The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane（TriFcM） in organic phase was studied with the ＂thin-layer electrochemistry＂ approach.Three pairs of symmetric p...The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane（TriFcM） in organic phase was studied with the ＂thin-layer electrochemistry＂ approach.Three pairs of symmetric peaks in cyclic voltammetry of TriFcM correspond to three one-electron electrochemical reaction processes and indicate strong intramolecular electronic communication,which could be used to study the multilevel ion-pairing effect.Three different formation constants of ion-pairs between the three ferroceniums of TriFcM and perchlorate in thin organic film were obtained and compared.展开更多
基金the NSFC(No.21173023)the 111 Project(No.B07012) in China and the TriFcM provided from professor Hua-Zhong Yu at Simon Fraser University in Canada
文摘The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane（TriFcM） in organic phase was studied with the ＂thin-layer electrochemistry＂ approach.Three pairs of symmetric peaks in cyclic voltammetry of TriFcM correspond to three one-electron electrochemical reaction processes and indicate strong intramolecular electronic communication,which could be used to study the multilevel ion-pairing effect.Three different formation constants of ion-pairs between the three ferroceniums of TriFcM and perchlorate in thin organic film were obtained and compared.
