Magnesium-based energy materials, which combine promising energy-related functional properties with low cost, environmental compatibility and high availability, have been regarded as fascinating candidates for sustain...Magnesium-based energy materials, which combine promising energy-related functional properties with low cost, environmental compatibility and high availability, have been regarded as fascinating candidates for sustainable energy conversion and storage. In this review,we provide a timely summary on the recent progress in three types of important Mg-based energy materials, based on the fundamental strategies of composition and structure engineering. With regard to Mg-based materials for batteries, we systematically review and analyze different material systems, structure regulation strategies as well as the relevant performance in Mg-ion batteries(MIBs) and Mg-air batteries(MABs), covering cathodes, electrolytes, anodes for MIBs, and anodes for MABs;as to Mg-based hydrogen storage materials, we discuss how catalyst adding, composite, alloying and nanostructuring improve the kinetic and thermodynamic properties of de/hydrogenation reactions, and in particular, the impacts of composition and structure modification on hydrogen absorption/dissociation processes and free energy modification mechanism are focused;regarding Mg-based thermoelectric materials, the relations between composition/structure and electrical/thermal transport properties of Mg_(3)X_(2)(X = Sb, Bi), Mg_(2)X(X = Si, Ge, Sn) and Mg Ag Sb-based materials, together with the representative research progress of each material system, are summarized and discussed. Finally, by pointing out remaining challenges and providing possible solutions, this review aims to shed light on the directions and perspectives for practical applications of magnesium-based energy materials in the future.展开更多
Mg_(3)Sb_(2)has attracted intensive attention as a typical Zintl-type thermoelectric material.Despite the exceptional thermoelectric performance in n-type Mg_(3)Sb_(2),the dimensionless figure of merit(zT)of p-type Mg...Mg_(3)Sb_(2)has attracted intensive attention as a typical Zintl-type thermoelectric material.Despite the exceptional thermoelectric performance in n-type Mg_(3)Sb_(2),the dimensionless figure of merit(zT)of p-type Mg_(3)Sb_(2)remains lower than 1,which is mainly attributed to its inferior electrical properties.Herein,we synergistically optimize the thermoelectric properties of p-type Mg_(3)Sb_(2)materials via codoping of Cd and Ag,which were synthesized by high-energy ball milling combined with hot pressing.It is found that Cd doping not only increases the carrier mobility of p-type Mg_(3)Sb_(2),but also diminishes its thermal conductivity(κ_(tot)),with Mg_(2.85)Cd_(0.5)Sb_(2)achieving a lowκtot value of∼0.67 W m^(−1)K^(−1)at room temperature.Further Ag doping elevates the carrier concentration,so that the power factor is optimized over the entire temperature range.Eventually,a peak zT of∼0.75 at 773 K and an excellent average zT of∼0.41 over 300−773 K are obtained in Mg_(2.82)Ag_(0.03)Cd_(0.5)Sb_(2),which are∼240%and∼490%higher than those of pristine Mg_(3.4)Sb_(2),respectively.This study provides an effective pathway to synergistically improve the thermoelectric performance of p-type Mg_(3)Sb_(2)by codoping Cd and Ag,which is beneficial to the future applications of Mg_(3)Sb_(2)-based thermoelectric materials.展开更多
As chondroitinase ABC can improve the hostile microenvironment and cell transplantation is proven to be effective after spinal cord injury, we hypothesized that their combination would be a more effective treatment op...As chondroitinase ABC can improve the hostile microenvironment and cell transplantation is proven to be effective after spinal cord injury, we hypothesized that their combination would be a more effective treatment option. At 5 days after T8 spinal cord crush injury, rats were injected with bone marrow mesenchymal stem cell suspension or chondroitinase ABC 1 mm from the edge of spinal cord damage zone. Chondroitinase ABC was first injected, and bone marrow mesenchymal stem cell suspension was injected on the next day in the combination group. At 14 days, the mean Basso, Beattie and Bresnahan score of the rats in the combination group was higher than other groups. Hematoxylin-eosin staining showed that the necrotic area was significantly reduced in the combination group compared with other groups. Glial fibrillary acidic protein-chondroitin sulfate proteoglycan double staining showed that the damage zone of astrocytic scars was significantly reduced without the cavity in the combination group. Glial fibrillary acidic protein/growth associated protein-43 double immunostaining revealed that positive fibers traversed the damage zone in the combination group. These results suggest that the combination of chondroitinase ABC and bone marrow mesenchymal stem cell transplantation contributes to the repair of spinal cord injury.展开更多
The dynamic stall problem for blades is related to the general performance of wind turbines,where a varying flow field is introduced with a rapid change of the effective angle of attack (AOA).The objective of this wor...The dynamic stall problem for blades is related to the general performance of wind turbines,where a varying flow field is introduced with a rapid change of the effective angle of attack (AOA).The objective of this work is to study the aerodynamic performance of a sinusoidally oscillating NACA0012 airfoil.The coupled k-ω Menter's shear stress transport (SST) turbulence model and γ-Reθ transition model were used for turbulence closure.Lagrangian coherent structures (LCS) were utilized to analyze the dynamic behavior of the flow structures.The computational results were supported by the experiments.The results indicated that this numerical method can well describe the dynamic stall process.For the case with reduced frequency K =0.1,the lift and drag coefficients increase constantly with increasing angle prior to dynamic stall.When the AOA reaches the stall angle,the lift and drag coefficients decline suddenly due to the interplay between the first leading-and trailing-edge vortex.With further increase of the AOA,both the lift and drag coefficients experience a secondary rise and fall process because of formation and shedding of the secondary vortex.The results also reveal that the dynamic behavior of the flow structures can be effectively identified using the finite-time Lyapunov exponent (FTLE) field.The influence of the reduced frequency on the flow structures and energy extraction efficiency in the dynamic stall process is further discussed.When the reduced frequency increases,the dynamic stall is delayed and the total energy extraction efficiency is enhanced.With K =0.05,the amplitude of the dynamic coefficients fluctuates more significantly in the poststall process than in the case of K =0.1.展开更多
To better understand the multiphase fluid dynamics and associated transport processes of cavitating flows at the capillary number of 0.74 and 0.54, and to validate the numerical results, a combined computational and e...To better understand the multiphase fluid dynamics and associated transport processes of cavitating flows at the capillary number of 0.74 and 0.54, and to validate the numerical results, a combined computational and experimental investigation of flows around a hydrofoil is studied based on flow visualizations and time-resolved interface movement. The computational model is based on a modified RNG k-ε model as turbulence closure, along with a vapor-liquid mass transfer model for treating the cavitation process. Overall, favorable agreement between the numerical and experimental results is observed. It is shown that the cavi- tation structure depends on the interaction of the water-vapor mixture and the vapor among the whole cavitation stage, the interface between the vapor and the two-phase mixture exhibits substantial unsteadiness. And, the adverse motion of the interface relates to pressure and velocity fluctuations inside the cavity. In particular, the velocity in the vapor region is lower than that in the two-phase region.展开更多
Indium selenide,aⅢ–Ⅴgroup semiconductor with layered structure,attracts intense attention in various photoelectric applications,due to its outstanding properties.Here,we report super deformability and thermoelectri...Indium selenide,aⅢ–Ⅴgroup semiconductor with layered structure,attracts intense attention in various photoelectric applications,due to its outstanding properties.Here,we report super deformability and thermoelectricity ofγ-In Se single crystals grown by modified Bridgeman method.The crystal structure of In Se is studied systematically by transmission electron microscopy methods combined with x-ray diffraction and Raman spectroscopy.The predominate phase ofγ-In Se with dense stacking faults and local multiphases is directly demonstrated at atomic scale.The bulkγ-In Se crystals demonstrate surprisingly high intrinsic super deformative ability which is highly pliable with bending strains exceeding12.5%and 264%extension by rolling.At the meantime,In Se also possesses graphite-like features which is printable,writable,and erasable.Finally,the thermoelectric properties ofγ-In Se bulk single crystals are preliminary studied and thermal conductivity can be further reduced via bending-induced defects.These findings will enrich the knowledge of structural and mechanical properties'flexibility of In Se and shed lights on the intrinsic and unique mechanical properties of In Se polytypes.展开更多
Magnesium-based materials have been regarded as promising candidates for large-scale,high-efficiency thermoelectric applications,owing to their excellent dimensionless figure of merit,high abundance,and low cost.In th...Magnesium-based materials have been regarded as promising candidates for large-scale,high-efficiency thermoelectric applications,owing to their excellent dimensionless figure of merit,high abundance,and low cost.In this review,we comprehensively summarize the recent advances of Mg-based thermoelectrics,including Mg_(2)X(X=Si,Ge,Sn),Mg3(Sb,Bi)_(2),andα-MgAgSb,from both material and device level.Their electrical and thermal transport properties are first elucidated based on the crystallographic characteristics,band structures,and phonon dispersions.We then review the optimization strategies towards higher thermoelectric performance,as well as the device applications of Mg-based thermoelectric materials and the related engineering issues.By highlighting the challenges and possible solutions in the end,this review intends to offer perspectives on the future research work to further enhance the performance of Mg-based materials for practical applications.展开更多
It is potentially useful to perform deception jamming using the digital image synthesizer （DIS） since it can form a two-dimensional （2D） decoy but suffers from multiple decoys ge- neration. Inspired by the intermi...It is potentially useful to perform deception jamming using the digital image synthesizer （DIS） since it can form a two-dimensional （2D） decoy but suffers from multiple decoys ge- neration. Inspired by the intermittent sampling repeater jamming （ISRJ）, the generation of inverse synthetic aperture radar （ISAR） decoys is addressed, associated with the DIS and the ISRJ. Radar pulses are sampled intermittently and modulated by the scatter- ing model of a false target by mounting the jammer on a moving platform, and then the jamming signals are retransmitted to the radar and a train of decoys are induced after ISAR imaging. A scattering model of Yak-42 is adopted as the false-target mo- dulation model to verify the effectiveness of the jamming method based on the standard ISAR motion compensation and image for- mation procedure.展开更多
BACKGROUND： Olfactory ensheathing cell （OEC） transplantation promotes repair of spinal cord injury. Neural regeneration inhibits binding of the myelin protein Nogo to its receptor （NgR）, activates downstream inhi...BACKGROUND： Olfactory ensheathing cell （OEC） transplantation promotes repair of spinal cord injury. Neural regeneration inhibits binding of the myelin protein Nogo to its receptor （NgR）, activates downstream inhibitory signal RhoA, and leads to axonal degeneration. OBJECTIVE： To determine the relationship between OECs transplantation for spinal cord injury and NogoA, NgR, and RhoA protein expression in the damaged zone. DESIGN, TIME AND SETTING： A randomized, controlled, animal experiment was performed from September 2006 to May 2007 at the Key Laboratory of Environment and Genes in Xi＇an Jiaotong University School of Medicine, China. MATERIALS： OECs were harvested from healthy, adult, male, Sprague Dawley rats aged 6 months. Mouse anti-rat NogoA, NgR, and RheA monoclonal antibodies were utilized for detection. METHODS： A total of 40 adult Sprague Dawley rats were randomly assigned to four groups： normal, model, OECs, and DF12, with 10 animals in each group. Transverse section spinal cord injury was established in the OECs and DF12 groups, followed by injection of 1μL OECs suspension （1×10^8/mL） or equivalent DF12 medium at 1 mm above and below the injury site. MAIN OUTCOME MEASURES： Immunohistochemistry and Western blot were utilized to detect NogoA, NgR, and RhoA expression in the spinal cord injury lesions. Morphological changes were observed by argyrophilia staining, and lower extremity function of the animals was assessed using Basso, Beattie, and Bresnahan scores. RESULTS： Eight weeks following OECs transplantation, a significant increase in new axons was observed in the OECs group, and nerve fibers crossed the injury site to repair spinal cord injury. Qualitative and quantitative results from the OECs group were superior to the model and DF12 groups. At 8 weeks after transplantation, Basso, Beattie, and Bresnahan scores were significantly greater in the OECs group compared with the model and DF12 groups （P 〈 0.01）, but expression of NogoA, NgR, and RhoA protein was significantly decreased compared with the model and DF12 groups （P〈 0.05）. CONCLUSION： OEC transplantation could inhibit NogoA, NgR, and RhoA expression in spinal cord injury lesions, thereby promoting repair of spinal cord injury.展开更多
Cavitation–structure interaction has become one of the major issues for most engineering applications. The present work reviews recent progress made toward developing experimental and numerical investigation for unst...Cavitation–structure interaction has become one of the major issues for most engineering applications. The present work reviews recent progress made toward developing experimental and numerical investigation for unsteady turbulent cavitating flow and cavitation–structure interaction. The goal of our overall efforts is to（1） summarize the progress made in the experimental and numerical modeling and approaches for unsteady cavitating flow and cavitation–structure interaction,（2） discuss the global multiphase structures for different cavitation regimes, with special emphasis on the unsteady development of cloud cavitation and corresponding cavitating flow-induced vibrations,with a high-speed visualization system and a structural vibration measurement system, as well as a simultaneous sampling system,（3） improve the understanding of the hydroelastic response in cavitating flows via combined physical and numerical analysis, with particular emphasis on the interaction between unsteady cavitation development and structural deformations. Issues including unsteady cavitating flow structures and cavitation–structure interaction mechanism are discussed.展开更多
A local vortical cavitation（LVC） model for the computation of unsteady cavitation is proposed.The model is derived from the Rayleigh–Plesset equations,and takes into account the relations between the cavitation bub...A local vortical cavitation（LVC） model for the computation of unsteady cavitation is proposed.The model is derived from the Rayleigh–Plesset equations,and takes into account the relations between the cavitation bubble radius and local vortical effects.Calculations of unsteady cloud cavitating fows around a Clark-Y hydrofoil are performed to assess the predictive capability of the LVC model using well-documented experimental data.Compared with the conventional Zwart＇s model,better agreement is observed between the predictions of the LVC model and experimental data,including measurements of time-averaged fl w structures,instantaneous cavity shapes and the frequency of the cloud cavity shedding process.Based on the predictions of the LVC model,it is demonstrated that the evaporation process largely concentrates in the core region of the leading edge vorticity in accordance with the growth in the attached cavity,and the condensation process concentrates in the core region of the trailing edge vorticity,which corresponds to the spread of the rear component of the attached cavity.When the attached cavity breaks up and moves downstream,the condensation area fully transports to the wake region,which is in accordance with the dissipation of the detached cavity.Furthermore,using vorticity transport equations,we also fin that the periodic formation,breakup,and shedding of the sheet/cloud cavities,along with the associated baroclinic torque,are important mechanisms for vorticity production and modification When the attached cavity grows,the liquid–vapour interface that moves towards the trailing edge enhances the vorticity in the attached cav-ity closure region.As the re-entrant jet moves upstream,the wavy/bubbly cavity interface enhances the vorticity near the trailing edge.At the end of the cycle,the break-up of the stable attached cavity is the main reason for the vorticity enhancement near the suction surface.展开更多
The objective of this paper is to address the transient flow structures around a pitching hydrofoil by com- bining physical and numerical studies. In order to predict the dynamic behavior of the flow structure effecti...The objective of this paper is to address the transient flow structures around a pitching hydrofoil by com- bining physical and numerical studies. In order to predict the dynamic behavior of the flow structure effectively, the Lagrangian coherent structures （LCS） defined by the ridges of the finite-time Lyapunov exponent （FTLE） are utilized under the framework of Navier-Stokes flow computations. In the numerical simulations, the k-w shear stress trans- port （SST） turbulence model, coupled with a two-equation F-Reo transition model, is used for the turbulence closure. Results are presented for a NACA66 hydrofoil undergoing slowly and rapidly pitching motions from 0° to 15° then back to 0° at a moderate Reynolds number Re = 7.5 × 105. The results reveal that the transient flow structures can be observed by the LCS method. For the slowly pitching case, it consists of five stages： quasi-steady and laminar, transition from laminar to turbulent, vortex development, large-scale vortex shedding, and reverting to laminar. The observation of LCS and Lagrangian particle tracers elucidates that the trailing edge vortex is nearly attached and stable during the vortex development stage and the interaction between the leading and trailing edge vortex caused by the adverse pres- sure gradient forces the vortexes to shed downstream during the large-scale vortex shedding stage, which corresponds to obvious fluctuations of the hydrodynamic response. For the rapidly pitching case, the inflection is hardly to be observed and the stall is delayed. The vortex formation, interaction, and shedding occurred once instead of being repeated three times, which is responsible for just one fluctuation in the hydrody- namic characteristics. The numerical results also show that the FTLE field has the potential to identify the transient flows, and the LCS can represent the divergence extent of infinite neighboring particles and capture the interface of the vortex region.展开更多
The rotational parameters estimation of maneuvering target is the key of cross-range scaling of ISAR （inverse synthetic aperture radar）, which can be used in the target feature extraction. The cross-range signal mod...The rotational parameters estimation of maneuvering target is the key of cross-range scaling of ISAR （inverse synthetic aperture radar）, which can be used in the target feature extraction. The cross-range signal model of rotating target with fixed acceleration is presented and the weighted linear least squares estimation of rotational parameters with fixed velocity or acceleration is proposed via the relationship of cross-range FM （frequency modulation） parameter, scatterers coordinates and rotational parameters. The FM parameter is calculated via RWT （Radon-Wigner transform）. The ISAR imaging and cross-range scaling based on scaled RWT imaging method are implemented after obtaining rotational parameters. The rotational parameters estimation and cross-range scaling are validated by the ISAR processing of experimental radar data, and the method presents good application foreground to the ISAR imaging and scaling of maneuvering target.展开更多
By using first-principles electronic structure calculations, we have studied the magnetic interactions in a proposed BaZn2P2-based diluted magnetic semiconductor（DMS）. For a typical compound Ba（Zn（0.944）Mn（0.05...By using first-principles electronic structure calculations, we have studied the magnetic interactions in a proposed BaZn2P2-based diluted magnetic semiconductor（DMS）. For a typical compound Ba（Zn（0.944）Mn（0.056））2P2 with only spin doping, due to the superexchange interaction between Mn atoms and the lack of itinerant carriers, the short-range antiferromagnetic coupling dominates. Partially substituting K atoms for Ba atoms, which introduces itinerant hole carriers into the p orbitals of P atoms so as to link distant Mn moments with the spin-polarized hole carriers via the p–d hybridization between P and Mn atoms, is very crucial for the appearance of ferromagnetism in the compound. Furthermore, applying hydrostatic pressure first enhances and then decreases the ferromagnetic coupling in（Ba0.75 K0.25）（Zn（0.944）Mn（0.056））2P2 at a turning point around 15 GPa, which results from the combined effects of the pressure-induced variations of electron delocalization and p–d hybridization. Compared with the BaZn2 As2-based DMS, the substitution of P for As can modulate the magnetic coupling effectively. Both the results for BaZn2 P2-based and BaZn2As2-based DMSs demonstrate that the robust antiferromagnetic（AFM） coupling between the nearest Mn–Mn pairs bridged by anions is harmful to improving the performance of these Ⅱ–Ⅱ–Ⅴ based DMS materials.展开更多
We have systematically studied the thermoelectric properties in Zn-doped Sn Te.Strikingly,band convergence and embedded precipitates arising from Zn doping,can trigger a prominent improvement of thermoelectric perform...We have systematically studied the thermoelectric properties in Zn-doped Sn Te.Strikingly,band convergence and embedded precipitates arising from Zn doping,can trigger a prominent improvement of thermoelectric performance.In particular,the value of dimensionless figure of merit z T has increased by 100% and up to ～ 0.5 at 775 K for the optimal sample with 2% Zn content.Present findings demonstrate that carrier concentration and effective mass play crucial roles on the Seebeck coefficient and power factor.The obvious deviation from the Pisarenko line（Seebeck coefficient versus carrier concentration） due to Zn-doping reveals the convergence of valence bands.When the doping concentration exceeds the solubility,precipitates occur and lead to a reduction of lattice thermal conductivity.In addition,bipolar conduction is suppressed,indicating an enlargement of band gap.The Zn-doped Sn Te is shown to be a promising candidate for thermoelectric applications.展开更多
A pipe model with a mass ratio（mass/displaced mass） of 4.30 was tested to investigate the vortex-induced vibrations of submarine pipeline spans near the seabed.The pipe model was designed as a bending stiffness-domi...A pipe model with a mass ratio（mass/displaced mass） of 4.30 was tested to investigate the vortex-induced vibrations of submarine pipeline spans near the seabed.The pipe model was designed as a bending stiffness-dominated beam.The gap ratios（gap to diameter ratio） at the pipe ends were 4.0,6.0,and 8.0.The flow velocity was systematically varied in the 0-16.71 nondimensional velocity range based on the first natural frequency.The mode transition between the first and the second mode as the flow velocity increases was investigated.At various transition flow velocities,the research indicates that the peak frequencies with respect to displacement are not identical along the pipe,nor the frequencies associated with the peak of the amplitude spectra for the first four modes as well.The mode transition is associated with a continuous change in the amplitude,but there＇s a jump in frequency,and a gradual process along the pipe length.展开更多
Binary Cu-based chalcogenide thermoelectric materials have attracted a great deal of attention due to their outstanding physical properties and fascinating phase sequence.However,the relatively low figure of merit z T...Binary Cu-based chalcogenide thermoelectric materials have attracted a great deal of attention due to their outstanding physical properties and fascinating phase sequence.However,the relatively low figure of merit z T restricts their practical applications in power generation.A general approach to enhancing z T value is to produce nanostructured grains,while one disadvantage of such a method is the expansion of grain size in heating-up process.Here,we report a prominent improvement of z T in Cu2Te（0.2）Se（0.8）,which is several times larger than that of the matrix.This significant enhancement in thermoelectric performance is attributed to the formation of abundant porosity via cold press.These pores with nano-to micrometer size can manipulate phonon transport simultaneously,resulting in an apparent suppression of thermal conductivity.Moreover,the Se substitution triggers a rapid promotion of power factor,which compensates for the reduction of electrical properties due to carriers scattering by pores.Our strategy of porosity engineering by phonon scattering can also be highly applicable in enhancing the performances of other thermoelectric systems.展开更多
Drought and water shortage are the biggest limiting factors of dry farming,and variety plays an important role in an increase in the yield of dryland maize.Screening high-yield maize varieties is helpful to the contin...Drought and water shortage are the biggest limiting factors of dry farming,and variety plays an important role in an increase in the yield of dryland maize.Screening high-yield maize varieties is helpful to the continuous increase and stable yield of dryland grain.In this experiment,the growth period,characters and yield of 12 maize varieties were analyzed.The results show that the yield of Ganyu series was low,while the yield of Lianda 169 was the highest(8 080.93 kg/ha),which was 31.40% higher than Jinsui 4.The yield of Dunyu 16 was6 621.06 kg/ha,7.64% higher than Jinsui 4.The two varieties had good comprehensive characters,so they could be popularized and planted in dry farming areas of Lanzhou City.展开更多
Keeping balance is the premise of human walking. ZMP(zero moment point) is a point where total torque achieves balance. It is an important evaluation parameter of balance ability in walking, since it can be used to be...Keeping balance is the premise of human walking. ZMP(zero moment point) is a point where total torque achieves balance. It is an important evaluation parameter of balance ability in walking, since it can be used to better reflect the dynamic balance during walking. ZMP can be used in many applications, such as medical rehabilitation, disease diagnosis, treatment and etc. In this paper, wearable inertial sensors system based on MEMS is used to measure ZMP(zero moment point) during walking, which is cheap, convenient, and free from the restriction of lab. Our wearable ZMP measurement system consists of inertial measurement subsystem and PC real-time monitoring station. Inertial measurement subsystem includes 9-axis inertial sensing nodes, the body communication network and the central node. Inertial sensing nodes are mounted on different parts of the body to collect body posture information in real-time, and then the best estimation of current posture are obtained by Kalman filter. The data from sensors is aggregated to the central node through the CAN bus, and then ZMP is calculated. Finally, it can be showed in the PC monitoring station. Experiments prove the system can achieve real-time ZMP detection during walking.展开更多
Tetrahedrite,an Earth-abundant natural mineral,has attracted extensive research interest because of its excellent thermoelectric performance.Herein,tetrahedrite samples comprising Cu-poor Cu_(12)Sb_(4)S_(13)and Cu-ric...Tetrahedrite,an Earth-abundant natural mineral,has attracted extensive research interest because of its excellent thermoelectric performance.Herein,tetrahedrite samples comprising Cu-poor Cu_(12)Sb_(4)S_(13)and Cu-rich Cu_(14)Sb_(4)S_(13)phases have been synthesized using a colloidal method,in which the ratio of two phases is manipulated by controlling the synthesis temperature to improve the thermoelectric perfor-mance.It is found that an ultralow total thermal conductivity of∼0.3 W m^(−1)K^(−1)at 723 K is realized in the sample with a Cu-rich phase fraction of∼50%,which can be attributed to maximized phonon scattering by phase boundaries.As a result,combined with a decent power factor,this sample obtains an optimal zT of 1.15,which is about 85%higher than that of the sample with a Cu-rich phase fraction of∼64%and comparable to zT values of other eco-friendly,abundant Cu-based thermoelectric materials.This work demonstrates an effective synthesis-temperature-dependent phase composition manipulation strategy toward enhanced thermoelectric performance in tetrahedrites.展开更多
基金financial support from the National Key Research and Development Program of China (No.2021YFB3502200)the National Natural Science Foundation of China (Grants Nos.52271202,51971040,52171101)+2 种基金the Shanghai Rising-Star Program (No.21QA1403200)supported by a start-up fund from Chongqing University (02110011044171)Liuchuang Program of Chongqing Municipality (cx2022038)。
文摘Magnesium-based energy materials, which combine promising energy-related functional properties with low cost, environmental compatibility and high availability, have been regarded as fascinating candidates for sustainable energy conversion and storage. In this review,we provide a timely summary on the recent progress in three types of important Mg-based energy materials, based on the fundamental strategies of composition and structure engineering. With regard to Mg-based materials for batteries, we systematically review and analyze different material systems, structure regulation strategies as well as the relevant performance in Mg-ion batteries(MIBs) and Mg-air batteries(MABs), covering cathodes, electrolytes, anodes for MIBs, and anodes for MABs;as to Mg-based hydrogen storage materials, we discuss how catalyst adding, composite, alloying and nanostructuring improve the kinetic and thermodynamic properties of de/hydrogenation reactions, and in particular, the impacts of composition and structure modification on hydrogen absorption/dissociation processes and free energy modification mechanism are focused;regarding Mg-based thermoelectric materials, the relations between composition/structure and electrical/thermal transport properties of Mg_(3)X_(2)(X = Sb, Bi), Mg_(2)X(X = Si, Ge, Sn) and Mg Ag Sb-based materials, together with the representative research progress of each material system, are summarized and discussed. Finally, by pointing out remaining challenges and providing possible solutions, this review aims to shed light on the directions and perspectives for practical applications of magnesium-based energy materials in the future.
基金financially supported by the National Natural Science Foundation of China (Grant No. 52071041, 11874356, 51802034)supported by the Key Research Program of Frontier Sciences, CAS (Grant No.QYZDB-SSW-SLH016)
文摘Mg_(3)Sb_(2)has attracted intensive attention as a typical Zintl-type thermoelectric material.Despite the exceptional thermoelectric performance in n-type Mg_(3)Sb_(2),the dimensionless figure of merit(zT)of p-type Mg_(3)Sb_(2)remains lower than 1,which is mainly attributed to its inferior electrical properties.Herein,we synergistically optimize the thermoelectric properties of p-type Mg_(3)Sb_(2)materials via codoping of Cd and Ag,which were synthesized by high-energy ball milling combined with hot pressing.It is found that Cd doping not only increases the carrier mobility of p-type Mg_(3)Sb_(2),but also diminishes its thermal conductivity(κ_(tot)),with Mg_(2.85)Cd_(0.5)Sb_(2)achieving a lowκtot value of∼0.67 W m^(−1)K^(−1)at room temperature.Further Ag doping elevates the carrier concentration,so that the power factor is optimized over the entire temperature range.Eventually,a peak zT of∼0.75 at 773 K and an excellent average zT of∼0.41 over 300−773 K are obtained in Mg_(2.82)Ag_(0.03)Cd_(0.5)Sb_(2),which are∼240%and∼490%higher than those of pristine Mg_(3.4)Sb_(2),respectively.This study provides an effective pathway to synergistically improve the thermoelectric performance of p-type Mg_(3)Sb_(2)by codoping Cd and Ag,which is beneficial to the future applications of Mg_(3)Sb_(2)-based thermoelectric materials.
文摘As chondroitinase ABC can improve the hostile microenvironment and cell transplantation is proven to be effective after spinal cord injury, we hypothesized that their combination would be a more effective treatment option. At 5 days after T8 spinal cord crush injury, rats were injected with bone marrow mesenchymal stem cell suspension or chondroitinase ABC 1 mm from the edge of spinal cord damage zone. Chondroitinase ABC was first injected, and bone marrow mesenchymal stem cell suspension was injected on the next day in the combination group. At 14 days, the mean Basso, Beattie and Bresnahan score of the rats in the combination group was higher than other groups. Hematoxylin-eosin staining showed that the necrotic area was significantly reduced in the combination group compared with other groups. Glial fibrillary acidic protein-chondroitin sulfate proteoglycan double staining showed that the damage zone of astrocytic scars was significantly reduced without the cavity in the combination group. Glial fibrillary acidic protein/growth associated protein-43 double immunostaining revealed that positive fibers traversed the damage zone in the combination group. These results suggest that the combination of chondroitinase ABC and bone marrow mesenchymal stem cell transplantation contributes to the repair of spinal cord injury.
基金the National Postdoctoral Program for Innovative Talents(Grant BX201700126)the China Postdoctoral Science Foundation(Grant 2017M620043)+1 种基金the National Natural Science Foundation of China(Grants 51679005 and 91752105)the National Natural Science Foundation of Beijing(Grant 3172029).
文摘The dynamic stall problem for blades is related to the general performance of wind turbines,where a varying flow field is introduced with a rapid change of the effective angle of attack (AOA).The objective of this work is to study the aerodynamic performance of a sinusoidally oscillating NACA0012 airfoil.The coupled k-ω Menter's shear stress transport (SST) turbulence model and γ-Reθ transition model were used for turbulence closure.Lagrangian coherent structures (LCS) were utilized to analyze the dynamic behavior of the flow structures.The computational results were supported by the experiments.The results indicated that this numerical method can well describe the dynamic stall process.For the case with reduced frequency K =0.1,the lift and drag coefficients increase constantly with increasing angle prior to dynamic stall.When the AOA reaches the stall angle,the lift and drag coefficients decline suddenly due to the interplay between the first leading-and trailing-edge vortex.With further increase of the AOA,both the lift and drag coefficients experience a secondary rise and fall process because of formation and shedding of the secondary vortex.The results also reveal that the dynamic behavior of the flow structures can be effectively identified using the finite-time Lyapunov exponent (FTLE) field.The influence of the reduced frequency on the flow structures and energy extraction efficiency in the dynamic stall process is further discussed.When the reduced frequency increases,the dynamic stall is delayed and the total energy extraction efficiency is enhanced.With K =0.05,the amplitude of the dynamic coefficients fluctuates more significantly in the poststall process than in the case of K =0.1.
基金supported by the National Natural Science Foundation of China (50679001)NASA Constellation University Institutes Program
文摘To better understand the multiphase fluid dynamics and associated transport processes of cavitating flows at the capillary number of 0.74 and 0.54, and to validate the numerical results, a combined computational and experimental investigation of flows around a hydrofoil is studied based on flow visualizations and time-resolved interface movement. The computational model is based on a modified RNG k-ε model as turbulence closure, along with a vapor-liquid mass transfer model for treating the cavitation process. Overall, favorable agreement between the numerical and experimental results is observed. It is shown that the cavi- tation structure depends on the interaction of the water-vapor mixture and the vapor among the whole cavitation stage, the interface between the vapor and the two-phase mixture exhibits substantial unsteadiness. And, the adverse motion of the interface relates to pressure and velocity fluctuations inside the cavity. In particular, the velocity in the vapor region is lower than that in the two-phase region.
基金the National Natural Science Foundation of China(Grant Nos.11674040,11604032,51472036,51672270,and 11904039)the Fundamental Research Funds for the Central Universities,China(Grant No.106112016CDJZR308808)Key Research Program of Frontier Sciences,Chinese Academy of Sciences(Grant No.QYZDB-SSW-SLH016)。
文摘Indium selenide,aⅢ–Ⅴgroup semiconductor with layered structure,attracts intense attention in various photoelectric applications,due to its outstanding properties.Here,we report super deformability and thermoelectricity ofγ-In Se single crystals grown by modified Bridgeman method.The crystal structure of In Se is studied systematically by transmission electron microscopy methods combined with x-ray diffraction and Raman spectroscopy.The predominate phase ofγ-In Se with dense stacking faults and local multiphases is directly demonstrated at atomic scale.The bulkγ-In Se crystals demonstrate surprisingly high intrinsic super deformative ability which is highly pliable with bending strains exceeding12.5%and 264%extension by rolling.At the meantime,In Se also possesses graphite-like features which is printable,writable,and erasable.Finally,the thermoelectric properties ofγ-In Se bulk single crystals are preliminary studied and thermal conductivity can be further reduced via bending-induced defects.These findings will enrich the knowledge of structural and mechanical properties'flexibility of In Se and shed lights on the intrinsic and unique mechanical properties of In Se polytypes.
基金financial support from the National Natural Science Foundation of China(Grant Nos.52125103,52071041,12104071,11874356,U21A2054)。
文摘Magnesium-based materials have been regarded as promising candidates for large-scale,high-efficiency thermoelectric applications,owing to their excellent dimensionless figure of merit,high abundance,and low cost.In this review,we comprehensively summarize the recent advances of Mg-based thermoelectrics,including Mg_(2)X(X=Si,Ge,Sn),Mg3(Sb,Bi)_(2),andα-MgAgSb,from both material and device level.Their electrical and thermal transport properties are first elucidated based on the crystallographic characteristics,band structures,and phonon dispersions.We then review the optimization strategies towards higher thermoelectric performance,as well as the device applications of Mg-based thermoelectric materials and the related engineering issues.By highlighting the challenges and possible solutions in the end,this review intends to offer perspectives on the future research work to further enhance the performance of Mg-based materials for practical applications.
基金supported by the National Natural Science Foundation of China(6137217061401491)
文摘It is potentially useful to perform deception jamming using the digital image synthesizer （DIS） since it can form a two-dimensional （2D） decoy but suffers from multiple decoys ge- neration. Inspired by the intermittent sampling repeater jamming （ISRJ）, the generation of inverse synthetic aperture radar （ISAR） decoys is addressed, associated with the DIS and the ISRJ. Radar pulses are sampled intermittently and modulated by the scatter- ing model of a false target by mounting the jammer on a moving platform, and then the jamming signals are retransmitted to the radar and a train of decoys are induced after ISAR imaging. A scattering model of Yak-42 is adopted as the false-target mo- dulation model to verify the effectiveness of the jamming method based on the standard ISAR motion compensation and image for- mation procedure.
基金Doctoral Fund of Ministry of Education of China,No.20050698043
文摘BACKGROUND： Olfactory ensheathing cell （OEC） transplantation promotes repair of spinal cord injury. Neural regeneration inhibits binding of the myelin protein Nogo to its receptor （NgR）, activates downstream inhibitory signal RhoA, and leads to axonal degeneration. OBJECTIVE： To determine the relationship between OECs transplantation for spinal cord injury and NogoA, NgR, and RhoA protein expression in the damaged zone. DESIGN, TIME AND SETTING： A randomized, controlled, animal experiment was performed from September 2006 to May 2007 at the Key Laboratory of Environment and Genes in Xi＇an Jiaotong University School of Medicine, China. MATERIALS： OECs were harvested from healthy, adult, male, Sprague Dawley rats aged 6 months. Mouse anti-rat NogoA, NgR, and RheA monoclonal antibodies were utilized for detection. METHODS： A total of 40 adult Sprague Dawley rats were randomly assigned to four groups： normal, model, OECs, and DF12, with 10 animals in each group. Transverse section spinal cord injury was established in the OECs and DF12 groups, followed by injection of 1μL OECs suspension （1×10^8/mL） or equivalent DF12 medium at 1 mm above and below the injury site. MAIN OUTCOME MEASURES： Immunohistochemistry and Western blot were utilized to detect NogoA, NgR, and RhoA expression in the spinal cord injury lesions. Morphological changes were observed by argyrophilia staining, and lower extremity function of the animals was assessed using Basso, Beattie, and Bresnahan scores. RESULTS： Eight weeks following OECs transplantation, a significant increase in new axons was observed in the OECs group, and nerve fibers crossed the injury site to repair spinal cord injury. Qualitative and quantitative results from the OECs group were superior to the model and DF12 groups. At 8 weeks after transplantation, Basso, Beattie, and Bresnahan scores were significantly greater in the OECs group compared with the model and DF12 groups （P 〈 0.01）, but expression of NogoA, NgR, and RhoA protein was significantly decreased compared with the model and DF12 groups （P〈 0.05）. CONCLUSION： OEC transplantation could inhibit NogoA, NgR, and RhoA expression in spinal cord injury lesions, thereby promoting repair of spinal cord injury.
基金supported by the National Natural Science Foundation of China (Grant 51679005)the Natural Science Foundation of Beijing Municipality (Grant 3172029)the Ph.D. Programs Foundation of Ministry of Education of China (Grant 20131101120014)
文摘Cavitation–structure interaction has become one of the major issues for most engineering applications. The present work reviews recent progress made toward developing experimental and numerical investigation for unsteady turbulent cavitating flow and cavitation–structure interaction. The goal of our overall efforts is to（1） summarize the progress made in the experimental and numerical modeling and approaches for unsteady cavitating flow and cavitation–structure interaction,（2） discuss the global multiphase structures for different cavitation regimes, with special emphasis on the unsteady development of cloud cavitation and corresponding cavitating flow-induced vibrations,with a high-speed visualization system and a structural vibration measurement system, as well as a simultaneous sampling system,（3） improve the understanding of the hydroelastic response in cavitating flows via combined physical and numerical analysis, with particular emphasis on the interaction between unsteady cavitation development and structural deformations. Issues including unsteady cavitating flow structures and cavitation–structure interaction mechanism are discussed.
基金supported by the National Natural Science Foundation of China (Grants 11172040,51239005)
文摘A local vortical cavitation（LVC） model for the computation of unsteady cavitation is proposed.The model is derived from the Rayleigh–Plesset equations,and takes into account the relations between the cavitation bubble radius and local vortical effects.Calculations of unsteady cloud cavitating fows around a Clark-Y hydrofoil are performed to assess the predictive capability of the LVC model using well-documented experimental data.Compared with the conventional Zwart＇s model,better agreement is observed between the predictions of the LVC model and experimental data,including measurements of time-averaged fl w structures,instantaneous cavity shapes and the frequency of the cloud cavity shedding process.Based on the predictions of the LVC model,it is demonstrated that the evaporation process largely concentrates in the core region of the leading edge vorticity in accordance with the growth in the attached cavity,and the condensation process concentrates in the core region of the trailing edge vorticity,which corresponds to the spread of the rear component of the attached cavity.When the attached cavity breaks up and moves downstream,the condensation area fully transports to the wake region,which is in accordance with the dissipation of the detached cavity.Furthermore,using vorticity transport equations,we also fin that the periodic formation,breakup,and shedding of the sheet/cloud cavities,along with the associated baroclinic torque,are important mechanisms for vorticity production and modification When the attached cavity grows,the liquid–vapour interface that moves towards the trailing edge enhances the vorticity in the attached cav-ity closure region.As the re-entrant jet moves upstream,the wavy/bubbly cavity interface enhances the vorticity near the trailing edge.At the end of the cycle,the break-up of the stable attached cavity is the main reason for the vorticity enhancement near the suction surface.
基金project was supported by the National Natural Science Foundation of China (Grants 51306020, 11172040)the Natural Science Foundation of Beijing (Grant 3144034)the Excellent Young Scholars Research Fund of Beijing Institute of Technology
文摘The objective of this paper is to address the transient flow structures around a pitching hydrofoil by com- bining physical and numerical studies. In order to predict the dynamic behavior of the flow structure effectively, the Lagrangian coherent structures （LCS） defined by the ridges of the finite-time Lyapunov exponent （FTLE） are utilized under the framework of Navier-Stokes flow computations. In the numerical simulations, the k-w shear stress trans- port （SST） turbulence model, coupled with a two-equation F-Reo transition model, is used for the turbulence closure. Results are presented for a NACA66 hydrofoil undergoing slowly and rapidly pitching motions from 0° to 15° then back to 0° at a moderate Reynolds number Re = 7.5 × 105. The results reveal that the transient flow structures can be observed by the LCS method. For the slowly pitching case, it consists of five stages： quasi-steady and laminar, transition from laminar to turbulent, vortex development, large-scale vortex shedding, and reverting to laminar. The observation of LCS and Lagrangian particle tracers elucidates that the trailing edge vortex is nearly attached and stable during the vortex development stage and the interaction between the leading and trailing edge vortex caused by the adverse pres- sure gradient forces the vortexes to shed downstream during the large-scale vortex shedding stage, which corresponds to obvious fluctuations of the hydrodynamic response. For the rapidly pitching case, the inflection is hardly to be observed and the stall is delayed. The vortex formation, interaction, and shedding occurred once instead of being repeated three times, which is responsible for just one fluctuation in the hydrody- namic characteristics. The numerical results also show that the FTLE field has the potential to identify the transient flows, and the LCS can represent the divergence extent of infinite neighboring particles and capture the interface of the vortex region.
基金supported by the National Natural Science Foundation of China (60875019)
文摘The rotational parameters estimation of maneuvering target is the key of cross-range scaling of ISAR （inverse synthetic aperture radar）, which can be used in the target feature extraction. The cross-range signal model of rotating target with fixed acceleration is presented and the weighted linear least squares estimation of rotational parameters with fixed velocity or acceleration is proposed via the relationship of cross-range FM （frequency modulation） parameter, scatterers coordinates and rotational parameters. The FM parameter is calculated via RWT （Radon-Wigner transform）. The ISAR imaging and cross-range scaling based on scaled RWT imaging method are implemented after obtaining rotational parameters. The rotational parameters estimation and cross-range scaling are validated by the ISAR processing of experimental radar data, and the method presents good application foreground to the ISAR imaging and scaling of maneuvering target.
基金supported by the National Key Research and Development Program of China(Grant No.2017YFA0302903)the National Natural Science Foundation of China(Grant Nos.11774422 and 11774424)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(Grant Nos.14XNLQ03 and 16XNLQ01)
文摘By using first-principles electronic structure calculations, we have studied the magnetic interactions in a proposed BaZn2P2-based diluted magnetic semiconductor（DMS）. For a typical compound Ba（Zn（0.944）Mn（0.056））2P2 with only spin doping, due to the superexchange interaction between Mn atoms and the lack of itinerant carriers, the short-range antiferromagnetic coupling dominates. Partially substituting K atoms for Ba atoms, which introduces itinerant hole carriers into the p orbitals of P atoms so as to link distant Mn moments with the spin-polarized hole carriers via the p–d hybridization between P and Mn atoms, is very crucial for the appearance of ferromagnetism in the compound. Furthermore, applying hydrostatic pressure first enhances and then decreases the ferromagnetic coupling in（Ba0.75 K0.25）（Zn（0.944）Mn（0.056））2P2 at a turning point around 15 GPa, which results from the combined effects of the pressure-induced variations of electron delocalization and p–d hybridization. Compared with the BaZn2 As2-based DMS, the substitution of P for As can modulate the magnetic coupling effectively. Both the results for BaZn2 P2-based and BaZn2As2-based DMSs demonstrate that the robust antiferromagnetic（AFM） coupling between the nearest Mn–Mn pairs bridged by anions is harmful to improving the performance of these Ⅱ–Ⅱ–Ⅴ based DMS materials.
基金Project supported by the National Natural Science Foundation of China(Grant No.51771126)the Youth Foundation of Science&Technology Department of Sichuan Province,China(Grant No.2016JQ0051)+3 种基金the Sichuan University Talent Introduction Research Funding(Grand No.YJ201537)the Sichuan University Outstanding Young Scholars Research Funding(Grant No.2015SCU04A20)the World First-Class University Construction Fundingthe Fundamental and Frontier Research in Chongqing(Grant No.CSTC2015JCYJBX0026)
文摘We have systematically studied the thermoelectric properties in Zn-doped Sn Te.Strikingly,band convergence and embedded precipitates arising from Zn doping,can trigger a prominent improvement of thermoelectric performance.In particular,the value of dimensionless figure of merit z T has increased by 100% and up to ～ 0.5 at 775 K for the optimal sample with 2% Zn content.Present findings demonstrate that carrier concentration and effective mass play crucial roles on the Seebeck coefficient and power factor.The obvious deviation from the Pisarenko line（Seebeck coefficient versus carrier concentration） due to Zn-doping reveals the convergence of valence bands.When the doping concentration exceeds the solubility,precipitates occur and lead to a reduction of lattice thermal conductivity.In addition,bipolar conduction is suppressed,indicating an enlargement of band gap.The Zn-doped Sn Te is shown to be a promising candidate for thermoelectric applications.
基金Supported by the National Natural Science Foundation of China（No.41176072） the Scientific Research Fund of Hunan Provincial Education Department（No.12C0030）+1 种基金 the Program for Hu’nan Province Key Laboratory of Water,Sediment Sciences and Flood Hazard Prevention（No.2012SS07） the National Natural Science Foundation for Youth of China（No.51109018）
文摘A pipe model with a mass ratio（mass/displaced mass） of 4.30 was tested to investigate the vortex-induced vibrations of submarine pipeline spans near the seabed.The pipe model was designed as a bending stiffness-dominated beam.The gap ratios（gap to diameter ratio） at the pipe ends were 4.0,6.0,and 8.0.The flow velocity was systematically varied in the 0-16.71 nondimensional velocity range based on the first natural frequency.The mode transition between the first and the second mode as the flow velocity increases was investigated.At various transition flow velocities,the research indicates that the peak frequencies with respect to displacement are not identical along the pipe,nor the frequencies associated with the peak of the amplitude spectra for the first four modes as well.The mode transition is associated with a continuous change in the amplitude,but there＇s a jump in frequency,and a gradual process along the pipe length.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51771126 and 11774247)the Youth Foundation of Science and Technology Department of Sichuan Province,China(Grant No.2016JQ0051)+2 种基金Sichuan University Outstanding Young Scholars Research Funding(Grant No.2015SCU04A20)the World First-Class University Construction Fundingthe Fundamental and Frontier Research Project in Chongqing(Grant No.CSTC2015JCYJBX0026)
文摘Binary Cu-based chalcogenide thermoelectric materials have attracted a great deal of attention due to their outstanding physical properties and fascinating phase sequence.However,the relatively low figure of merit z T restricts their practical applications in power generation.A general approach to enhancing z T value is to produce nanostructured grains,while one disadvantage of such a method is the expansion of grain size in heating-up process.Here,we report a prominent improvement of z T in Cu2Te（0.2）Se（0.8）,which is several times larger than that of the matrix.This significant enhancement in thermoelectric performance is attributed to the formation of abundant porosity via cold press.These pores with nano-to micrometer size can manipulate phonon transport simultaneously,resulting in an apparent suppression of thermal conductivity.Moreover,the Se substitution triggers a rapid promotion of power factor,which compensates for the reduction of electrical properties due to carriers scattering by pores.Our strategy of porosity engineering by phonon scattering can also be highly applicable in enhancing the performances of other thermoelectric systems.
基金Supported by Planning Project of Lanzhou Science and Technology Bureau(2015-3-60)
文摘Drought and water shortage are the biggest limiting factors of dry farming,and variety plays an important role in an increase in the yield of dryland maize.Screening high-yield maize varieties is helpful to the continuous increase and stable yield of dryland grain.In this experiment,the growth period,characters and yield of 12 maize varieties were analyzed.The results show that the yield of Ganyu series was low,while the yield of Lianda 169 was the highest(8 080.93 kg/ha),which was 31.40% higher than Jinsui 4.The yield of Dunyu 16 was6 621.06 kg/ha,7.64% higher than Jinsui 4.The two varieties had good comprehensive characters,so they could be popularized and planted in dry farming areas of Lanzhou City.
基金supported by "the Fundamental Research Funds for the Central Universities" ZYGX2013J123
文摘Keeping balance is the premise of human walking. ZMP(zero moment point) is a point where total torque achieves balance. It is an important evaluation parameter of balance ability in walking, since it can be used to better reflect the dynamic balance during walking. ZMP can be used in many applications, such as medical rehabilitation, disease diagnosis, treatment and etc. In this paper, wearable inertial sensors system based on MEMS is used to measure ZMP(zero moment point) during walking, which is cheap, convenient, and free from the restriction of lab. Our wearable ZMP measurement system consists of inertial measurement subsystem and PC real-time monitoring station. Inertial measurement subsystem includes 9-axis inertial sensing nodes, the body communication network and the central node. Inertial sensing nodes are mounted on different parts of the body to collect body posture information in real-time, and then the best estimation of current posture are obtained by Kalman filter. The data from sensors is aggregated to the central node through the CAN bus, and then ZMP is calculated. Finally, it can be showed in the PC monitoring station. Experiments prove the system can achieve real-time ZMP detection during walking.
基金supported by the National Natu-ral Science Foundation of China(Grant Nos.52125103,52071041,52271202,and 12274044).
文摘Tetrahedrite,an Earth-abundant natural mineral,has attracted extensive research interest because of its excellent thermoelectric performance.Herein,tetrahedrite samples comprising Cu-poor Cu_(12)Sb_(4)S_(13)and Cu-rich Cu_(14)Sb_(4)S_(13)phases have been synthesized using a colloidal method,in which the ratio of two phases is manipulated by controlling the synthesis temperature to improve the thermoelectric perfor-mance.It is found that an ultralow total thermal conductivity of∼0.3 W m^(−1)K^(−1)at 723 K is realized in the sample with a Cu-rich phase fraction of∼50%,which can be attributed to maximized phonon scattering by phase boundaries.As a result,combined with a decent power factor,this sample obtains an optimal zT of 1.15,which is about 85%higher than that of the sample with a Cu-rich phase fraction of∼64%and comparable to zT values of other eco-friendly,abundant Cu-based thermoelectric materials.This work demonstrates an effective synthesis-temperature-dependent phase composition manipulation strategy toward enhanced thermoelectric performance in tetrahedrites.
