The U-Pb (on zircon) and Sm-Nd analysis is a popular isotope-geochronological tool for estimating the age of rocks from PGE mafic-ultramafic intrusions. Sulphides can be used to study the geochronology of ore processe...The U-Pb (on zircon) and Sm-Nd analysis is a popular isotope-geochronological tool for estimating the age of rocks from PGE mafic-ultramafic intrusions. Sulphides can be used to study the geochronology of ore processes as well, since they should indicate the time of ore mineralization. Gabbronorite has been sampled from the Passivaara reef at the Penikat layered intrusion (Finland) for U-Pb and Sm-Nd isotope single zircon analyses in order to separate sulphide minerals. The Sm-Nd isotope age of gabbronorite has been dated at 2426 ± 36 Ma;eNd(T) = −1.4 ± 0.4. The Sm-Nd isotope age on sulphides and rock-forming minerals reflects the crystallization time of the ore-bearing gabbronorite from the Passivaara reef of the Penikat layered intrusion. The mass-spectrometer analytical environment and modes of operation have been adjusted to detect REE in sulphide minerals on example of pyrite from the PGE Penikat layered intrusion (Finland) and chalcopyrite from the Talnakh deposit (Norilsk area, Russia) has been estimated. The total REE content in pyrite is ca. 3.5 ppm, which is enough to define the Sm-Nd age of pyrite. The study shows how to use the mineral/chondrite spectra to evaluate the accuracy of the REE analytical results on example of State Standard Sample 2463 (Russia).展开更多
Baddeleyite is an important mineral geochronometer. It is valued in the U-Pb (ID-TIMS) geochronology more than zircon because of its magmatic origin, while zircon can be metamorphic, hydrothermal or occur as xenocryst...Baddeleyite is an important mineral geochronometer. It is valued in the U-Pb (ID-TIMS) geochronology more than zircon because of its magmatic origin, while zircon can be metamorphic, hydrothermal or occur as xenocrysts. Detailed mineralogical (BSE, KL, etc.) research of baddeleyite started in the Fennoscandian Shield in the 1990s. The mineral was first extracted from the Paleozoic Kovdor deposit, the second-biggest baddeleyite deposit in the world after Phalaborwa (2.1 Ga), South Africa. The mineral was successfully introduced into the U-Pb systematics. This study provides new U-Pb and LA-ICP-MS data on Archean Ti-Mgt and BIF deposits, Paleoproterozoic layered PGE intrusions with Pt-Pd and Cu-Ni reefs and Paleozoic complex deposits (baddeleyite, apatite, foscorite ores, etc.) in the NE Fennoscandian Shield. Data on concentrations of REE in baddeleyite and temperature of the U-Pb systematics closure are also provided. It is shown that baddeleyite plays an important role in the geological history of the Earth, in particular, in the break-up of supercontinents.展开更多
Genesis of the oldest continental crust retains a marked trace in the Earth’s evolution over its 4.5 Ga history. Despite ample isotope data on the role of the continental crust in the Earth’s evolution, there has be...Genesis of the oldest continental crust retains a marked trace in the Earth’s evolution over its 4.5 Ga history. Despite ample isotope data on the role of the continental crust in the Earth’s evolution, there has been much debate on the origin of grey gneisses and tonalite-trondhjemite-granodiorites (TTG). Precise U-Pb (ID-TIMS) and SHRIMP data on single zircon for paragneisses and TTG (3158.2 ± 8.2 Ma) have indicated the Central-Kola and Belomorian (White Sea) megablocks of the Fennoscandian Shield to be 3.16 Ga and 3.70 Ga, respectively. The newly obtained ages of zircon from these megablocks indicate the origin of the discrete continental crust to be 3.16 and 3.70 Ga. It is close to the Nordsim zircon data on the Siurua TTG (Finland), which are 3.45 and 3.73 Ga in the core. The new summarized data on the Earth’s oldest rocks (basement and continental crust) indicate the younger age of the rocks in the Fennoscandian Shield as compared to those in Australia (Kronendonk et al., 2019).展开更多
文摘The U-Pb (on zircon) and Sm-Nd analysis is a popular isotope-geochronological tool for estimating the age of rocks from PGE mafic-ultramafic intrusions. Sulphides can be used to study the geochronology of ore processes as well, since they should indicate the time of ore mineralization. Gabbronorite has been sampled from the Passivaara reef at the Penikat layered intrusion (Finland) for U-Pb and Sm-Nd isotope single zircon analyses in order to separate sulphide minerals. The Sm-Nd isotope age of gabbronorite has been dated at 2426 ± 36 Ma;eNd(T) = −1.4 ± 0.4. The Sm-Nd isotope age on sulphides and rock-forming minerals reflects the crystallization time of the ore-bearing gabbronorite from the Passivaara reef of the Penikat layered intrusion. The mass-spectrometer analytical environment and modes of operation have been adjusted to detect REE in sulphide minerals on example of pyrite from the PGE Penikat layered intrusion (Finland) and chalcopyrite from the Talnakh deposit (Norilsk area, Russia) has been estimated. The total REE content in pyrite is ca. 3.5 ppm, which is enough to define the Sm-Nd age of pyrite. The study shows how to use the mineral/chondrite spectra to evaluate the accuracy of the REE analytical results on example of State Standard Sample 2463 (Russia).
文摘Baddeleyite is an important mineral geochronometer. It is valued in the U-Pb (ID-TIMS) geochronology more than zircon because of its magmatic origin, while zircon can be metamorphic, hydrothermal or occur as xenocrysts. Detailed mineralogical (BSE, KL, etc.) research of baddeleyite started in the Fennoscandian Shield in the 1990s. The mineral was first extracted from the Paleozoic Kovdor deposit, the second-biggest baddeleyite deposit in the world after Phalaborwa (2.1 Ga), South Africa. The mineral was successfully introduced into the U-Pb systematics. This study provides new U-Pb and LA-ICP-MS data on Archean Ti-Mgt and BIF deposits, Paleoproterozoic layered PGE intrusions with Pt-Pd and Cu-Ni reefs and Paleozoic complex deposits (baddeleyite, apatite, foscorite ores, etc.) in the NE Fennoscandian Shield. Data on concentrations of REE in baddeleyite and temperature of the U-Pb systematics closure are also provided. It is shown that baddeleyite plays an important role in the geological history of the Earth, in particular, in the break-up of supercontinents.
文摘Genesis of the oldest continental crust retains a marked trace in the Earth’s evolution over its 4.5 Ga history. Despite ample isotope data on the role of the continental crust in the Earth’s evolution, there has been much debate on the origin of grey gneisses and tonalite-trondhjemite-granodiorites (TTG). Precise U-Pb (ID-TIMS) and SHRIMP data on single zircon for paragneisses and TTG (3158.2 ± 8.2 Ma) have indicated the Central-Kola and Belomorian (White Sea) megablocks of the Fennoscandian Shield to be 3.16 Ga and 3.70 Ga, respectively. The newly obtained ages of zircon from these megablocks indicate the origin of the discrete continental crust to be 3.16 and 3.70 Ga. It is close to the Nordsim zircon data on the Siurua TTG (Finland), which are 3.45 and 3.73 Ga in the core. The new summarized data on the Earth’s oldest rocks (basement and continental crust) indicate the younger age of the rocks in the Fennoscandian Shield as compared to those in Australia (Kronendonk et al., 2019).
