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一种锐化误差小波EDXRF光谱解析方法研究
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作者 杜志恒 何剑锋 +3 位作者 李卫东 汪雪元 叶志翔 王文 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2023年第6期1719-1724,共6页
在轻元素自身和实测元素间的特征X射线相互影响之下,受仪器能量分辨率的制约,实测X射线荧光光谱会产生严重重叠。以色谱分离度Rs判定谱峰重叠程度,针对Rs低于0.3的重叠峰,提出一种解析EDXRF光谱的新方法,并对模拟X射线荧光光谱进行了新... 在轻元素自身和实测元素间的特征X射线相互影响之下,受仪器能量分辨率的制约,实测X射线荧光光谱会产生严重重叠。以色谱分离度Rs判定谱峰重叠程度,针对Rs低于0.3的重叠峰,提出一种解析EDXRF光谱的新方法,并对模拟X射线荧光光谱进行了新方法的验证。首先,详细介绍基于四阶导的峰锐化法和提出误差小波变换。通过仿真结果发现:当Rs=0.27时,两种方法皆不能单独实现重叠谱峰的解析与识别;然而,原始信号在四阶峰锐化法处理后保留了峰位特征的同时,还出现了Rs明显增大的有利现象。因此,只需要通过调节四阶峰锐化法的权重完成对低分离度重叠峰的初步锐化处理,再对锐化后的信号进行误差小波变换,结果实现了对模拟重叠峰的分解,证明了结合后的新方法(锐化误差小波变换)针对极低分离度的重叠谱峰具有强大的分解能力。对两组重叠谱峰采用叠加的高斯函数进行模拟,分别是Mn的K_(β)能量峰与Fe的K_(α)能量峰的重叠光谱(Rs=0.19)以及Al的K_(α)能量峰与其K_(β)能量峰的重叠光谱(Rs=0.11)。用新方法对谱线进行处理,实现了重叠峰分解,结果表明针对极低分离度的重叠谱峰该方法具有可行性。通过锐化误差小波对实测的EDXRF光谱进行解析,通过对三组数据解析特定三种低分离度重叠峰进行对比实验,均成功解析与识别了低分离度的重叠谱峰。结果表明:针对极低分离度的重叠谱峰,锐化误差小波变换可以有效分解,具有突破性,实用性和创新性。 展开更多
关键词 X射线荧光光谱 低分离度重叠峰 峰锐化 锐化误差小波变换 重峰分解
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Genetic Diversity Analysis Among Populations of Mink from China by Inter-simple Sequence Repeat(ISSR) Markers 被引量:2
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作者 Yang Hong-yan Fu Jing +2 位作者 Ning Fang-yong du zhi-heng Bai Xiu-juan 《Journal of Northeast Agricultural University(English Edition)》 CAS 2013年第3期47-54,共8页
Inter-simple Sequence Repeat(ISSR) analysis was applied to assess the genetic diversity within and among five populations of mink from Liaoning Province. A total of 20 primers were screened, five selected primers prod... Inter-simple Sequence Repeat(ISSR) analysis was applied to assess the genetic diversity within and among five populations of mink from Liaoning Province. A total of 20 primers were screened, five selected primers produced 35 discernible bands, with 30(85.71%) being polymorphic, indicating high genetic diversity at the species level. The highest genetic diversity was observed in the brown mink population, whereas the lowest diversity was found in the standard-pitchy mink population. Based on genetic distance(1972), a dendrogram was constructed by using UPGMA algorithm, and five populations were divided into two major groups. Group I consisted of only the standard-pitchy mink population, and Group II included other four populations, in Group II, sapphire mink was close to brown mink population. The results of genetic differentiation indicated that the genetic differentiation degree between populations was lower and the genetic variation primarily came from within populations. This paper showed that ISSR technique was a reliable tool that could be used to study genetic diversity in the mink. 展开更多
关键词 MINK ISSR genetic diversity
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A shallow ice core from East Greenland showing a reduction in black carbon during 1990-2016 被引量:2
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作者 du zhi-heng XIAO Cun-De +6 位作者 DOU Ting-Feng LI Chuan-Jin DING Ming-Hu Sangeeta SHARMA MA Xiang-Yu WANG Shi-Meng ZHANG Wang-Bing 《Advances in Climate Change Research》 SCIE CSCD 2020年第4期360-369,共10页
This study reports on the measurements of ion and refractory black carbon(rBC)concentrations in a shallow(10.96 m)ice core sample which was drilled from the field site of the East Greenland Ice Core Project(EGRIP)in J... This study reports on the measurements of ion and refractory black carbon(rBC)concentrations in a shallow(10.96 m)ice core sample which was drilled from the field site of the East Greenland Ice Core Project(EGRIP)in July,2016.The results provide a recent record of rBC deposition in the East Greenland ice sheet from 1990 to 2016.The annual variability in oxygen(δ^(18)O)and hydrogen(δD)isotopic compositions indicated that notably warm events occurred since 2008.Peaks in rBC occurred during summer seasons,which may be attributed to the burning of biomass in boreal summer.The rBC record and analysis of historical air trajectories using the HYSPLIT model indicated that anthropogenic BC emissions from Russia,North America and Europe contributed to the majority of rBC deposition in the Greenland region,and a reduction in anthropogenic BC consumption in these areas played a dominant role in the decrease in BC concentrations since 2000.This record also suggests that the emissions from the East Asian region(China)contributed very little to the recorded BC concentrations in East Greenland ice core.The model results indicated that radiative forcing due to BC had decreased significantly since 1990,and had remained below 0.02W m^(-2) since 2000. 展开更多
关键词 East Greenland Ice core Black carbon Seasonal variability Potential emission sources
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