The Xianshuihe-Anninghe fault extends SE–S and constitutes the southeastern margin of the Tibetan Plateau.However,the Dadu River which is associated with the fault does not flow following the path,but makes a 90º...The Xianshuihe-Anninghe fault extends SE–S and constitutes the southeastern margin of the Tibetan Plateau.However,the Dadu River which is associated with the fault does not flow following the path,but makes a 90ºturn within a distance of 1 km at Shimian,heading east,and joins the Yangtze River,finally flowing into the East China Sea.Adjacent to the abrupt turn,a low and wide pass near the Daqiao reservoir at Mianning separates the N–S course of the Dadu River from the headwater of the Anning River which then flows south into the Yunnan Province along the Anninghe fault.Therefore,many previous studies assumed southward flow of the paleo-Dadu River from the Shimian to the Anning River.However,evidences for the capture of the integrated N–S paleo-Dadu-Anning River,its timing,and causes are still insufficient.This study explored the paleo-drainage pattern of the Dadu and Anning Rivers based on bulk mineral and geochemical analyses of the large quantities of fluvial/lacustrine sediments along the trunk of the Dadu and Anning Rivers.Similar with sands in the modern Dadu River,the Xigeda sediments also exhibit a granitoid affinity with the bulk major mineral compositions of quartz(>50%),anorthite(about 10%),orthoclase(about 5%),muscovite(about 5%),and clinochlore(about 4%).Correspondingly,bulk major elements show high SiO_(2),with all samples>60%,and some of them>70%,low TiO_(2)(≤0.75%),P_(2)O_(5)(≤0.55%),FeO*(≤5%),and relatively high CaO(1.02%–8.51%),Na_(2)O(1.60%–2.52%),and K_(2)O(2.17%–2.71%),with a uniform REE patterns.Therefore,synthesizing all these results indicate that these lacustrine sediments have similar material sources,which are mainly derived from its course in the Songpan-Ganzi flysch block,implying that the paleo-Dadu originally flowed southward into the Anning River and provided materials to the Xigeda ancient lake.The rearrangement of the paleo-Dadu River appears to be closely related to the locally focused uplift driven by strong activities of the XianshuiheXiaojiang fault system.展开更多
The timing of the initial Indo-Asian collision is a subject of debate for a long time.Besides,the magmatic trace of the collisional process is also unclear.In the present study,the authors report Early Eocene leucocra...The timing of the initial Indo-Asian collision is a subject of debate for a long time.Besides,the magmatic trace of the collisional process is also unclear.In the present study,the authors report Early Eocene leucocratic sill/dike swarms in the northern edge of the Nymo intrusive complex of the Gangdese belt,southern Tibet.The Nymo intrusive complex was emplaced at ca.50–47 Ma and surrounded by the metamorphosed Jurassic-aged Bima Formation volcano-sedimentary sequence along its northern side.At outcrops,the leucocratic sills/dikes intruded along or truncated the deformed foliations of the host Bima Formation,which has been subject to high-temperature amphibolite-facies metamorphism at ca.50–47 Ma.Detailed cathodoluminescence image analyses reveal that the zircon grains of the leucocratic sills/dikes have core-mantle textures.The cores yield the Jurassic ages comparable to the protolith ages of the Bima Formation.In contrast,the mantles of zircon grains yield weighted mean ages of ca.49–47 Ma,representing the crystallization timing of these leucocratic sills/dikes.The coeval ages for the Nymo intrusive complex,the high-temperature metamorphism,and the leucocratic sills/dikes indicate that a close relationship exists among them.The authors tentatively suggest that these leucocratic sills/dikes were generated from partial melting of the Jurassic-aged Bima Formation volcanic rocks,triggered by the high heat from the magma chamber of the Nymo intrusive complex.This Early Eocene tectono-thermal event of coeval magmatism,metamorphism and partial melting was most likely formed during the Indo-Asian collisional setting.展开更多
BACKGROUND Fracture risk assessment in children with benign bone lesions of long bones remains poorly investigated.AIM To investigate the risk factors for pathological fracture in children with benign bone lesions and...BACKGROUND Fracture risk assessment in children with benign bone lesions of long bones remains poorly investigated.AIM To investigate the risk factors for pathological fracture in children with benign bone lesions and to propose a modified scoring system for quantitative analysis of the pathologic fracture risk.METHODS We retrospectively reviewed 96 pediatric patients with benign bone lesions.We compared radiographic and clinical features between 40 patients who had fractures through a benign bone lesion and 56 who had no fracture.Information including histological diagnosis,anatomical site,radiographic appearance,severity of pain,and lesion size was recorded for the patients.A modified scoring system was proposed to predict the risk of fracture.RESULTS The univariate comparisons showed a significant difference between the fracture and non-fracture groups in terms of lesion type,pain,lesion-to-bone width,and axial cortical involvement of the patients(P<0.05).Lesion type,pain,lesion-tobone width,and axial cortical involvement were independently correlated with an increased risk of fracture.The mean score of the fracture group was 7.89,whereas the mean score of the non-fracture group was 6.01.The optimum cut-off value of the score to predict pathological fracture was 7.The scoring system had a sensitivity of 70%and a specificity of 80%for detecting patients with fractures.The Youden index was 0.5,which was the maximum value.The area under the receiver operator characteristic was 0.814.CONCLUSION Lesion type,pain,lesion-to-bone width,and axial cortical involvement are risk factors for pathological fracture.The modified scoring system can provide evidence for clinical decision-making in children with benign bone lesions.A bone lesion with a total score>7 indicates a high risk of a pathologic fracture and is an indication for prophylactic internal fixation.展开更多
Securities fraud is a common worldwide problem, resulting in serious negative consequences to securities market each year. Securities Regulatory Commission from various countries has also attached great importance to ...Securities fraud is a common worldwide problem, resulting in serious negative consequences to securities market each year. Securities Regulatory Commission from various countries has also attached great importance to the detection and prevention of securities fraud activities. Securities fraud is also increasing due to the rapid expansion of securities market in China. In accomplishing the task of securities fraud detection, China Securities Regulatory Commission (CSRC) could be facilitated in their work by using a number of data mining techniques. In this paper, we investigate the usefulness of Logistic regression model, Neural Networks (NNs), Sequential minimal optimization (SMO), Radial Basis Function (RBF) networks, Bayesian networks and Grammar Based Genet- ic Programming (GBGP) in the classification of the real, large and latest China Corporate Securities Fraud (CCSF) database. The six data mining techniques are compared in terms of their performances. As a result, we found GBGP outperforms others. This paper describes the GBGP in detail in solving the CCSF problem. In addition, the Synthetic Minority Over-sampling Technique (SMOTE) is applied to generate synthetic minority class examples for the imbalanced CCSF dataset.展开更多
Stainless steel(SS)/carbon steel(CS)clad plates were generated by means of the all-around weld of interface and vacuuming(AAWIV)followed by hot rolling,wherein AAWIV was utilized for controlling the interface oxidatio...Stainless steel(SS)/carbon steel(CS)clad plates were generated by means of the all-around weld of interface and vacuuming(AAWIV)followed by hot rolling,wherein AAWIV was utilized for controlling the interface oxidation during hot rolling.The structure near the interface was analyzed by optical microscopy(OM),scanning electron microscopy(SEM)and transmission electron microscopy(TEM).The mechanical properties of SS/CS clad plates were investigated by tensile and shear as well as bend tests.The SS/CS interface is relatively flat and no visible separation appears.Line scanning analysis shows that diffusion of Cr and Ni from SS to CS and C from CS to SS occurred during bonding.Higher dislocation densities are observed in both layers of parent plates adhering to the interface.The SS/CS clad plates reveal higher yield,tensile and shear strengths.Both macroscopic delamination at the interface and fracture of base CS as well as intergranular fracture appearance of flyer plate are observed in the tensile test.The shear specimen fails in a ductile manner and the bend specimen tested shows no visible crack at the interface.Taking both interfacial structure and mechanical properties into account,the SS/CS clad plates exhibit sound bonding by the process of AAWIV and hot rolling.展开更多
<正>Several water-soluble calix[4]arenes were synthesized via radical addition reaction between thiols and alkenes under UV lamp irradiation(λ= 365 nm) in good yields.The structures of these compounds synthesiz...<正>Several water-soluble calix[4]arenes were synthesized via radical addition reaction between thiols and alkenes under UV lamp irradiation(λ= 365 nm) in good yields.The structures of these compounds synthesized herein were fully confirmed by ~1 H NMR.ES1-MS and elemental analysis.展开更多
A novel series of calix[4]arene derivatives were synthesized via a Pd-catalyzed Sonogashira coupling reaction from para-substituted iodobenzene and 25,27-dipropargyl-calix[4]arene.Fluorescence studies found that nitro...A novel series of calix[4]arene derivatives were synthesized via a Pd-catalyzed Sonogashira coupling reaction from para-substituted iodobenzene and 25,27-dipropargyl-calix[4]arene.Fluorescence studies found that nitro-phenols clearly exhibited quenching effects on 2c.Moreover,we minimized the free energy of the complexes by theoretical calculations.As the result,the n-n stacking interactions take place between the 4-nitrophenol and calix[4Jarene,which may lead to the significant fluorescence quench.展开更多
基金financially supported by the Natural Science Foundation of China(41941016,42072240,41830217)Ministry of Science and Technology of China(2019QZKK0901,2021FY100101)+2 种基金Key Special Project for Introduced Talents Team of the Southern Marine Science and Engineering Guangdong Laboratory(GML2019ZD0201)China Geological Survey(DD20221630)Special Fund of the Institute of Geophysics,China Earthquake Administration(DQJB20B21).
文摘The Xianshuihe-Anninghe fault extends SE–S and constitutes the southeastern margin of the Tibetan Plateau.However,the Dadu River which is associated with the fault does not flow following the path,but makes a 90ºturn within a distance of 1 km at Shimian,heading east,and joins the Yangtze River,finally flowing into the East China Sea.Adjacent to the abrupt turn,a low and wide pass near the Daqiao reservoir at Mianning separates the N–S course of the Dadu River from the headwater of the Anning River which then flows south into the Yunnan Province along the Anninghe fault.Therefore,many previous studies assumed southward flow of the paleo-Dadu River from the Shimian to the Anning River.However,evidences for the capture of the integrated N–S paleo-Dadu-Anning River,its timing,and causes are still insufficient.This study explored the paleo-drainage pattern of the Dadu and Anning Rivers based on bulk mineral and geochemical analyses of the large quantities of fluvial/lacustrine sediments along the trunk of the Dadu and Anning Rivers.Similar with sands in the modern Dadu River,the Xigeda sediments also exhibit a granitoid affinity with the bulk major mineral compositions of quartz(>50%),anorthite(about 10%),orthoclase(about 5%),muscovite(about 5%),and clinochlore(about 4%).Correspondingly,bulk major elements show high SiO_(2),with all samples>60%,and some of them>70%,low TiO_(2)(≤0.75%),P_(2)O_(5)(≤0.55%),FeO*(≤5%),and relatively high CaO(1.02%–8.51%),Na_(2)O(1.60%–2.52%),and K_(2)O(2.17%–2.71%),with a uniform REE patterns.Therefore,synthesizing all these results indicate that these lacustrine sediments have similar material sources,which are mainly derived from its course in the Songpan-Ganzi flysch block,implying that the paleo-Dadu originally flowed southward into the Anning River and provided materials to the Xigeda ancient lake.The rearrangement of the paleo-Dadu River appears to be closely related to the locally focused uplift driven by strong activities of the XianshuiheXiaojiang fault system.
基金the National Key Research and Development Project“Key scientific issues of transformative technology”(2019YFA0708601)the Key Special Project for Introduced Talents Team of the Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(GML2019ZD0201)+4 种基金the second Tibetan Plateau Scientific Expedition and Research Program(STEP)Grant(2019QZKK0802)the Research Grants of Chinese Academy of Geological Sciences(J2024)the Geological Survey of China(DD20190057 and DD20190060)the National Natural Science Foundation of China(41502198)the open fund of State Key Laboratory for Mineral Deposits Research at Nanjing University(2020-LAMD-K04).
文摘The timing of the initial Indo-Asian collision is a subject of debate for a long time.Besides,the magmatic trace of the collisional process is also unclear.In the present study,the authors report Early Eocene leucocratic sill/dike swarms in the northern edge of the Nymo intrusive complex of the Gangdese belt,southern Tibet.The Nymo intrusive complex was emplaced at ca.50–47 Ma and surrounded by the metamorphosed Jurassic-aged Bima Formation volcano-sedimentary sequence along its northern side.At outcrops,the leucocratic sills/dikes intruded along or truncated the deformed foliations of the host Bima Formation,which has been subject to high-temperature amphibolite-facies metamorphism at ca.50–47 Ma.Detailed cathodoluminescence image analyses reveal that the zircon grains of the leucocratic sills/dikes have core-mantle textures.The cores yield the Jurassic ages comparable to the protolith ages of the Bima Formation.In contrast,the mantles of zircon grains yield weighted mean ages of ca.49–47 Ma,representing the crystallization timing of these leucocratic sills/dikes.The coeval ages for the Nymo intrusive complex,the high-temperature metamorphism,and the leucocratic sills/dikes indicate that a close relationship exists among them.The authors tentatively suggest that these leucocratic sills/dikes were generated from partial melting of the Jurassic-aged Bima Formation volcanic rocks,triggered by the high heat from the magma chamber of the Nymo intrusive complex.This Early Eocene tectono-thermal event of coeval magmatism,metamorphism and partial melting was most likely formed during the Indo-Asian collisional setting.
基金Natural Science Foundation of Zhejiang Province,No.LY20H060001.
文摘BACKGROUND Fracture risk assessment in children with benign bone lesions of long bones remains poorly investigated.AIM To investigate the risk factors for pathological fracture in children with benign bone lesions and to propose a modified scoring system for quantitative analysis of the pathologic fracture risk.METHODS We retrospectively reviewed 96 pediatric patients with benign bone lesions.We compared radiographic and clinical features between 40 patients who had fractures through a benign bone lesion and 56 who had no fracture.Information including histological diagnosis,anatomical site,radiographic appearance,severity of pain,and lesion size was recorded for the patients.A modified scoring system was proposed to predict the risk of fracture.RESULTS The univariate comparisons showed a significant difference between the fracture and non-fracture groups in terms of lesion type,pain,lesion-to-bone width,and axial cortical involvement of the patients(P<0.05).Lesion type,pain,lesion-tobone width,and axial cortical involvement were independently correlated with an increased risk of fracture.The mean score of the fracture group was 7.89,whereas the mean score of the non-fracture group was 6.01.The optimum cut-off value of the score to predict pathological fracture was 7.The scoring system had a sensitivity of 70%and a specificity of 80%for detecting patients with fractures.The Youden index was 0.5,which was the maximum value.The area under the receiver operator characteristic was 0.814.CONCLUSION Lesion type,pain,lesion-to-bone width,and axial cortical involvement are risk factors for pathological fracture.The modified scoring system can provide evidence for clinical decision-making in children with benign bone lesions.A bone lesion with a total score>7 indicates a high risk of a pathologic fracture and is an indication for prophylactic internal fixation.
文摘Securities fraud is a common worldwide problem, resulting in serious negative consequences to securities market each year. Securities Regulatory Commission from various countries has also attached great importance to the detection and prevention of securities fraud activities. Securities fraud is also increasing due to the rapid expansion of securities market in China. In accomplishing the task of securities fraud detection, China Securities Regulatory Commission (CSRC) could be facilitated in their work by using a number of data mining techniques. In this paper, we investigate the usefulness of Logistic regression model, Neural Networks (NNs), Sequential minimal optimization (SMO), Radial Basis Function (RBF) networks, Bayesian networks and Grammar Based Genet- ic Programming (GBGP) in the classification of the real, large and latest China Corporate Securities Fraud (CCSF) database. The six data mining techniques are compared in terms of their performances. As a result, we found GBGP outperforms others. This paper describes the GBGP in detail in solving the CCSF problem. In addition, the Synthetic Minority Over-sampling Technique (SMOTE) is applied to generate synthetic minority class examples for the imbalanced CCSF dataset.
基金Item Sponsored by National Key Technology Research and Development Program in 12th Five-year Plan of China(2012CB722801)National Natural Science Foundation of China(51105264)Postdoctoral Science Foundation of China(2012M520677)
文摘Stainless steel(SS)/carbon steel(CS)clad plates were generated by means of the all-around weld of interface and vacuuming(AAWIV)followed by hot rolling,wherein AAWIV was utilized for controlling the interface oxidation during hot rolling.The structure near the interface was analyzed by optical microscopy(OM),scanning electron microscopy(SEM)and transmission electron microscopy(TEM).The mechanical properties of SS/CS clad plates were investigated by tensile and shear as well as bend tests.The SS/CS interface is relatively flat and no visible separation appears.Line scanning analysis shows that diffusion of Cr and Ni from SS to CS and C from CS to SS occurred during bonding.Higher dislocation densities are observed in both layers of parent plates adhering to the interface.The SS/CS clad plates reveal higher yield,tensile and shear strengths.Both macroscopic delamination at the interface and fracture of base CS as well as intergranular fracture appearance of flyer plate are observed in the tensile test.The shear specimen fails in a ductile manner and the bend specimen tested shows no visible crack at the interface.Taking both interfacial structure and mechanical properties into account,the SS/CS clad plates exhibit sound bonding by the process of AAWIV and hot rolling.
基金supported by the National Natural Science Foundation of China(Nos.21072072 and 21102051)PCSIRT(No.IRTO953)+1 种基金Program for New Century Excellent Talent in University(No.NCET-10-0428)Self-determined Research Funds of CCNU from the Colleges Basic Research and Operation of MOE (Nos.CCNU11C01002,CCNU12A01004 and CCNU12A02012)
文摘<正>Several water-soluble calix[4]arenes were synthesized via radical addition reaction between thiols and alkenes under UV lamp irradiation(λ= 365 nm) in good yields.The structures of these compounds synthesized herein were fully confirmed by ~1 H NMR.ES1-MS and elemental analysis.
基金financially supported by the National Natural Science Foundation of China(Nos.21372092,21072072, 21102051)PCSIRT(No.IRT0953)+2 种基金Program for New Century Excellent Talent in University(No.NCET-10-0428)self-determined research funds of CCNU from the colleges,basic research and operation of MOE(Nos.CCNU11C01002,CCNU13F005)State Key Laboratory of Chemo/Biosensing and Chemometrics (201003)
文摘A novel series of calix[4]arene derivatives were synthesized via a Pd-catalyzed Sonogashira coupling reaction from para-substituted iodobenzene and 25,27-dipropargyl-calix[4]arene.Fluorescence studies found that nitro-phenols clearly exhibited quenching effects on 2c.Moreover,we minimized the free energy of the complexes by theoretical calculations.As the result,the n-n stacking interactions take place between the 4-nitrophenol and calix[4Jarene,which may lead to the significant fluorescence quench.
