Efficient parallel screening of combinatorial lib-ra ries is one of the most challenging aspects of the high-throughput(HT) heterogeneous catalysis workflow. Today, a number of methods have been used in HT catalyst st...Efficient parallel screening of combinatorial lib-ra ries is one of the most challenging aspects of the high-throughput(HT) heterogeneous catalysis workflow. Today, a number of methods have been used in HT catalyst studies, including various optical, mass-spectrometry, and gas-chromatography techniques. Of these, rapid-scanning Fourier-transform infrared(FTIR) imaging is one of the fastest and most versatile screening techniques. Here, the new design of the 16--channel HT reactor is presented and test results for its accuracy and reproducibility are shown. The performance of the system was evaluated through the oxidation of CO over commercial Pd/Al_2O_3 and cobalt oxide nanoparticles synthesized with different reducer-reductant molar ratios, surfactant types, metal and surfactant concentrations, synthesis temperatures, and ramp rates.展开更多
基金the South Carolina Smart State Center for Strategic Approaches to the Generation of Electricity (SAGE) for funding
文摘Efficient parallel screening of combinatorial lib-ra ries is one of the most challenging aspects of the high-throughput(HT) heterogeneous catalysis workflow. Today, a number of methods have been used in HT catalyst studies, including various optical, mass-spectrometry, and gas-chromatography techniques. Of these, rapid-scanning Fourier-transform infrared(FTIR) imaging is one of the fastest and most versatile screening techniques. Here, the new design of the 16--channel HT reactor is presented and test results for its accuracy and reproducibility are shown. The performance of the system was evaluated through the oxidation of CO over commercial Pd/Al_2O_3 and cobalt oxide nanoparticles synthesized with different reducer-reductant molar ratios, surfactant types, metal and surfactant concentrations, synthesis temperatures, and ramp rates.
