In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the elec...In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the electrical discharge plasma are reviewed, and their possible roles in the degradation of contaminants are discussed. Measurement methods for the quantification of important reactive species and their advantages and shortcomings are presented. Approaches on how to enhance the diffusion of the reactive species in solution are examined. In addition, the formation of typical reactive species in different electrical discharge plasma is compared.展开更多
To improve the phosphorus(P)recovery efficiency from livestock wastewater,a novel MgO doped mildewed corn biochar with thermal pre-puffing treatment(Mg-PBC)and without pre-puffing(Mg-BC)was synthesized and tested.The ...To improve the phosphorus(P)recovery efficiency from livestock wastewater,a novel MgO doped mildewed corn biochar with thermal pre-puffing treatment(Mg-PBC)and without pre-puffing(Mg-BC)was synthesized and tested.The thermal-puffing pretreatment improved the effectiveness of metal soaking and MgO dispersion.P recovery time with Mg-PBC(7 h)was significantly shorter than that with Mg-BC(12 h).Moreover,Mg-PBC showed significantly higher P recovery capacity(241 mg g^(−1))than Mg-BC(96.6 mg g^(−1)).P recovery capacity of the Mg-PBC fitted to the Thomas model was 90.7 mg g^(−1),which was 4 times higher than that of Mg-BC(22.9 mg g^(−1))under column test conditions.The mechanisms involved in P recovery included precipitation,surface complexation,and electrostatic interaction.After adsorption,both Mg-BC and Mg-PBC showed relatively low regeneration abilities.The P loaded Mg-BC(Mg-BC-P)and Mg-PBC(Mg-PBC-P),the later particularly,obviously increased the available P content and promoted plant growth.The release of P increased with time in the Mg-PBC-P treated soil,while it decreased with time in the P fertilizer treated soil.A cost-benefit analysis revealed that thermal-puffing pretreatment greatly increased the profit of MgO doped biochar from−0.66 to 5.90 US$kg^(−1).These findings highlight that biomass pre-puffing is a feasible treatment to produce MgO modified biochar and to recover P from livestock wastewater,and that the Mg-PBC-P can be used as a slow-release P fertilizer.展开更多
基金funded by National Natural Science Foundation of China (Nos. 51608448 and 21737003)Young Talent Cultivation Scheme Funding of Northwest A&F University (No. Z109021802)the Fundamental Research Funds for the Central Universities (No. Z109021617) for their financial support in this research
文摘In the electrical discharge plasma process, various chemical and physical processes can participate in the removal of contaminants. In this paper, the chemical and physical processes that occur as a result of the electrical discharge plasma are reviewed, and their possible roles in the degradation of contaminants are discussed. Measurement methods for the quantification of important reactive species and their advantages and shortcomings are presented. Approaches on how to enhance the diffusion of the reactive species in solution are examined. In addition, the formation of typical reactive species in different electrical discharge plasma is compared.
基金The National Natural Science Foundation of China(32172679)Open Research Project of Ningxia Key Laboratory for the Development and Application of Microbial Resources in Extreme Environments,China(NXTS05)financially supported this work.
文摘To improve the phosphorus(P)recovery efficiency from livestock wastewater,a novel MgO doped mildewed corn biochar with thermal pre-puffing treatment(Mg-PBC)and without pre-puffing(Mg-BC)was synthesized and tested.The thermal-puffing pretreatment improved the effectiveness of metal soaking and MgO dispersion.P recovery time with Mg-PBC(7 h)was significantly shorter than that with Mg-BC(12 h).Moreover,Mg-PBC showed significantly higher P recovery capacity(241 mg g^(−1))than Mg-BC(96.6 mg g^(−1)).P recovery capacity of the Mg-PBC fitted to the Thomas model was 90.7 mg g^(−1),which was 4 times higher than that of Mg-BC(22.9 mg g^(−1))under column test conditions.The mechanisms involved in P recovery included precipitation,surface complexation,and electrostatic interaction.After adsorption,both Mg-BC and Mg-PBC showed relatively low regeneration abilities.The P loaded Mg-BC(Mg-BC-P)and Mg-PBC(Mg-PBC-P),the later particularly,obviously increased the available P content and promoted plant growth.The release of P increased with time in the Mg-PBC-P treated soil,while it decreased with time in the P fertilizer treated soil.A cost-benefit analysis revealed that thermal-puffing pretreatment greatly increased the profit of MgO doped biochar from−0.66 to 5.90 US$kg^(−1).These findings highlight that biomass pre-puffing is a feasible treatment to produce MgO modified biochar and to recover P from livestock wastewater,and that the Mg-PBC-P can be used as a slow-release P fertilizer.
