Roadside soil samples were collected from four sites (heavy traffic area (Wurukum);industrial site (Gboko road);residential area (Federal Lowcost) and FederalMedicalCenter(Wadata) representing different activities acr...Roadside soil samples were collected from four sites (heavy traffic area (Wurukum);industrial site (Gboko road);residential area (Federal Lowcost) and FederalMedicalCenter(Wadata) representing different activities across the Benue Metropolis. At each of the sample site, roadside soils were collected at different distance from the edge of the main road (2, 10, 30, 40 and 60 meters). In each of the distance, roadside soil were collected at three depth of 0 -1 cm, 2 -4 cmand 4 - 6 cm for the determination of pH, organic matter, organic carbon, Cu, Cd, Fe, Pb, As, Mn, Zn, Cd and Ni. pH, electrical conductivity (EC), organic matter and organic carbon were determined using standard procedures, while heavy metals were determined using Perkin-Elmer Analyst 300 Atomic Absorption spectroscopy (AAS). Zinc was observed to show the higher levels in all the sampling sites, such higher level can be related back to the wear-and-tear of vehicle components as a result of the stop-start traffic patterns and brake pads. The concentrations of all the metals in the four sampling sites decreased exponentially with distance from the edge of the road and dropped to the minimum levels at about 60 meters. Similarly, mean concentrations of Cu, Fe, Pb, As, Mn, Zn, Cd and Ni were significantly higher around the industrial area (Gboko road) and heavy traffic (Wurunkum) areas than other sampling areas followed an increasing trend with the increase in depth. The vertical movement of all the metals, exhibited predominant association with soil pH and organic carbon. From the results of this study, the pH of the roadside soils from all the sampling points ranged from 4.56 to 7.71, which enhances increased of heavy metals down the soil profiles. Organic carbon content ranged of 0.27% to 5.44% across all the sampling points appears to increase the mobility of all the metals to a depth6 cm. The values of the heavy metals suggest that automobiles and traffic activities are a major source of these metals in the roadside soil within the study area. Also, with the exception of Pb, Fe and Cd, the levels of Cu, As, Mn, Zn and Ni in the present study were lower as compared with results found by other researcher in various countries worldwide.展开更多
This study was aim to determined the levels of some heavy metals in the gills, liver, stomach, kidney, bones and flesh of four fish species (Tilapia zilli, Clarias anguillaris, Synodentis budgetti and Oreochronmis nil...This study was aim to determined the levels of some heavy metals in the gills, liver, stomach, kidney, bones and flesh of four fish species (Tilapia zilli, Clarias anguillaris, Synodentis budgetti and Oreochronmis niloticus) collected at River Benue in Vinikilang, Adamawa State, Nigeria for analysis of Cu, Zn, Co, Mn, Fe, Cr, Cd, Ni and Pb. These metals were chosen because at higher concentrations there might be toxic to the fish and by extension humans that depends on such fish as food. The concentrations of the metals were carried out using Flame Atomic Absorption Spectrophotometer (AAS, Unicam 969). Large differences in trace metal concentrations were observed between different tissues within each fish. The highest concentration of Fe (12.65 μg/g) was recorded in gill of Synodentis budgetti, while the lowest value of 0.68 μg/g was recorded in the flesh of Oreochronmis niloticus. The liver of Synodentis budgetti accumulates significant higher levels of Mn and Cd than other species;Fe and Zn was highest in the stomach of Tilapia zilli, while Clarias angullaris shows more of Cr, Pb, Cd and Co. The stomach of Synodentis budgetti accumulate significant higher levels of Fe than other species;Zn was highest in the stomach of Tilapia zilli, while Clarias angullaris shows more of Mn, Cr, Cu, Cd and Pb. Similarly, the bone of Synodentis budgettiaccumulates significant higher levels of Mn and Cd than other species;Zn and Fe were highest in the bone of Tilapia zilli, while Clarias angullaris shows more of Cr, Pb, Ni, and Co. The highest levels of Fe (12.65 μg/g) observed in this study was recorded in the gill of Synodentis budgetti and it was below the high residue concentrations of Fe (34 - 107 ppm) in fish samples. Based on the above results, it can therefore be concluded that metals bioaccumulation in the entire fish species study did not exceeds the permissible limits set for heavy metals by FAO, FEPA and WHO.展开更多
The purpose of this research is to determine the levels of some physicochemical parameters in water and sediment samples from Kwantan turare in Lake Chad, Baga, Borno State, Nigeria. Water samples were collected from ...The purpose of this research is to determine the levels of some physicochemical parameters in water and sediment samples from Kwantan turare in Lake Chad, Baga, Borno State, Nigeria. Water samples were collected from five point designated as S1 to S5 for the determination of biochemical oxygen demand (BOD), chemical oxygen demand (COD), dissolved oxygen (DO) total dissolved solid (TDS), total suspended solid (TSS) anions and trace element. Sediment samples were also collected for the determination of heavy metals and total organic carbon (TOC). These parameters were determined using approved standard procedures. The levels of heavy metals in the water and sediment samples were determined using atomic absorption spectrophotometer (AAS). The concentrations of DO, BOD, COD, TSS, TDS, TOC, nitrite, nitrate, Phosphate, Sulphate, and Chloride in the water samples from the five sampling point were higher than the WHO limits for the protection of fish and other aquatic life. The concentrations of Fe, Mn, Cu, Cd, Pb, Ni and Co in the water samples were higher than the WHO guideline limits, indicating severed pollution of this portion of Lake Chad. This high level of heavy metals in the water samples is expected owing to runoff of wastewater from agricultural activities within the study area. However, the concentrations of all the metals in the sediment samples were higher than the recommended values stipulated by WHO;indicating that the sediment samples from this portion of Lake Chad were also polluted by heavy metals. Results of Analysis of variance (ANOVA) revealed that the concentrations of all the parameters studied were statistically significant among the sampling points. The prolonged presence of heavy metals in the water and sediment samples from this portion of Lake Chad give course for concern with time. The results of the study implies that continuous monitoring has to be carried out to ascertain the long-term impact of anthropogenic inputs to take remedial measures so as to ensure the health of aquatic life.展开更多
文摘Roadside soil samples were collected from four sites (heavy traffic area (Wurukum);industrial site (Gboko road);residential area (Federal Lowcost) and FederalMedicalCenter(Wadata) representing different activities across the Benue Metropolis. At each of the sample site, roadside soils were collected at different distance from the edge of the main road (2, 10, 30, 40 and 60 meters). In each of the distance, roadside soil were collected at three depth of 0 -1 cm, 2 -4 cmand 4 - 6 cm for the determination of pH, organic matter, organic carbon, Cu, Cd, Fe, Pb, As, Mn, Zn, Cd and Ni. pH, electrical conductivity (EC), organic matter and organic carbon were determined using standard procedures, while heavy metals were determined using Perkin-Elmer Analyst 300 Atomic Absorption spectroscopy (AAS). Zinc was observed to show the higher levels in all the sampling sites, such higher level can be related back to the wear-and-tear of vehicle components as a result of the stop-start traffic patterns and brake pads. The concentrations of all the metals in the four sampling sites decreased exponentially with distance from the edge of the road and dropped to the minimum levels at about 60 meters. Similarly, mean concentrations of Cu, Fe, Pb, As, Mn, Zn, Cd and Ni were significantly higher around the industrial area (Gboko road) and heavy traffic (Wurunkum) areas than other sampling areas followed an increasing trend with the increase in depth. The vertical movement of all the metals, exhibited predominant association with soil pH and organic carbon. From the results of this study, the pH of the roadside soils from all the sampling points ranged from 4.56 to 7.71, which enhances increased of heavy metals down the soil profiles. Organic carbon content ranged of 0.27% to 5.44% across all the sampling points appears to increase the mobility of all the metals to a depth6 cm. The values of the heavy metals suggest that automobiles and traffic activities are a major source of these metals in the roadside soil within the study area. Also, with the exception of Pb, Fe and Cd, the levels of Cu, As, Mn, Zn and Ni in the present study were lower as compared with results found by other researcher in various countries worldwide.
文摘This study was aim to determined the levels of some heavy metals in the gills, liver, stomach, kidney, bones and flesh of four fish species (Tilapia zilli, Clarias anguillaris, Synodentis budgetti and Oreochronmis niloticus) collected at River Benue in Vinikilang, Adamawa State, Nigeria for analysis of Cu, Zn, Co, Mn, Fe, Cr, Cd, Ni and Pb. These metals were chosen because at higher concentrations there might be toxic to the fish and by extension humans that depends on such fish as food. The concentrations of the metals were carried out using Flame Atomic Absorption Spectrophotometer (AAS, Unicam 969). Large differences in trace metal concentrations were observed between different tissues within each fish. The highest concentration of Fe (12.65 μg/g) was recorded in gill of Synodentis budgetti, while the lowest value of 0.68 μg/g was recorded in the flesh of Oreochronmis niloticus. The liver of Synodentis budgetti accumulates significant higher levels of Mn and Cd than other species;Fe and Zn was highest in the stomach of Tilapia zilli, while Clarias angullaris shows more of Cr, Pb, Cd and Co. The stomach of Synodentis budgetti accumulate significant higher levels of Fe than other species;Zn was highest in the stomach of Tilapia zilli, while Clarias angullaris shows more of Mn, Cr, Cu, Cd and Pb. Similarly, the bone of Synodentis budgettiaccumulates significant higher levels of Mn and Cd than other species;Zn and Fe were highest in the bone of Tilapia zilli, while Clarias angullaris shows more of Cr, Pb, Ni, and Co. The highest levels of Fe (12.65 μg/g) observed in this study was recorded in the gill of Synodentis budgetti and it was below the high residue concentrations of Fe (34 - 107 ppm) in fish samples. Based on the above results, it can therefore be concluded that metals bioaccumulation in the entire fish species study did not exceeds the permissible limits set for heavy metals by FAO, FEPA and WHO.
文摘The purpose of this research is to determine the levels of some physicochemical parameters in water and sediment samples from Kwantan turare in Lake Chad, Baga, Borno State, Nigeria. Water samples were collected from five point designated as S1 to S5 for the determination of biochemical oxygen demand (BOD), chemical oxygen demand (COD), dissolved oxygen (DO) total dissolved solid (TDS), total suspended solid (TSS) anions and trace element. Sediment samples were also collected for the determination of heavy metals and total organic carbon (TOC). These parameters were determined using approved standard procedures. The levels of heavy metals in the water and sediment samples were determined using atomic absorption spectrophotometer (AAS). The concentrations of DO, BOD, COD, TSS, TDS, TOC, nitrite, nitrate, Phosphate, Sulphate, and Chloride in the water samples from the five sampling point were higher than the WHO limits for the protection of fish and other aquatic life. The concentrations of Fe, Mn, Cu, Cd, Pb, Ni and Co in the water samples were higher than the WHO guideline limits, indicating severed pollution of this portion of Lake Chad. This high level of heavy metals in the water samples is expected owing to runoff of wastewater from agricultural activities within the study area. However, the concentrations of all the metals in the sediment samples were higher than the recommended values stipulated by WHO;indicating that the sediment samples from this portion of Lake Chad were also polluted by heavy metals. Results of Analysis of variance (ANOVA) revealed that the concentrations of all the parameters studied were statistically significant among the sampling points. The prolonged presence of heavy metals in the water and sediment samples from this portion of Lake Chad give course for concern with time. The results of the study implies that continuous monitoring has to be carried out to ascertain the long-term impact of anthropogenic inputs to take remedial measures so as to ensure the health of aquatic life.
