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Persistence of charge density wave against variation of band structures in V_(x)Ti_(1−x)Se_(2)(x=0–0.1)
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作者 Zhanfeng Liu Tongrui Li +13 位作者 Wen Zhu hongwei shou Mukhtar Lawan Adam Qilong Cui Yuliang Li Sheng Wang Yunbo Wu Hongen Zhu Yi Liu Shuangming Chen Xiaojun Wu Shengtao Cui Li Song Zhe Sun 《Nano Research》 SCIE EI CSCD 2024年第3期2129-2135,共7页
Charge density wave(CDW)is a phenomenon that occurs in materials,accompanied by changes in their intrinsic electronic properties.The study of CDW and its modulation in materials holds tremendous significance in materi... Charge density wave(CDW)is a phenomenon that occurs in materials,accompanied by changes in their intrinsic electronic properties.The study of CDW and its modulation in materials holds tremendous significance in materials research,as it provides a unique approach to controlling the electronic properties of materials.TiSe_(2) is a typical layered material with a CDW phase at low temperatures.Through V substitution for Ti in TiSe_(2),we tuned the carrier concentration in V_(x)Ti_(1-x)Se_(2) to study how its electronic structures evolve.Angle-resolved photoemission spectroscopy(ARPES)shows that the band-folding effect is sustained with the doping level up to 10%,indicating the persistence of the CDW phase,even though the band structure is strikingly different from that of the parent compound TiSe_(2).Though CDW can induce the band fold effect with a driving force from the perspective of electronic systems,our studies suggest that this behavior could be maintained by lattice distortion of the CDW phase,even if band structures deviate from the electron-driven CDW scenario.Our work provides a constraint for understanding the CDW mechanism in TiSe_(2),and highlights the role of lattice distortion in the band-folding effect. 展开更多
关键词 charge density wave band structure lattice distortion
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Interfacial electronic interaction enabling exposed Pt(110)facets with high specific activity in hydrogen evolution reaction 被引量:1
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作者 Sicong Qiao Qun He +7 位作者 Quan Zhou Yuzhu Zhou Wenjie Xu hongwei shou Yuyang Cao Shuangming Chen Xiaojun Wu Li Song 《Nano Research》 SCIE EI CSCD 2023年第1期174-180,共7页
To achieve a complete industrial chain of hydrogen energy,the development of efficient electrocatalysts for hydrogen evolution reaction(HER)is of great concerns.Herein,a nickel nitride supported platinum(Pt)catalyst w... To achieve a complete industrial chain of hydrogen energy,the development of efficient electrocatalysts for hydrogen evolution reaction(HER)is of great concerns.Herein,a nickel nitride supported platinum(Pt)catalyst with highly exposed Pt(110)facets(Pt_((110))-Ni_(3)N)is obtained for catalyzing HER.Combined X-ray spectra and density functional theory studies demonstrate that the interfacial electronic interaction between Pt and Ni3N support can promote the hydrogen evolution on Pt(110)facets by weakening hydrogen adsorption.As a result,the Pt_((110))-Ni_(3)N catalyst delivers an obviously higher specific activity than commercial 20 wt.%Pt/C in acidic media.This work suggests that the suitable interface modulation may play a vital role in rationally designing advanced electrocatalysts. 展开更多
关键词 Interfacial electronic interaction hydrogen evolution reaction X-ray spectroscopy Pt(110)facets density functional theory
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Support induced phase engineering toward superior electrocatalyst 被引量:1
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作者 Beibei Sheng Dengfeng Cao +11 位作者 hongwei shou Oyawale Adetunji Moses Wenjie Xu Yujian Xia Yuzhu Zhou Huijuan Wang Ping Wan Shuang Zhu Wangsheng Chu Xiaojun Wu Shuangming Chen Li Song 《Nano Research》 SCIE EI CSCD 2022年第3期1831-1837,共7页
The phase transformation of catalysts has been extensively observed in heterogeneous catalytic reactions that hinder the long cycling catalysis,and it remains a big challenge to precisely control the active phase duri... The phase transformation of catalysts has been extensively observed in heterogeneous catalytic reactions that hinder the long cycling catalysis,and it remains a big challenge to precisely control the active phase during the complex conditions in electrochemical catalysis.Here,we theoretically predict that carbon-based support could achieve the phase engineering regulation of catalysts by suppressing specific phase transformation.Taken single-walled carbon nanotube(SWCNT)as typical support,combined with calculated E-pH(Pourbaix)diagram and advanced synchrotron-based characterizations technologies prove there are two different active phases source from cobalt selenide which demonstrate that the feasibility of using support effect regulating the potential advantageous catalysts.Moreover,it is worth noting that the phase engineering derived Co_(3)O_(4)-SWCNT exhibits a low overpotential of 201 mV for delivering the current density of 10 mA/cm^(2)in electrocatalytic oxygen evolution reaction(OER).Also,it reaches a record current density of 529 mA/cm^(2)at 1.63 V(vs.RHE)in the electrocatalytic urea oxidation reaction(UOR),overwhelming most previously reported catalysts. 展开更多
关键词 phase engineering SUPPORT synchrotron radiation characterization oxygen evolution reaction(OER) urea oxidation reaction(UOR)
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Probing self-optimization of carbon support in oxygen evolution reaction 被引量:1
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作者 Wenjie Xu Dengfeng Cao +6 位作者 Oyawale Adetunji Moses Beibei Sheng Chuanqiang Wu hongwei shou Xiaojun Wu Shuangming Chen Li Song 《Nano Research》 SCIE EI CSCD 2021年第12期4534-4540,共7页
Despite acknowledgment of structural reconstruction of materials following oxygen evolution reaction (OER) reaction, the role of support during the reconstruction process has been ignored. Given this, we directly in s... Despite acknowledgment of structural reconstruction of materials following oxygen evolution reaction (OER) reaction, the role of support during the reconstruction process has been ignored. Given this, we directly in situ transform the residual iron present in raw single-walled carbon nanotubes (SWCNT) into Fe_(2)O_(3) and thus build Fe_(2)O_(3)-CNT as the model system. Intriguingly, an anomalous self-optimization occurred on SWCNT and the derived components show satisfactory electrochemical performance. Soft X-ray absorption spectroscopy (sXAS) analysis and theory calculation correspondingly indicate that self-optimization yields stronger interaction between SWCNT and Fe_(2)O_(3) nanoparticles, where the electrons migrate from Fe_(2)O_(3) to optimized SWCNT. Such polarization will generate a positive charge center and thus boost the OER activity. This finding directly observes the self-optimization of support effect, providing a new perspective for OER and related electrochemical reactions. 展开更多
关键词 self-optimization of support single-walled carbon nanotube(SWCNT) oxygen evolution reaction(OER) Fe_(2)O_(3) soft X-ray absorption spectroscopy(sXAS)
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Anomalous self-optimization of sulfate ions for boosted oxygen evolution reaction 被引量:1
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作者 Dengfeng Cao Oyawale Adetunji Moses +16 位作者 Beibei Sheng Shuangming Chen Haibin Pan Lihui Wu hongwei shou Wenjie Xu Dongdong Li Lirong Zheng Shengqi Chu Chuansheng Hu Daobin Liu Shiqiang Wei Xusheng Zheng Zeming Qi Xiaojun Wu Jing Zhang Li Song 《Science Bulletin》 SCIE EI CSCD 2021年第6期553-561,M0003,共10页
Broadly,the oxygen evolution reaction(OER)has been deeply understood as a significant part of energy conversion and storage.Nevertheless,the anions in the OER catalysts have been neglected for various reasons such as ... Broadly,the oxygen evolution reaction(OER)has been deeply understood as a significant part of energy conversion and storage.Nevertheless,the anions in the OER catalysts have been neglected for various reasons such as inactive sites,dissolution,and oxidation,amongst others.Herein,we applied a model catalyst s-Ni(OH)2 to track the anionic behavior in the catalyst during the electrochemical process to fill this gap.The advanced operando synchrotron radiation Fourier transform infrared(SR-FTIR)spectroscopy,synchrotron radiation photoelectron spectroscopy(SRPES)depth detection and differential X-ray absorption fine structure(D-XAFS)spectrum jointly point out that some oxidized sulfur species(SO_(4)^(2-))will selfoptimize new Ni–S bonds during OER process.Such amazing anionic self-optimization(ASO)behavior has never been observed in the OER process.Subsequently,the optimization-derived component shows a significantly improved electrocatalytic performance(activity,stability,etc.)compared to reference catalyst Ni(OH)_(2).Theoretical calculation further suggests that the ASO process indeed derives a thermodynamically stable structure of the OER catalyst,and then gives its superb catalytic performance by optimizing the thermodynamic and kinetic processes in the OER,respectively.This work demonstrates the vital role of anions in the electrochemical process,which will open up new perspectives for understanding OER and provide some new ideas in related fields(especially catalysis and chemistry). 展开更多
关键词 Oxygen evolution reaction(OER) Operando synchrotron radiation Fourier transform infrared(SR-FTIR)spectroscopy Synchrotron radiation photoelectron spectroscopy(SRPES)depth detection Differential X-ray absorption fine structure(D-XAFS)spectrum Anionic self-optimization(ASO)
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