretical guidance and scientific and technological support for the construction of reef area.展开更多
Under the background of a new round of transformation and upgrading of the marine fishery industrial structure and the"speed up and upgrading"of the national marine ranching,this paper uses the method of com...Under the background of a new round of transformation and upgrading of the marine fishery industrial structure and the"speed up and upgrading"of the national marine ranching,this paper uses the method of combining practical experience,literature review,and field research to describe the development of marine ranching at home and abroad,and summarizes the practice process and achievements of Tianjin marine ranch:one national and two provincial marine ranch demonstration areas,16 ecotype reef areas,one seafood demonstration area,and one floating fish reef demonstration area were built,with a total scale of 26.9 km^(2),and a total of 134900 m^(2) fish reefs.This paper emphatically analyzed the construction experience and characteristics of the Tianjin Dashentang Marine Ranch demonstration area.Combined with the development orientation and objectives of Tianjin marine ranch,it is proposed to unify understanding,perfect development concept,accelerate the pace of scientific research,and adhere to ecological priority.In future,the construction of Tianjin marine ranch should encourage innovation to achieve leap-forward development,explore a new model of fishery development based on the'Economic Union',with'marine ranching-ecological farming-leisure tourism-featured products'as the main body.Based on relevant experience at home and abroad,the industrialization model of marine ranch with Tianjin characteristics should be established,which aims to provide strong support for the construction of"blue granary"in Tianjin,the implementation of Tianjin's coastal ranching strategy,and the promotion of Tianjin coastal ecosystem reconstruction and fishery resource recovery.展开更多
基金The project was supported by the National Key R&D Program of China(2021YFF0500702)Natural Science Foundation of Shanghai(22JC1404200)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1404000)Natural Science Foundation of China(U22B20136,22293023)Science and Technology Major Project of Inner Mongolia(2021ZD0042)the Youth Innovation Promotion Association of CAS。
文摘Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support interaction.It is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active sites.The exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile dominated.Therefore,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ratio.Ni/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),respectively.These rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with anatase.This study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction.
基金supported by the National Key R&D Plan(No.2023YFD2401104)Tianjin Agricultural Development Service Center Science and Technology Innovation Project for Youth(No.ZXKJ202429 and No.ZXKJ202454).
文摘Artificial fish reef is a kind of artificial structure in water,which provides a necessary and safe place for aquatic life such as fish to inhabit,grow,and breed,and creates an environment suitable for fish growth,so as to protect and multiply fishery resources.In a large time scale,the physical process of sea area can deeply affect the chemical process and biological process,so the structure characteristics of artificial reef are the key factors affecting the flow field effect around the reef.In this study,through the hydrodynamic experiments of four kinds of reef models,including big windows box reef,big and small windows box reef,"(卐)"shaped reef and double-layer shellfish breeding reef,the influence of single reef structure on the flow field effect is analyzed,and the force conditions of different reefs under the same incoming current velocity are obtained.According to the simulation results,the safety research and calculation of five kinds of reef models are carried out,and the volumes of vortex area and upwelling area behind four kinds of reef are obtained.Using hydrodynamic model to simulate the flow field effect of reef area,optimizing the reef structure design,improving the maximum biological trapping and proliferation effect of reef,can provide theoretical guidance and scientific and technological support for the construction of reef area.
基金supported by the National Key R&D Plan(2019YFE0122300)Tianjin City Science and Technology Major Special Project and Project(18ZXRHSF00270)+1 种基金Tianjin Agricultural Development Service Center youth science and technology innovation project(ZXKJ202429)Tianjin City Mariculture Modern Agricultural Industry Technology System Innovation Team Project(ITTMRS2023005).
文摘Under the background of a new round of transformation and upgrading of the marine fishery industrial structure and the"speed up and upgrading"of the national marine ranching,this paper uses the method of combining practical experience,literature review,and field research to describe the development of marine ranching at home and abroad,and summarizes the practice process and achievements of Tianjin marine ranch:one national and two provincial marine ranch demonstration areas,16 ecotype reef areas,one seafood demonstration area,and one floating fish reef demonstration area were built,with a total scale of 26.9 km^(2),and a total of 134900 m^(2) fish reefs.This paper emphatically analyzed the construction experience and characteristics of the Tianjin Dashentang Marine Ranch demonstration area.Combined with the development orientation and objectives of Tianjin marine ranch,it is proposed to unify understanding,perfect development concept,accelerate the pace of scientific research,and adhere to ecological priority.In future,the construction of Tianjin marine ranch should encourage innovation to achieve leap-forward development,explore a new model of fishery development based on the'Economic Union',with'marine ranching-ecological farming-leisure tourism-featured products'as the main body.Based on relevant experience at home and abroad,the industrialization model of marine ranch with Tianjin characteristics should be established,which aims to provide strong support for the construction of"blue granary"in Tianjin,the implementation of Tianjin's coastal ranching strategy,and the promotion of Tianjin coastal ecosystem reconstruction and fishery resource recovery.
