[Objectives]This study was conducted to optimize the Formulation Process of glucosamine chondroitin sulfate tablets. [Methods] The orthogonal design with three levels was carried out with microcrystalline cellulose, c...[Objectives]This study was conducted to optimize the Formulation Process of glucosamine chondroitin sulfate tablets. [Methods] The orthogonal design with three levels was carried out with microcrystalline cellulose, calcium hydrophosphate and cross-linked polyvinylpyrrolidone as three factors to optimize the preparation process. [Results] When microcrystalline cellulose 200 mg/tablet, calcium hydrophosphate 150 mg/tablet, and cross-linked polyvinylpyrrolidone 80 mg/tablet were added, the angle of repose could meet the requirements of tablet pressing, and the dissolution could reach more than 95% in 30 min. The results of the orthogonal test showed that the dissolution effect of self-made tablets was faster than that of commercial products. [Conclusions] The glucosamine hydrochloride chondroitin sulfate tablets prepared by this prescription have better quality.展开更多
Using a three-dimensional classical ensemble model,we investigate the dependence of relative frequency and relative initial phase for nonsequential double ionization(NSDI)of atoms driven by orthogonal two-color(OTC)fi...Using a three-dimensional classical ensemble model,we investigate the dependence of relative frequency and relative initial phase for nonsequential double ionization(NSDI)of atoms driven by orthogonal two-color(OTC)fields.Our findings reveal that the NSDI probability is clearly dependent on the relative initial phase of OTC fields at different relative frequencies.The inversion analysis results indicate that adjusting the relative frequency of OTC fields helps control returning probability and flight time of the first electron.Furthermore,manipulating the relative frequency at the same relative initial phases can vary the revisit time of the recolliding electron,leading that the emission direction of Ar^(2+)ions is explicitly dependent on the relative frequency.展开更多
Interface control in inorganic/organic composites has always been regarded as one of the effective means to optimize their thermoelectric(TE)performance,and the past few years have witnessed its development,including ...Interface control in inorganic/organic composites has always been regarded as one of the effective means to optimize their thermoelectric(TE)performance,and the past few years have witnessed its development,including carrier-energy filtering and phonon scattering.However,the energy barrier created by the band alignment at the composite interface depends on the Fermi level difference between the organic and inorganic components,which is difficult to be controlled by the common means.Herein,a core/hybrid-shell strategy aiming for efficient interface control is proposed to tune the energy barrier of the inorganic/organic core/shell nanowire interface.The Fermi level of hybrid-shell can be effectively controlled by separating the charge carriers compared to the single-shell composites.The energy barrier of the core/hybrid-shell interface is tuned to an appropriate position,and the energy filtering effect is utilized,resulting in a substantial improvement in power factor and reduction in thermal conductivity for the prepared core/hybrid-shell composites with good air-stability and flexibility.Moreover,both the flexible p type and p-n type TE devices based on the prepared core/hybrid-shell films yield excellent output properties with the maximum power densities of 41 and 45μW·cm^(−2)at a temperature difference of ca.30 K,respectively.This study provides a novel strategy to improve the TE performance of the inorganic/organic composites,displaying great potential for low-power wearable electronics.展开更多
Corrosion protection of the hull steel by the conventional epoxy paint containing a small amount of commercial poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate)(PEDOT/PSS),which is one of the most popular and s...Corrosion protection of the hull steel by the conventional epoxy paint containing a small amount of commercial poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate)(PEDOT/PSS),which is one of the most popular and successful inherently conducting polymers as the corrosion inhibitor was studied.The corrosion behavior of the samples was investigated in seawater by electrochemical impedance spectroscopy and open circuit potential.Scanning electron microscopy was used to observe the surface morphology of the samples after corrosion.It was found that adding a small amount of PEDOT/PSS to the epoxy resin can significantly improve its corrosion protection.展开更多
π-Conjugated polymers(CPs)represent one of the quite important and rapidly growing branches of flexible electrochromic materials.Electrosynthesized hybrid CPs employing dibenzo pentacycles(fluorenes,carbazoles,dibenz...π-Conjugated polymers(CPs)represent one of the quite important and rapidly growing branches of flexible electrochromic materials.Electrosynthesized hybrid CPs employing dibenzo pentacycles(fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran)as the backbones have received considerable attention owing to their special structures and interesting electrochromic performances.Recent studies show that polymers from these structures exhibit decent contrast ratios,favorable coloration efficiencies,low switching voltages,fast response time,excellent stability,and color persistence.Intrinsically,their electrochromic properties significantly depend on fine-tailoring of precursor monomer structures,and polymerization techniques and conditions.This review devotes to showing a clear picture of the research progress of dibenzo pentacycle-centered CPs via electrochemical polymerization,including fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran-based hybrid electrochromic polymers.Critical influences of the tailored precursor structures on their electropolymerization and resultant polymer performances are highlighted,aiming at providing an insight for the development of novel fused ring-based polymer electrochromic materials.展开更多
Photocatalysts with exposure of different crystal facets often show great differences in their photocatalytic activities due to differences in surface atomic arrangement and coordination.Thus,the actual photoreaction ...Photocatalysts with exposure of different crystal facets often show great differences in their photocatalytic activities due to differences in surface atomic arrangement and coordination.Thus,the actual photoreaction mechanism of a specific crystal facet in photocatalysis deserves to be explored.In this paper,as a case study,Sr Bi_(2)Ta_(2)O_(9)photocatalyst with preferential facet exposure was explored for the photocatalytic removal of NO at a ppb level.The efficiency of NO removal was remarkably improved by tuning the crystal exposure facet with high(200)facet exposure ratio.Optimized exposure of(200)crystal facet in Sr Bi_(2)Ta_(2)O_(9)(SBT)by thermal calcination at 800℃(SBT-800)leads to the highest NO removal activity of51%under a 300 W Xe lamp for 20 min;under visible light,SBT 800 achieves a 5-fold enhancement in NO removal efficiency compared to its counterpart,SBT-900.Active species capture experiments prove that the superoxide radical·O_(2)-is the main active species for the photocatalytic removal of NO,and surface selective deposition experiments conclude that(200)is the main electron-rich crystal plane,based on which the results of density functional theory(DFT)computation reveal the Bi O terminated nature of(001)crystal plane,where the models with both Bi O and Ta O terminated(001)planes were created and computated.Mechanistic study reveals that Sr Bi_(2)Ta_(2)O_(9)with a larger exposure of(200)facet provides more active reduction sites,thereby reducing more O_(2)to·O_(2)-,which further oxidizes the adsorbed NO to NO_(2)-/NO_(3)-.The present work underlines the role of facet tuning in the photoactivity modulation for NO removal photocatalytically.展开更多
A ternary single-walled carbon nanotubes/RuO2/polyindole(SWCNT/RuO2/PIn)nanocomposite was fabricated by the oxidation polymerization of indole on the prefabricated SWCNT/RuO2 binary nanocomposites.The nanocomposite wa...A ternary single-walled carbon nanotubes/RuO2/polyindole(SWCNT/RuO2/PIn)nanocomposite was fabricated by the oxidation polymerization of indole on the prefabricated SWCNT/RuO2 binary nanocomposites.The nanocomposite was measured by FTIR,XRD,SEM,TEM,EDS and XPS,together with the electrochemical technique.The electrochemical results demonstrated that the symmetric supercapacitor used SWCNT/RuO2/PIn as electrodes presented 95%retention rate after 10000 cycles,superior capacitive performance of1203 F·g^-1 at1 A·g^-1,and high energy density of 33 w h·kg^-1 at 5000 W·kg^-1.The high capacitance performance of SWCNT/RuO2/PIn nanocomposite was mainly ascribed to the beneficial cooperation effect among components.This indicated that the SWCNT/RuO2/PIn nanocomposite would be a good candidate for high-performance supercapacitors.展开更多
基金Supported by School-level High-level Talent Project (XGY2021A022)Doctoral Research Startup Fund of Department of Science&Technology of Liaoning Province (2021-BS-252)。
文摘[Objectives]This study was conducted to optimize the Formulation Process of glucosamine chondroitin sulfate tablets. [Methods] The orthogonal design with three levels was carried out with microcrystalline cellulose, calcium hydrophosphate and cross-linked polyvinylpyrrolidone as three factors to optimize the preparation process. [Results] When microcrystalline cellulose 200 mg/tablet, calcium hydrophosphate 150 mg/tablet, and cross-linked polyvinylpyrrolidone 80 mg/tablet were added, the angle of repose could meet the requirements of tablet pressing, and the dissolution could reach more than 95% in 30 min. The results of the orthogonal test showed that the dissolution effect of self-made tablets was faster than that of commercial products. [Conclusions] The glucosamine hydrochloride chondroitin sulfate tablets prepared by this prescription have better quality.
基金supported by the National Natural Science Foundation of China(Grant Nos.12074329,12004323,12104389,1174131,and 91850114)the Nanhu Scholars Program for Young Scholars of Xinyang Normal Universitythe Open Research Fund of State Key Laboratory of Transient Optics and Photonics。
文摘Using a three-dimensional classical ensemble model,we investigate the dependence of relative frequency and relative initial phase for nonsequential double ionization(NSDI)of atoms driven by orthogonal two-color(OTC)fields.Our findings reveal that the NSDI probability is clearly dependent on the relative initial phase of OTC fields at different relative frequencies.The inversion analysis results indicate that adjusting the relative frequency of OTC fields helps control returning probability and flight time of the first electron.Furthermore,manipulating the relative frequency at the same relative initial phases can vary the revisit time of the recolliding electron,leading that the emission direction of Ar^(2+)ions is explicitly dependent on the relative frequency.
基金supported by the financial support of the National Natural Science Foundation of China(Nos.51863009,52073128,52272214,and 22065013)the Natural Science Foundation of Jiangxi province(Nos.20202ACBL204005,20202ACBL214005,20212BAB214017,and 20203AEI003)C.C.L.acknowledges the support from the program of Chinese Scholarships Council(CSC No.201906070063)。
文摘Interface control in inorganic/organic composites has always been regarded as one of the effective means to optimize their thermoelectric(TE)performance,and the past few years have witnessed its development,including carrier-energy filtering and phonon scattering.However,the energy barrier created by the band alignment at the composite interface depends on the Fermi level difference between the organic and inorganic components,which is difficult to be controlled by the common means.Herein,a core/hybrid-shell strategy aiming for efficient interface control is proposed to tune the energy barrier of the inorganic/organic core/shell nanowire interface.The Fermi level of hybrid-shell can be effectively controlled by separating the charge carriers compared to the single-shell composites.The energy barrier of the core/hybrid-shell interface is tuned to an appropriate position,and the energy filtering effect is utilized,resulting in a substantial improvement in power factor and reduction in thermal conductivity for the prepared core/hybrid-shell composites with good air-stability and flexibility.Moreover,both the flexible p type and p-n type TE devices based on the prepared core/hybrid-shell films yield excellent output properties with the maximum power densities of 41 and 45μW·cm^(−2)at a temperature difference of ca.30 K,respectively.This study provides a novel strategy to improve the TE performance of the inorganic/organic composites,displaying great potential for low-power wearable electronics.
基金the financial support from the National Natural Science Foundation of China(Nos.50963002 and 51073074)
文摘Corrosion protection of the hull steel by the conventional epoxy paint containing a small amount of commercial poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate)(PEDOT/PSS),which is one of the most popular and successful inherently conducting polymers as the corrosion inhibitor was studied.The corrosion behavior of the samples was investigated in seawater by electrochemical impedance spectroscopy and open circuit potential.Scanning electron microscopy was used to observe the surface morphology of the samples after corrosion.It was found that adding a small amount of PEDOT/PSS to the epoxy resin can significantly improve its corrosion protection.
基金the National Natural Science Foundationof China(51303073,51463008,51572117)the Ganpo Outstanding Talents 555 projects(2013)+4 种基金the National Science Fund for Distinguished Young Scholars in Jiangxi Province,Key Project of Jiangxi Educational Committee(GJJ150795)the Natural Science Foundation of Jiangxi Province(20161BAB216130)Scientific Fund of Jiangxi Science & Technology Normal University(2014QNBJRC003)Jiangxi Science & Technology Normal University Program for Scientific Research Innovation Team (2015CXTD001)Scientific Research Foundation for Doctors in Jiangxi Science & Technology
文摘π-Conjugated polymers(CPs)represent one of the quite important and rapidly growing branches of flexible electrochromic materials.Electrosynthesized hybrid CPs employing dibenzo pentacycles(fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran)as the backbones have received considerable attention owing to their special structures and interesting electrochromic performances.Recent studies show that polymers from these structures exhibit decent contrast ratios,favorable coloration efficiencies,low switching voltages,fast response time,excellent stability,and color persistence.Intrinsically,their electrochromic properties significantly depend on fine-tailoring of precursor monomer structures,and polymerization techniques and conditions.This review devotes to showing a clear picture of the research progress of dibenzo pentacycle-centered CPs via electrochemical polymerization,including fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran-based hybrid electrochromic polymers.Critical influences of the tailored precursor structures on their electropolymerization and resultant polymer performances are highlighted,aiming at providing an insight for the development of novel fused ring-based polymer electrochromic materials.
基金supported by the National Natural Science Foundation of China(Nos.21976116,52161145409)Shaanxi Science and Technology Program(No.2020KWZ-005)+3 种基金High Level Talents Introduction Project of"Pearl River Talent Plan"in Guangdong Province(No.2019CX01L308)the Support Scheme of Guangzhou for Leading Talents in Innovation and Entrepreneurship Funding(No.2016015)SAFEA of China(High-end Foreign Expert Project)Alexander-von-Humboldt Foundation of Germany(Group-Linkage Program)。
文摘Photocatalysts with exposure of different crystal facets often show great differences in their photocatalytic activities due to differences in surface atomic arrangement and coordination.Thus,the actual photoreaction mechanism of a specific crystal facet in photocatalysis deserves to be explored.In this paper,as a case study,Sr Bi_(2)Ta_(2)O_(9)photocatalyst with preferential facet exposure was explored for the photocatalytic removal of NO at a ppb level.The efficiency of NO removal was remarkably improved by tuning the crystal exposure facet with high(200)facet exposure ratio.Optimized exposure of(200)crystal facet in Sr Bi_(2)Ta_(2)O_(9)(SBT)by thermal calcination at 800℃(SBT-800)leads to the highest NO removal activity of51%under a 300 W Xe lamp for 20 min;under visible light,SBT 800 achieves a 5-fold enhancement in NO removal efficiency compared to its counterpart,SBT-900.Active species capture experiments prove that the superoxide radical·O_(2)-is the main active species for the photocatalytic removal of NO,and surface selective deposition experiments conclude that(200)is the main electron-rich crystal plane,based on which the results of density functional theory(DFT)computation reveal the Bi O terminated nature of(001)crystal plane,where the models with both Bi O and Ta O terminated(001)planes were created and computated.Mechanistic study reveals that Sr Bi_(2)Ta_(2)O_(9)with a larger exposure of(200)facet provides more active reduction sites,thereby reducing more O_(2)to·O_(2)-,which further oxidizes the adsorbed NO to NO_(2)-/NO_(3)-.The present work underlines the role of facet tuning in the photoactivity modulation for NO removal photocatalytically.
基金supported by the National Natural Science Foundation of China(Grant Nos.51862011 and 51662012)the Jiangxi Outstanding Young Talent Fund Projects(20171 BCB23076)+1 种基金the Natural Science Foundation of Jiangxi Province(20171BAB206013)the Young Top-Notch Talent of Jiangxi Science and Technology Normal University(2016QNBJRC001).
文摘A ternary single-walled carbon nanotubes/RuO2/polyindole(SWCNT/RuO2/PIn)nanocomposite was fabricated by the oxidation polymerization of indole on the prefabricated SWCNT/RuO2 binary nanocomposites.The nanocomposite was measured by FTIR,XRD,SEM,TEM,EDS and XPS,together with the electrochemical technique.The electrochemical results demonstrated that the symmetric supercapacitor used SWCNT/RuO2/PIn as electrodes presented 95%retention rate after 10000 cycles,superior capacitive performance of1203 F·g^-1 at1 A·g^-1,and high energy density of 33 w h·kg^-1 at 5000 W·kg^-1.The high capacitance performance of SWCNT/RuO2/PIn nanocomposite was mainly ascribed to the beneficial cooperation effect among components.This indicated that the SWCNT/RuO2/PIn nanocomposite would be a good candidate for high-performance supercapacitors.
