The principle of“poverty alleviation first helps the poor”is fundamental to poverty alleviation through education in rural areas.It serves as an important foundation for improving the soft power of rural culture and...The principle of“poverty alleviation first helps the poor”is fundamental to poverty alleviation through education in rural areas.It serves as an important foundation for improving the soft power of rural culture and promoting the development of rural cultural construction.However,college students,being one of the main participants in educational poverty alleviation,have not been equipped with a well-established institutionalized participation mechanism and a sufficient awareness of participation.To enhance college students’awareness and participation in rural education and poverty alleviation and to improve the institutionalization,this research focuses on college students as a group,delves into the current situation and willingness of college students to participate in rural education and poverty alleviation,and analyzes the influencing factors affecting college students’participation in rural education and poverty alleviation by means of a questionnaire and a computerized statistical algorithm.Lastly,based on mathematical and statistical analysis,the research puts forward corresponding optimization countermeasures and suggestions from the perspectives of the government,colleges and universities,and villages,so as to provide decision-making guidelines for solving the problems of rural education development and talent constraints.展开更多
High-energy density lithium-sulfur(Li-S) batteries have received intensive attention as promising energy storage system.Among diverse sulfur-based cathodes,sulfurized pyrolyzed poly(acrylonitrile)(S@pPAN)cathode deliv...High-energy density lithium-sulfur(Li-S) batteries have received intensive attention as promising energy storage system.Among diverse sulfur-based cathodes,sulfurized pyrolyzed poly(acrylonitrile)(S@pPAN)cathode delivered superior electrochemical performance.However,the sulfur content of S@pPAN is relatively low(<50 wt%),which significantly limits the energy density.Herein,a hydrogel SA-Cu binder was proposed with a crosslinking network constructed by Cu^(2+) ions.The introduction of Cu^(2+) ions enabled excellent electrochemical behaviors of S@pPAN cathode even with high sulfur content of 52.6 wt% via chemical interaction with sulfur and polysulfide.Moreover,a favorable cathode interphase was formed containing electrochemically active and conductive CuSx.S@pPAN/SA-Cu exhibited a high sulfur utilization of 85.3%,long cycling stability over 1000 cycles and remarkable capacity of 1200 mAh g_(s)^(-1) even at10 C.Furthermore,ascribed to the improved electrode structure,high-loading electrode(sulfur loading:4 mg cm^(-2)) displayed stable cycling with areal capacity of 5.26 mAh cm^(-2)(1315 mAh g_(s)^(-1)) after 40 cycles.This study provides new directions to prepare high-sulfur content and high-loading S@pPAN cathode for higher energy density.展开更多
A novel electrolyte with chloromethyl pivalate(CP) used as solvent was first reported for non-aqueous lithium-oxygen(Li-O_2) batteries. Since there are no α-H atoms in the structure of CP, the CP based electrolyte in...A novel electrolyte with chloromethyl pivalate(CP) used as solvent was first reported for non-aqueous lithium-oxygen(Li-O_2) batteries. Since there are no α-H atoms in the structure of CP, the CP based electrolyte in both superoxide radical solution and real Li-O_2 battery environment showed good chemical stability against superoxide radicals, which was confirmed by ~1H NMR and ~13C NMR measurements.Without a catalyst in the cathode of Li-O_2 batteries, the batteries showed high specific capacity and cycling stability.展开更多
文摘The principle of“poverty alleviation first helps the poor”is fundamental to poverty alleviation through education in rural areas.It serves as an important foundation for improving the soft power of rural culture and promoting the development of rural cultural construction.However,college students,being one of the main participants in educational poverty alleviation,have not been equipped with a well-established institutionalized participation mechanism and a sufficient awareness of participation.To enhance college students’awareness and participation in rural education and poverty alleviation and to improve the institutionalization,this research focuses on college students as a group,delves into the current situation and willingness of college students to participate in rural education and poverty alleviation,and analyzes the influencing factors affecting college students’participation in rural education and poverty alleviation by means of a questionnaire and a computerized statistical algorithm.Lastly,based on mathematical and statistical analysis,the research puts forward corresponding optimization countermeasures and suggestions from the perspectives of the government,colleges and universities,and villages,so as to provide decision-making guidelines for solving the problems of rural education development and talent constraints.
基金financially supported by the National Natural Science Foundation of China (U1705255 and 21975158)the Program of Shanghai Academic Research Leader (20XD1401900)the Key-Area Research and Development Program of Guangdong Province (2019B090908001)。
文摘High-energy density lithium-sulfur(Li-S) batteries have received intensive attention as promising energy storage system.Among diverse sulfur-based cathodes,sulfurized pyrolyzed poly(acrylonitrile)(S@pPAN)cathode delivered superior electrochemical performance.However,the sulfur content of S@pPAN is relatively low(<50 wt%),which significantly limits the energy density.Herein,a hydrogel SA-Cu binder was proposed with a crosslinking network constructed by Cu^(2+) ions.The introduction of Cu^(2+) ions enabled excellent electrochemical behaviors of S@pPAN cathode even with high sulfur content of 52.6 wt% via chemical interaction with sulfur and polysulfide.Moreover,a favorable cathode interphase was formed containing electrochemically active and conductive CuSx.S@pPAN/SA-Cu exhibited a high sulfur utilization of 85.3%,long cycling stability over 1000 cycles and remarkable capacity of 1200 mAh g_(s)^(-1) even at10 C.Furthermore,ascribed to the improved electrode structure,high-loading electrode(sulfur loading:4 mg cm^(-2)) displayed stable cycling with areal capacity of 5.26 mAh cm^(-2)(1315 mAh g_(s)^(-1)) after 40 cycles.This study provides new directions to prepare high-sulfur content and high-loading S@pPAN cathode for higher energy density.
基金supported by the National Basic Research Program of China (No. 2014CB932303)National Natural ScienceFoundation of China (No. 21573145)
文摘A novel electrolyte with chloromethyl pivalate(CP) used as solvent was first reported for non-aqueous lithium-oxygen(Li-O_2) batteries. Since there are no α-H atoms in the structure of CP, the CP based electrolyte in both superoxide radical solution and real Li-O_2 battery environment showed good chemical stability against superoxide radicals, which was confirmed by ~1H NMR and ~13C NMR measurements.Without a catalyst in the cathode of Li-O_2 batteries, the batteries showed high specific capacity and cycling stability.
