The single-phase face-centered cubic(fcc)-structured Fe_(50)Mn_(27)Ni_(10)Cr_(13) high entropy alloy(HEA)exhibits good ductility but low strength,which presents a challenge.By Mo-alloying and thermomechanical treatmen...The single-phase face-centered cubic(fcc)-structured Fe_(50)Mn_(27)Ni_(10)Cr_(13) high entropy alloy(HEA)exhibits good ductility but low strength,which presents a challenge.By Mo-alloying and thermomechanical treatments,we have designed the(Fe_(50)Mn_(27)Ni_(10)Cr_(13))_(100-x)Mo_(x)(x=0-6 at.%)alloy series with a wide range of mechanical properties.The careful control of secondary phases introduced in the cold-rolled and annealed(Fe_(50)Mn_(27)Ni_(10)Cr_(13))Mo_(2) sample resulted in an enhanced tensile strength from 250 MPa to 665 MPa,still having~25%ductility.TEM investigations of this alloy revealed the presence of deformation twins,dislocation cells,and ordered bcc na no-pa rticles embedded in the ductile fcc matrix post-deformation.The observed deformation structures are an indication of succes s ful cooperation between deformation twinning and precipitation strengthening in enhancing the tensile strength at maintained ductility compared to its cast counterpart.This work provides insight into the tunability of the mechanical properties of non-equiatomic HEAs via alloying and thermomechanical processing.展开更多
Nondestructive cryogenically thermal cycling has been a simple but effective treatment to enhance mechanical properties of glassy materials.However,how the structural heterogeneities on nanometer scales are affected b...Nondestructive cryogenically thermal cycling has been a simple but effective treatment to enhance mechanical properties of glassy materials.However,how the structural heterogeneities on nanometer scales are affected by thermal cycling is still an issue.Here,we report the response of spatial heterogeneities in three selected Ti_(41)Zr_(25)Be_(28)Fe_(6),Zr_(56)Co_(14)Cu_(14)Al_(16)and Zr_(42)Y_(14)Co_(22)Al_(22)(at.%)metallic glasses(MGs)with different compositions to the thermal cycling,which show significantly different structure and properties after the same treatments and could be ascribed to the joint contribution of relaxation and rejuvenation induced by thermal cycling.The rejuvenation is initially prevailed in a Zr-Y-containing MG,whereas the relaxation is dominant in a Cu-Co-containing MG,both eventually entering into a dynamic equilibrium state.By employing nanometer-scale structural models,the intrinsic correlation between the spatial heterogeneity and thermal cycling is proposed.The discovery could provide the fundamental understanding of the role of spatial heterogeneity in influencing the macroscopic properties of MGs via thermal cycling and help design high-performance glassy materials by tailoring their atomic structures with suitable thermal treatments.展开更多
Tensile elastic behavior of bulk Zr46（Cu4.5/5.5Ag1/5.5）46Al8 metallic glass was experimentally investigated. It exhibited linear and non-linear time-independent elastic deformation with a demarcative stress of appro...Tensile elastic behavior of bulk Zr46（Cu4.5/5.5Ag1/5.5）46Al8 metallic glass was experimentally investigated. It exhibited linear and non-linear time-independent elastic deformation with a demarcative stress of approximately 500 MPa within the timescale in the present work, and repeated loading-unloading before yielding did not alter stress-strain relationship. The pure linear elastic strain limit is 0.6%, significantly lower than 2% as generally reported, but still much higher than 0.1% observed for typical crystalline alloys. Deviation from linear elastic behavior at stresses higher than 500 MPa is explained here as a macroscopic manifestation of local fluctuations in elastic strain, which becomes pronounced at stresses higher than the critical value. The occurrence of non-linear elasticity is possibly also related to the sinusoidal relationship between shear stress and atomic displacement.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.U1832203,11975202and 51871198)the National Key Research and Development Program of China(Nos.2016YFB0701203,2016YFB0700201,and 2017YFA0403400)+1 种基金the Natural Science Foundation of Zhejiang Province(Nos.Z1110196,Y4110192,and LY15E010003)the Fundamental Research Funds for the Central Universities。
文摘The single-phase face-centered cubic(fcc)-structured Fe_(50)Mn_(27)Ni_(10)Cr_(13) high entropy alloy(HEA)exhibits good ductility but low strength,which presents a challenge.By Mo-alloying and thermomechanical treatments,we have designed the(Fe_(50)Mn_(27)Ni_(10)Cr_(13))_(100-x)Mo_(x)(x=0-6 at.%)alloy series with a wide range of mechanical properties.The careful control of secondary phases introduced in the cold-rolled and annealed(Fe_(50)Mn_(27)Ni_(10)Cr_(13))Mo_(2) sample resulted in an enhanced tensile strength from 250 MPa to 665 MPa,still having~25%ductility.TEM investigations of this alloy revealed the presence of deformation twins,dislocation cells,and ordered bcc na no-pa rticles embedded in the ductile fcc matrix post-deformation.The observed deformation structures are an indication of succes s ful cooperation between deformation twinning and precipitation strengthening in enhancing the tensile strength at maintained ductility compared to its cast counterpart.This work provides insight into the tunability of the mechanical properties of non-equiatomic HEAs via alloying and thermomechanical processing.
基金the National Natural Science Foundation of China(Nos.U1832203,11975202,51671169,and 51671170)the National Key Research and Development Program of China(Nos.2016YFB0701203,2016YFB0700201 and 2017YFA0403400)+1 种基金the Natural Science Foundation of Zhejiang Province(Nos.LZ20E010002,Z1110196 and Y4110192)the Fundamental Research Funds for the Central Universities。
文摘Nondestructive cryogenically thermal cycling has been a simple but effective treatment to enhance mechanical properties of glassy materials.However,how the structural heterogeneities on nanometer scales are affected by thermal cycling is still an issue.Here,we report the response of spatial heterogeneities in three selected Ti_(41)Zr_(25)Be_(28)Fe_(6),Zr_(56)Co_(14)Cu_(14)Al_(16)and Zr_(42)Y_(14)Co_(22)Al_(22)(at.%)metallic glasses(MGs)with different compositions to the thermal cycling,which show significantly different structure and properties after the same treatments and could be ascribed to the joint contribution of relaxation and rejuvenation induced by thermal cycling.The rejuvenation is initially prevailed in a Zr-Y-containing MG,whereas the relaxation is dominant in a Cu-Co-containing MG,both eventually entering into a dynamic equilibrium state.By employing nanometer-scale structural models,the intrinsic correlation between the spatial heterogeneity and thermal cycling is proposed.The discovery could provide the fundamental understanding of the role of spatial heterogeneity in influencing the macroscopic properties of MGs via thermal cycling and help design high-performance glassy materials by tailoring their atomic structures with suitable thermal treatments.
基金supports from the National Key Basic Research Program of China (No. 2012CB825700)the National Natural Science Foundation of China (Nos. 50701038, 10979002, 51371157 and 11179026)+1 种基金the Natural Science Foundation of Zhejiang Province (Nos. Y4110192 and Z1110196)the Fundamental Research Funds for the Central Universities (2014FZA4006)are gratefully acknowledged
文摘Tensile elastic behavior of bulk Zr46（Cu4.5/5.5Ag1/5.5）46Al8 metallic glass was experimentally investigated. It exhibited linear and non-linear time-independent elastic deformation with a demarcative stress of approximately 500 MPa within the timescale in the present work, and repeated loading-unloading before yielding did not alter stress-strain relationship. The pure linear elastic strain limit is 0.6%, significantly lower than 2% as generally reported, but still much higher than 0.1% observed for typical crystalline alloys. Deviation from linear elastic behavior at stresses higher than 500 MPa is explained here as a macroscopic manifestation of local fluctuations in elastic strain, which becomes pronounced at stresses higher than the critical value. The occurrence of non-linear elasticity is possibly also related to the sinusoidal relationship between shear stress and atomic displacement.
