The synthetic path of a catalyst determines its morphology,species,and performance,and in-situ monitoring the catalyst formation process is fascinating and challenging.Herein,a newly developed synchrotron radiation sm...The synthetic path of a catalyst determines its morphology,species,and performance,and in-situ monitoring the catalyst formation process is fascinating and challenging.Herein,a newly developed synchrotron radiation smallangle X-ray scattering/X-ray diffraction/X-ray absorption fine structure(SAXS/XRD/XAFS)combined technique was used to in-situ monitor the isothermal-isobaric synthesis process of CO_(2)-assisted(BiO)_(2)CO_(3)(BOC)photocatalyst,and the atomic near-neighbor structure,crystalline structure and nanoscale particle size evolution with reaction time were simultaneously captured.The results show that both polyvinyl pyrrolidone and CO_(2)formed uniformly-distributed nano-sized scatterers in the Bi-based precursor solution,presenting short-range ordered structures to a certain extent.The as-prepared BOC catalytic particles underwent the evolution process of initial Bi(OH)3 precipitate,early-stage formed KBiO_(2)molecules,intermediate amorphous(BiO)4CO3(OH)2 nanoparticles,and finally crystallized flower-like BOC particles self-assembled by nanosheets.The flower-like BOC particles,Bi/BOC composite,and Bi nanospheres were further prepared with different synthesis paths.Flower-like BOC particles showed the best photocatalytic degradation performance of RhB.Scavenger experiment and theoretical calculation revealed the photocatalytic mechanisms of BOC.This work has implications for path-dependent synthesis of other catalysts.展开更多
The influence of taxation on the economy and society is everywhere. Given the fact that CO_(2) emission is closely connected with human activities, the question naturally arises whether the tax burden affects the carb...The influence of taxation on the economy and society is everywhere. Given the fact that CO_(2) emission is closely connected with human activities, the question naturally arises whether the tax burden affects the carbon emissions. To address this issue, based on the data of 21 OECD countries over the period from 1991–2014, we use the ratio of tax revenue to GDP as a proxy of the tax burden and employ a panel quantile model with the non-additive fixed effects for analysis. The results suggest that the impact of the tax burden on carbon emissions is heterogeneous across countries based on the level of carbon emissions. Moreover, we find a stable U-shaped relationship between the tax burden and carbon emissions whether for countries with a high or low level of carbon emissions. Our findings suggest that moderate taxes could help reduce carbon emissions, but the effect of excessive taxation is the opposite.展开更多
基金supported by the National Natural Science Foundation of China(12305372)the National Key R&D Program(2017YFA0403001 and 2022YFA1603802)of China。
文摘The synthetic path of a catalyst determines its morphology,species,and performance,and in-situ monitoring the catalyst formation process is fascinating and challenging.Herein,a newly developed synchrotron radiation smallangle X-ray scattering/X-ray diffraction/X-ray absorption fine structure(SAXS/XRD/XAFS)combined technique was used to in-situ monitor the isothermal-isobaric synthesis process of CO_(2)-assisted(BiO)_(2)CO_(3)(BOC)photocatalyst,and the atomic near-neighbor structure,crystalline structure and nanoscale particle size evolution with reaction time were simultaneously captured.The results show that both polyvinyl pyrrolidone and CO_(2)formed uniformly-distributed nano-sized scatterers in the Bi-based precursor solution,presenting short-range ordered structures to a certain extent.The as-prepared BOC catalytic particles underwent the evolution process of initial Bi(OH)3 precipitate,early-stage formed KBiO_(2)molecules,intermediate amorphous(BiO)4CO3(OH)2 nanoparticles,and finally crystallized flower-like BOC particles self-assembled by nanosheets.The flower-like BOC particles,Bi/BOC composite,and Bi nanospheres were further prepared with different synthesis paths.Flower-like BOC particles showed the best photocatalytic degradation performance of RhB.Scavenger experiment and theoretical calculation revealed the photocatalytic mechanisms of BOC.This work has implications for path-dependent synthesis of other catalysts.
基金Supported by the National Natural Science Foundation of China(71850012,72104075,72101120)the National Social Science Fund of China(19AZD014)+2 种基金the Major Special Projects of the Department of Science and Technology of Hunan province(2018GK1020)Hunan social science achievement review committee(XSP21YBC087)Hunan University Youth Talent Program。
文摘The influence of taxation on the economy and society is everywhere. Given the fact that CO_(2) emission is closely connected with human activities, the question naturally arises whether the tax burden affects the carbon emissions. To address this issue, based on the data of 21 OECD countries over the period from 1991–2014, we use the ratio of tax revenue to GDP as a proxy of the tax burden and employ a panel quantile model with the non-additive fixed effects for analysis. The results suggest that the impact of the tax burden on carbon emissions is heterogeneous across countries based on the level of carbon emissions. Moreover, we find a stable U-shaped relationship between the tax burden and carbon emissions whether for countries with a high or low level of carbon emissions. Our findings suggest that moderate taxes could help reduce carbon emissions, but the effect of excessive taxation is the opposite.
