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4种检出限确定方法的讨论--以离子色谱法测定冬瓜中亚硝酸盐含量为例 被引量:1
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作者 张林 方明强 +2 位作者 唐浩文 陈洁 郑卫东 《现代食品》 2022年第15期217-222,共6页
目的:目前国内对检测方法检出限的计算没有统一的规定,但在进行检测方法验证或确认时检出限却是必做指标,因此需确定各检出限实验方法的有优缺点,根据实际情况确定最佳的实验方法。方法:本文以离子色谱法测定冬瓜中的亚硝酸盐含量为例,... 目的:目前国内对检测方法检出限的计算没有统一的规定,但在进行检测方法验证或确认时检出限却是必做指标,因此需确定各检出限实验方法的有优缺点,根据实际情况确定最佳的实验方法。方法:本文以离子色谱法测定冬瓜中的亚硝酸盐含量为例,通过4种应用较多的方法,即全程序空白法、加入标准目标分析物法、稀释标准溶液法和计算校准直线的检测能力法获得4个检出限,并加以比较。结果:检出限随确定方法的不同而不同,通过稀释标准溶液获得的检出限因减少了前处理实验步骤的干扰,获得的检出限数值往往较低,更接近于仪器检出限。通过加入标准目标分析物及通过全程序空白获得的检出限更能综合反映实验室检测水平,但受基质限制,若要获得多种物质的检出限,工作量较大。通过校准直线计算检测能力获得的检出限操作简单,但无法全面反映基质、人员、试剂等的综合影响。结论:实验室在进行方法验证或确认时可尝试多种检出限获得方法,对结果进行比较后结合实验室实际情况确定最终的检出限实验方法,同时也建议相关部门在发布检测方法标准时一并列出详细的检出限实验或计算方法,以供比较或借鉴。 展开更多
关键词 检出限 离子色谱法 冬瓜 亚硝酸盐
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A Preliminary Study on the Relation Between the Thermal and Geometric Surface Centroids of the Western Pacific Warm Pool
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作者 fang mingqiang 《Journal of Ocean University of China》 SCIE CAS 2006年第2期91-98,共8页
Numerous published results have showr the importance of the Wcstern Pacific Warm Pool (WPWP)surface centroid movement in ENSO-(EI Nino/Southcrn Oscillation)rclated studies .Howcver,some rccent research conclusions... Numerous published results have showr the importance of the Wcstern Pacific Warm Pool (WPWP)surface centroid movement in ENSO-(EI Nino/Southcrn Oscillation)rclated studies .Howcver,some rccent research conclusions make it necessary to clarify the differenccs of the currently exicing two types of WPWP surface centroid:the geometric centroid and the thermal (heat)centrold.This study analyzes the physical backgrounds of the two typcs of centroid and points out their differenccs.which suggest that different types of ccntroid may scrve different study purposes.This study also shows that the ‘geometric center’of WPWP.actually a close approximation to the mass ccntroid,is more related to the Nino-3 region sca surfacc temperaturc(SST)ancmaly and can also be regarded as an important indicator of ENSO events. 展开更多
关键词 Western Pacific Warm Pool (WPWP) ENSO thermal centroid geometric centroid mass centroid
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Meridional Variation of the 1955-2003 Sea Level Anomalies in the Tropical Pacific Ocean Associated with El Nio Events
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作者 fang mingqiang and QU Liqin 《Journal of Ocean University of China》 SCIE CAS 2007年第4期332-338,共7页
The Sea Level Anomaly-Torque (SLAT, relative to a reference location in the Pacific Ocean), which means the total torque of the gravity forces of sea waters with depths equal to the Sea Level Anomaly (S/A) in the ... The Sea Level Anomaly-Torque (SLAT, relative to a reference location in the Pacific Ocean), which means the total torque of the gravity forces of sea waters with depths equal to the Sea Level Anomaly (S/A) in the tropical Pacific Ocean, is defined in this study. The time series of the SLAT from merged altimeter data (1993-2003) had a great meridional variation during the 1997-1998 E1 Nifio event. By using historical upper layer temperature data (1955-2003) for the tropical Pacific Ocean, the temperature-based SLAT is also calculated and the meridional variation can be found in the historical E1 Nifio events (1955-2003), which suggests that the meridional shifts of the sea level anomaly are also intrinsic oscillating modes of the E1 Nifio cycles like the zonal shifts. 展开更多
关键词 E1 Nifio sea level anomaly tropical Pacific meridional transport
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Low Frequency Oscillations of the Heat Distribution in the Global Upper Ocean Layers
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作者 fang mingqiang 《Journal of Ocean University of China》 SCIE CAS 2006年第1期35-38,共4页
The heat distributions in the upper layers of the ocean have been studied and some important low frequency oscillations (LFOs) are already found and quantified by using various characteristic factors. In this paper,... The heat distributions in the upper layers of the ocean have been studied and some important low frequency oscillations (LFOs) are already found and quantified by using various characteristic factors. In this paper, the ‘heat center' of a sea area is defined with a simple method. Then the temperature data set of the upper layer of the global ocean (from surface down to 400 m, 1955-2003) is analyzed to detect the possible LFOs. Not only some zonal LFOs, which were reported early, but also some strong LFOs of the vertical and meridional heat distribution, which might imply some physical sense, are detected. It should be noted that the similar vertical oscillation pattern can be found in the Pacific Ocean, Atlantic Ocean and Indian Ocean. Results from some preliminary studies show that the vertical LFO might be caused by the solar irradiance anomalies. This study may help reveal some unknown dynamical processes in the global oceans and may also benefit other related studies. 展开更多
关键词 upper ocean layer leat distribution low frequency oscillation
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