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Synthesis and Crystal Structure of a New Nickel(II) Complex with Unsymmetric Quadridentate Schiff Base Containing Oxime 被引量:1
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作者 ZHANGGuo-Juan fengyun-long GAOShan 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第4期454-456,共3页
The title complex, C18H15N3NiO3, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group Cc with a = 10.939(2), b = 22.909(5), c = 6.907(1) ?, β = 11... The title complex, C18H15N3NiO3, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group Cc with a = 10.939(2), b = 22.909(5), c = 6.907(1) ?, β = 116.75(3)°, V = 1545.7(5) ?, Z = 4, Mr = 380.04, F(000) = 784, Dc = 1.633 g/cm3 and μ(MoKα) = 1.279 mm–1. The structure was refined to R = 0.0472 and wR = 0.0893 for 2571 observed reflections with I > 2σ(I). The absolute structure Flack parameter X is 0.01(2). In this crystal structure, strong face-to-face π-π stacking interactions between adjacent molecules lead to a one-dimensional chain structure. 展开更多
关键词 nickel(II) complex Schiff base OXIME crystal structure π-π stacking interaction
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Synthesis and Crystal Structure of Chloro(p-toluidine)[4-(p-tolyl)imino-2-pentanone-3-oximato]- palladium(Ⅱ), PdCl(p-CH_3C_6H_4NH_2)(p-CH_3C_6H_4-iai)
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作者 fengyun-long LIUShi-Xiong 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2003年第3期275-278,共4页
The title complex chloro(p-toluidine)[4-(p-tolyl)imino-2-pentanone-3-oximato]- palladium(Ⅱ), PdCl(p-CH3C6H4NH2)(p-CH3C6H4-iai), C19H22ClN3O2Pd, (p-CH3C6H4NH2 and p-CH3C6H4-iai- are p-toluidine and the anion of 4-(p-t... The title complex chloro(p-toluidine)[4-(p-tolyl)imino-2-pentanone-3-oximato]- palladium(Ⅱ), PdCl(p-CH3C6H4NH2)(p-CH3C6H4-iai), C19H22ClN3O2Pd, (p-CH3C6H4NH2 and p-CH3C6H4-iai- are p-toluidine and the anion of 4-(p-tolyl)imino-2-pentanone-3-oximato, respec- tively), crystallizes in the monoclinic system, space group C2/c with a = 26.082(5), b = 13.521(3), c = 12.578(3) ? b = 112.18(3), Mr = 466.25, V = 4108(2) 3, Dc = 1.508 g/cm3, F(000) = 1888, m(MoKa) = 1.051 mm-1, Z = 8, the final R = 0.0368 and wR = 0.0855 for 3243 observed reflections (I ≥ 2s(I)). The coordination environment around Pd is a distorted PdClN3 square-plane composed of imino- and oximo-nitrogen from the Schiff base ligand of p-CH3C6H4-iai-, and amino-nitrogen from p-toluidine and chlorine atom. 展开更多
关键词 palladium complex isonitroso-b-ketoimine Schiff base crystal structure
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