A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differ...A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differentiation mechanism between polymetallic deposits(Ni-Mo and V),the Zhijin Gezhongwu profile located in the outer shelf and the Sansui Haishan V deposit located in the lower slope are selected to study the in situ sulfur isotopes and trace elements of pyrite.The results show that δ^(34)S values of pyrite vary widely from−7.8‰to 28‰in the Gezhongwu profile,while the δ^(34)S values are relatively uniform(from 27.8‰to 38.4‰)in the Haishan profile.The isotopic S composition is consistent with the transition that occurs in the sedimentary phase from the shelf to the deep sea on the transgressive Yangtze platform;this indicates that the δ^(34)SO_(4)^(2−)values in seawater must be differently distributed in depositional environments.The sulfur in the Ni-Mo layer is produced after the mixing of seawater and hydrothermal fluid,while the V layer mainly originates from seawater.Overall,the Ni-Mo and V deposits have been differentiated primarily on the basis of the combined effect of continental weathering and hydrothermal fluid.展开更多
To investigate the corrosion degradation law and service life of reinforced concrete in various salt solution environments,reinforced concrete specimens were semi-immersed in 3%Na_(2)CO_(3)(N3-0-0),3%Na_(2)CO_(3)+3%Na...To investigate the corrosion degradation law and service life of reinforced concrete in various salt solution environments,reinforced concrete specimens were semi-immersed in 3%Na_(2)CO_(3)(N3-0-0),3%Na_(2)CO_(3)+3%NaCl(N3-Cl3-0)and 3%Na_(2)CO_(3)+3%NaCl+3%Na_(2)SO_(4)(N3-Cl3-S3)salt solutions.The electrochemical workstation was used for regular non-destructive testing,and the polarization curve and related electrochemical parameters were used as the macroscopic durability evaluation indicators,while microscopic analysis of steel bar corrosion products was performed in combination with SEM and EDS.In addition,the corrosion current density degradation model of GM(1,1)was established and compared with the modified GM(1,1)-Markov degradation model.The results showed that the prediction error of the GM(1,1)-Markov model was smaller and more accurate than that of GM(1,1).The reinforced concrete specimens in the N3-0-0,N3-Cl3-0 and N3-Cl3-S3 solutions reached the failure state in 3.08,1.67,and 2.30 years,respectively,as predicted by the GM(1,1)-Markov model.According to ESM and EDS microscopic analysis of reinforcement,carbonate had no significant effect on reinforcement corrosion,chloride ions played a dominant role in reinforcement corrosion,and sulfate ion improved concrete's resistance to chloride ion corrosion.Based on GM(1,1)-Markov model,the failure and damage of reinforced concrete in saline soil areas can be quantitatively evaluated in the whole life cycle,which provides a theoretical basis for the early maintenance or reinforcing of reinforced concrete.展开更多
文摘【目的】奥陶纪生物大辐射事件(Great Ordovician Biodiversification Event,GOBE)是海洋环境与生物相互作用的结果,通过对该时期碳酸盐台地沉积相和层序的研究可揭示其形成与演化过程及海平面变化历史,并为奥陶纪生物时空分布特征及演化规律的探讨提供沉积背景和等时地层格架。【方法】在野外露头剖面实测和显微镜下观察的基础上,识别了黔北地区瓢儿田剖面下奥陶统(桐梓组和红花园组)的岩相类型,进一步分析了沉积模式和高频米级沉积旋回及沉积层序,最后探讨了沉积演化过程中的控制因素。【结果和结论】(1)瓢儿田剖面下奥陶统发育10种岩相类型,主要形成于碳酸盐缓坡沉积体系,且桐梓组和红花园组沉积时期分别以非骨架碳酸盐颗粒和骨架碳酸盐颗粒为特征;(2)桐梓组和红花园组主要发育非对称性的开阔海沉积旋回;(3)识别出3个半三级层序(Sq1~Sq4),每个三级层序均为Ⅱ型层序界面(即岩性转换面)所限。其中Sq1~Sq3为完整的三级层序,由海侵体系域(Transgressive Systems Tract,TST)和海退体系域(Regressive Systems Tract,RST)构成,但Sq4仅发育TST;(4)瓢儿田剖面下奥陶统的沉积演化和层序发育主要受不同级次的相对海平面变化和古地理格局的共同控制。其中不同级次相对海平面波动制约着沉积相的垂向演化,古地理格局则控制着沉积相带的空间分布。
基金supported by the National Natural Science Foundation of China(Grant Nos.42272103,92062221,42063009,U1812402)the Guizhou Provincial Science and Technology Projects(Grant No.Qiankehejichu–ZK[2022]common 213)the Higher Education Scientific Research Projects of the Education Department of Guizhou Province(Grant No.Qianjiaoji[2022]157).
文摘A polymetallic layer is usually developed at the bottom of the early Cambrian black shale in Guizhou Province.The mineral that makes up the polymetallic layer is related to the sedimentary facies.To analyze the differentiation mechanism between polymetallic deposits(Ni-Mo and V),the Zhijin Gezhongwu profile located in the outer shelf and the Sansui Haishan V deposit located in the lower slope are selected to study the in situ sulfur isotopes and trace elements of pyrite.The results show that δ^(34)S values of pyrite vary widely from−7.8‰to 28‰in the Gezhongwu profile,while the δ^(34)S values are relatively uniform(from 27.8‰to 38.4‰)in the Haishan profile.The isotopic S composition is consistent with the transition that occurs in the sedimentary phase from the shelf to the deep sea on the transgressive Yangtze platform;this indicates that the δ^(34)SO_(4)^(2−)values in seawater must be differently distributed in depositional environments.The sulfur in the Ni-Mo layer is produced after the mixing of seawater and hydrothermal fluid,while the V layer mainly originates from seawater.Overall,the Ni-Mo and V deposits have been differentiated primarily on the basis of the combined effect of continental weathering and hydrothermal fluid.
基金Funded by National Natural Science Foundation of China(No.52178216)Gansu Provincial Science and Technology Programme(No.23JRRA813)。
文摘To investigate the corrosion degradation law and service life of reinforced concrete in various salt solution environments,reinforced concrete specimens were semi-immersed in 3%Na_(2)CO_(3)(N3-0-0),3%Na_(2)CO_(3)+3%NaCl(N3-Cl3-0)and 3%Na_(2)CO_(3)+3%NaCl+3%Na_(2)SO_(4)(N3-Cl3-S3)salt solutions.The electrochemical workstation was used for regular non-destructive testing,and the polarization curve and related electrochemical parameters were used as the macroscopic durability evaluation indicators,while microscopic analysis of steel bar corrosion products was performed in combination with SEM and EDS.In addition,the corrosion current density degradation model of GM(1,1)was established and compared with the modified GM(1,1)-Markov degradation model.The results showed that the prediction error of the GM(1,1)-Markov model was smaller and more accurate than that of GM(1,1).The reinforced concrete specimens in the N3-0-0,N3-Cl3-0 and N3-Cl3-S3 solutions reached the failure state in 3.08,1.67,and 2.30 years,respectively,as predicted by the GM(1,1)-Markov model.According to ESM and EDS microscopic analysis of reinforcement,carbonate had no significant effect on reinforcement corrosion,chloride ions played a dominant role in reinforcement corrosion,and sulfate ion improved concrete's resistance to chloride ion corrosion.Based on GM(1,1)-Markov model,the failure and damage of reinforced concrete in saline soil areas can be quantitatively evaluated in the whole life cycle,which provides a theoretical basis for the early maintenance or reinforcing of reinforced concrete.
