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Structure and Combustion Characteristics of Methane/Air Premixed Flame under the Action of Wall
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作者 feiyang li Jianfeng Pan +2 位作者 Chenxin Zhang Evans K.Quaye Xia Shao 《Energy Engineering》 EI 2021年第4期1135-1154,共20页
In order to obtain the combustion characteristics of the CH4/Air premixed flame under the action of the wall interaction,a study on the impact of the jet flame on the wall at different separation distances was carried... In order to obtain the combustion characteristics of the CH4/Air premixed flame under the action of the wall interaction,a study on the impact of the jet flame on the wall at different separation distances was carried out.The separation distance from the burner outlet to the lower surface of the wall is changed and the flame structure is obtained through experiments.The temperature,velocity and reaction rate are obtained through numerical simulation,and the law of flame characteristics change is obtained through analysis.The results show that as the separation distance increases,the premixing cone inside the flame gradually changes from a horn shape to a complete cone shape and the length of the premixing cone profile increases.Also,the peak temperature and velocity of the mixture in the axial direction gradually increase,and the temperature and velocity in the radial direction first increase and then decrease.The temperature gradient and velocity reach the maximum when the separation distance is 11 mm.The peaks of reactants(CH_(4))net reaction rate intermediate products(CO)and products(CO_(2),H_(2)O)on the axis and the axial distance corresponding to the peaks increase accordingly.The chemical reaction rate near the wall also gradually decreases with the increase of the separation distance. 展开更多
关键词 Flame-wall interaction separation distance flame structure air flow temperature flow velocity reaction rate
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Negotiation during A Crisis:Possible Problems and Three Suggestions for SME Leaders
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作者 feiyang li Siyuan Pan +2 位作者 Xinyan Wang Qingyu li Anda Ding 《Proceedings of Business and Economic Studies》 2020年第5期36-40,共5页
Negotiation skills are essential for everyone especially business leaders to agree on how to share a limited resource,create mutual benefit and avoid conflicts in crisis.In this recent coronavirus outbreak,the Chinese... Negotiation skills are essential for everyone especially business leaders to agree on how to share a limited resource,create mutual benefit and avoid conflicts in crisis.In this recent coronavirus outbreak,the Chinese government is encouraging people to stay at home as much as possible,prohibiting any gathering activities,and forcing some businesses to close.Therefore,this paper will use data analysis,case study and investigation for a small garment processor enterprise to indicate the problem about capital chain rupture and loss of profit from macro to micro perspectives.From the second half of this paper,there are three suggestions including preparation,adjustment of emotions and some common tactics for SMEs to use in negotiation in crisis. 展开更多
关键词 EVERYONE GATHERING mutual
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Development of a new cerebral ischemia reperfusion model of Mongolian gerbils and standardized evaluation system
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作者 Ying Wu Caijiao Hu +9 位作者 Zhihui li feiyang li Jianyi Lv Meng Guo Xin liu Changlong li Xueyun Huo Zhenwen Chen lifeng Yang Xiaoyan Du 《Animal Models and Experimental Medicine》 CAS 2024年第1期48-55,共8页
Background:The Mongolian gerbil is an excellent laboratory animal for preparing the cerebral ischemia model due to its inherent deficiency in the circle of Willis.However,the low incidence and unpredictability of symp... Background:The Mongolian gerbil is an excellent laboratory animal for preparing the cerebral ischemia model due to its inherent deficiency in the circle of Willis.However,the low incidence and unpredictability of symptoms are caused by numerous complex variant types of the circle.Additionally,the lack of an evaluation system for the cer-ebral ischemia/reperfusion(I/R)model of gerbils has shackled the application of this model.Methods:We created a symptom-oriented principle and detailed neurobehavioral scoring criteria.At different time points of reperfusion,we analyzed the alteration in locomotion by rotarod test and grip force score,infarct volume by triphenyltetrazo-lium chloride(TTC)staining,neuron loss using Nissl staining,and histological charac-teristics using hematoxylin-eosin(H&E)straining.Results:With a successful model rate of 56%,32 of the 57 gerbils operated by our method harbored typical features of cerebral I/R injury,and the mortality rate in the male gerbils was significantly higher than that in the female gerbils.The suc-cessfully prepared I/R gerbils demonstrated a significant reduction in motility and grip strength at 1 day after reperfusion;formed obvious infarction;exhibited typi-cal pathological features,such as tissue edema,neuronal atrophy and death,and vacuolated structures;and were partially recovered with the extension of reperfu-sion time.Conclusion:This study developed a new method for the unilateral common carotid artery ligation I/R model of gerbil and established a standardized evaluation system for this model,which could provide a new cerebral I/R model of gerbils with more practical applications. 展开更多
关键词 ischemia/reperfusion Mongolian gerbil standardized model system unilateral carotid occlusion
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Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors
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作者 Yanling Zhuang Weiwei Zhao +5 位作者 Longlu Wang feiyang li Weikang Wang Shujuan liu Wei Huang Qiang Zhao 《Science China Chemistry》 SCIE EI CAS CSCD 2020年第11期1632-1644,共13页
Electrochromic supercapacitors have drawn enormous attention due to their ability to monitor the charge and discharge processes through color changes of electroactive materials.However,there are few work on small orga... Electrochromic supercapacitors have drawn enormous attention due to their ability to monitor the charge and discharge processes through color changes of electroactive materials.However,there are few work on small organic molecules as active materials for all-solid-state electrochromic supercapacitors.Herein,we reported two novel multifunctional symmetric viologens(TPA-bpy and CZ-bpy),which showed different solvatochromic,electrochromic,electroluminochromic and energy storage behaviors despite their similar chemical structures.The different performances between these two viologens were attributed to the difference in the intramolecular charge transfer capability and the solubility in organic solvents.Devices containing TPA-bpy displayed faster response time and higher coloration efficiency due to the introduction of packing-disruptive and three-dimensional triarylamine groups.Moreover,devices containing TPA-bpy also showed energy storage characteristics with an obvious color change from purple to yellow.It showed a wide voltage window(2.0 V),long discharge time(230.3 s at 0.01 mA cm−2),and excellent cycling stability with 90%capacitance retention after 6,000 cycles.The work provides a new and convenient strategy towards the development of novel electrochromic capacitive materials. 展开更多
关键词 VIOLOGEN SOLVATOCHROMISM ELECTROCHROMISM electroluminochromism SUPERCAPACITORS
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金属离子辅助转化法助力Ti_(3)C_(2)T_(x)前驱体衍生制备儿茶酚基MOF
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作者 王维康 白岩 +8 位作者 杨品 袁帅 李飞阳 赵为为 金贝贝 张璇 刘淑娟 袁大强 赵强 《Science Bulletin》 SCIE EI CAS CSCD 2023年第19期2180-2189,M0004,共11页
MXene具有丰富的高电负性末端原子、较大的比表面积和较小的原子厚度等优点,已被用作前驱体制备多种纳米材料.然而,目前已报道的用于衍生金属有机框架(MOF)的MXene仅限于V_(2)CT_(x).因此,通过增加MXene和有机配体的种类,合理设计和合... MXene具有丰富的高电负性末端原子、较大的比表面积和较小的原子厚度等优点,已被用作前驱体制备多种纳米材料.然而,目前已报道的用于衍生金属有机框架(MOF)的MXene仅限于V_(2)CT_(x).因此,通过增加MXene和有机配体的种类,合理设计和合成新型MOF,并进一步深入探索其合成机理仍是目前面临的重要挑战.本文采用金属离子辅助转化策略,以二维Ti_(3)C_(2)T_(x)为前驱体,合成了具有非互穿SrSi2(srs)框架的基于儿茶酚的三维(3D)TiCu-HHTP(HHTP=2,3,6,7,10,11-六羟基三苯)MOF.该策略表现出了良好的普适性,Ti3C2和辅助Cu^(2+)离子可以扩展到V2C MXene和其他辅助金属离子Mn^(+)(M=Ni^(2+)、Co^(2+),Mn^(2+)和Zn^(2+)).转化机制包括从Ti3C2纳米片到辅助金属离子的电荷转移、Ti-C键断裂促进释放Ti^(4+)离子以及Ti^(4+)/Mn^(+)与HHTP之间的强螯合配位协同促进TiCu-HHTP的形成.独特的3D导电网络和丰富的氧化还原位点赋予了TiCu-HHTP-7/PPy复合柔性透明电极快速的离子/电子传输和可逆的法拉第反应.在0.02 mA cm^(-2)电流密度下,TiCu-HHTP/PPy透明电极的面积比电容值达到3.63 mF cm^(-2),明显高于纯PPy电极的面积电容值(1.79 mF cm^(-2)).TiCu-HHTP/PPy透明电容器在0.75μW cm^(-2)的功率密度下,能量密度为0.042μWh cm^(-2). 展开更多
关键词 金属有机框架 儿茶酚 离子辅助 电荷转移 有机配体 电负性 电子传输 透明电极
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调控分子间的电子耦合效应实现多彩超长有机室温磷光
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作者 佘鹏飞 段嘉宇 +6 位作者 李飞阳 周宇翔 秦妍妍 魏娟 刘淑娟 马云 赵强 《Science China Materials》 SCIE EI CAS CSCD 2023年第12期4749-4755,共7页
有机超长室温磷光聚合物因其优异的可加工性、灵活性和可重复性等特点,在各种光电应用中表现出巨大的应用潜力.然而,实现全彩的室温磷光仍然是一个挑战.在本文中,我们通过在聚乙烯醇中掺杂不同浓度的三苯基膦盐,成功制备了一系列余晖颜... 有机超长室温磷光聚合物因其优异的可加工性、灵活性和可重复性等特点,在各种光电应用中表现出巨大的应用潜力.然而,实现全彩的室温磷光仍然是一个挑战.在本文中,我们通过在聚乙烯醇中掺杂不同浓度的三苯基膦盐,成功制备了一系列余晖颜色可调的有机室温磷光聚合物(从蓝色到红色).实验和理论计算证明:室温磷光聚合物颜色的宽范围调控归因于掺杂体膦盐分子间的电子耦合作用大小.此外,这些多彩的磷光聚合物可应用于柔性3D显示和防伪. 展开更多
关键词 electronic coupling room-temperature phosphorescence polymer continuous RTP band tuning full-color RTP secure information printing
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二叠纪-三叠纪之交深水海洋环境生态系统工程 被引量:2
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作者 张立军 党志英 +1 位作者 李飞洋 杨琦琦 《科学通报》 EI CAS CSCD 北大核心 2021年第33期4295-4306,共12页
发生在距今约252.28 Ma的二叠纪末生物大灭绝事件是显生宙中最大的生物危机,导致了陆地和海洋约3/4的物种灭绝.旧的海陆生态系统几乎崩溃,但生物群体对环境恶化的应对策略和海洋生态系统工程仍不确定.本研究从生物学和生态学的角度出发... 发生在距今约252.28 Ma的二叠纪末生物大灭绝事件是显生宙中最大的生物危机,导致了陆地和海洋约3/4的物种灭绝.旧的海陆生态系统几乎崩溃,但生物群体对环境恶化的应对策略和海洋生态系统工程仍不确定.本研究从生物学和生态学的角度出发,以深水海洋环境遗迹化石为研究对象,通过实际资料和文献调研建立了二叠纪-三叠纪深水海洋环境遗迹化石和生物扰动数据库.依据遗迹化石反映的生物运动能力、觅食策略、生物与沉积物相互作用的方式、生物改造沉积物的方式,构建出二叠纪-三叠纪之交深水海洋环境生态空间利用和生态系统工程的三维空间模型.研究结果发现深水海洋环境遗迹多样性、遗迹歧异度、生态空间利用立方体和生态系统工程立方体并未有显著的丢失现象.乐平世至中三叠世深水海洋环境生态系统仍处于一个相对稳定的状态,其中非选择型食沉积物(觅食策略)、自由型(运动能力)、巷道型运输者(生物改造沉积物的方式)和压实作用(生物与沉积物相互作用方式)是二叠纪-三叠纪之交最为常见的深水海洋环境生态工程建造者,代表着生态级次较高的生态工程建造者,控制着深水海洋环境生态系统中的资源流动和物理化学环境的变化. 展开更多
关键词 二叠纪-三叠纪之交 深水海洋环境 生态空间利用 生态系统工程 遗迹化石
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寿命可调的有机室温磷光材料实现大面积安全打印 被引量:2
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作者 佘鹏飞 秦妍妍 +8 位作者 马云 李飞阳 陆金玉 戴佩伶 胡豪 刘向杰 刘淑娟 黄维 赵强 《Science China Materials》 SCIE EI CAS CSCD 2021年第6期1485-1494,共10页
有机室温磷光材料因其独特的光物理性质,在安全记录和防伪领域展现出了巨大的应用前景.然而,基于这类材料制备的防伪图案或标签存在分辨低、安全性低、不易大面积加工等缺点,极大地限制了其大规模商业化应用.本文设计、合成了一系列含... 有机室温磷光材料因其独特的光物理性质,在安全记录和防伪领域展现出了巨大的应用前景.然而,基于这类材料制备的防伪图案或标签存在分辨低、安全性低、不易大面积加工等缺点,极大地限制了其大规模商业化应用.本文设计、合成了一系列含不同长度烷基链的有机膦盐来解决以上问题.这类有机膦盐晶体中存在较强的分子内/间相互作用,使得它们具有高结晶能力,因此在经过研磨后仍然具有超长室温磷光.此外,通过改变烷基链长度和卤素离子,实现了室温磷光寿命的大范围调控(从1.27 ms到884.71 ms),并利用商用喷墨打印机成功实现了多重信息加密和防伪. 展开更多
关键词 persistent room-temperature phosphorescence organic salts tunable lifetime large-area processability security printing
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