Opencast coal mining produces trash of soil and rock containing various minerals,that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drain...Opencast coal mining produces trash of soil and rock containing various minerals,that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drainage(AMD)through oxidation pyrite minerals.The current study entailed assessing the potential production of AMD from an opencast coal mining region in Northeast part of India.In order to have a comprehensive overview of the AMD problem in Makum coalfield,the physico-chemical,geochemical,and petrological characteristics of the coal and overburden(OB)samples collected from the Makum coalfield(Northeast India)were thoroughly investigated.The maceral compositions reveal that coal features all three groups of macerals(liptinite,vitrinite,and inertinite),with a high concentration of liptinite indicating the coal of perhydrous,thereby rendering it more reactive.Pyrite(FeS_(2))oxidation kinetics were studied by conducting the aqueous leaching experiments of coal and(OB)samples to interpret the chemical weathering under controlled laboratory conditions of various temperature and time periods,and to replicate the actual mine site leaching.Inductively coupled plasma-optical emission spectroscopy(ICP-OES)was operated to detect the disposal of some precarious elements from coal and OB samples to the leachates during our controlled leaching experiment.The Rare earth element(REE)enrichment in the samples shows the anthropogenic incorporation of the REE in the coal and OB.These experiments reveal the change in conductivity,acid producing tendency,total dissolved solid(TDS),total Iron(Fe)and dissolved Sulfate(SO_(4)^(2−))ions on progress of the leaching experiments.Moreover,the discharge of FeS_(2) via atmospheric oxidation in laboratory condition undergoes a significant growth with the rise of temperature of the reaction systems in the environment and follows pseudo first order kinetics.A bio-remediative strategies is also reported in this paper to mitigate AMD water by employing size-segregated powdered limestone and water hyacinth plant in an indigenously developed site-specific prototype station.Apart from neutralisation of AMD water,this eco-friendly AMD remediation strategy demonstrates a reduction in PHEs concentrations in the treated AMD water.展开更多
Meso-Neoarchean fuchsite quartzites are present in different stratigraphic positions of Dharwar Craton including the oldest(~3.3 Ga)Sargur Group of western Dharwar Craton.The present study deals with the petro-graphic...Meso-Neoarchean fuchsite quartzites are present in different stratigraphic positions of Dharwar Craton including the oldest(~3.3 Ga)Sargur Group of western Dharwar Craton.The present study deals with the petro-graphic and geochemical characteristics of the fuchsite quartzites from the Ghattihosahalli belt to evaluate their genesis,depositional setting and the enigma involved in the ancient sedimentation history.Their major mineral assemblages include quartz,fuchsite,and feldspars along with accessory kyanite and rutile.The geochemical com-positions are characterized by high SiO_(2),Al_(2)O_(3),low MgO,CaO,strongly enriched Cr(1326–6899 ppm),Ba(1165–3653 ppm),Sr(46–210 ppm),V(107–868 ppm)and Zn(11–158 ppm)contents compared to the upper continental crust(UCC).The UCC normalized rare earth element(REE)patterns are characterized by depleted light REE[(La/Sm)UCC=0.33–0.95]compared to heavy REE[(Gd/Yb)_(UCC)=0.42–1.65]with conspicuous positive Eu-anomalies(Eu/Eu^(*)=1.35–18.27)characteristic of hydrothermal solutions evidenced through the interlayered barites.The overall major and trace element systematics reflect a combined mafic-felsic provenance and suggest their deposition at a passive continental margin environ-ment.The comprehensivefield,petrographic,and geo-chemical studies indicate that these quartzites are infiltrated by Cr-richfluids released during high-grade metamorphism of associated ultramafic rocks.The Sargur and the subse-quent Dharwar orogeny amalgamated diverse lithounits from different tectonic settings,possibly leading to the release of Cr-richfluids and the formation of fuchsite quartzite during or after the orogeny.Thesefindings sug-gest a pre-existing stable crust prior to the Sargur Group and the link between orogenic events and various mineral deposits in the Dharwar Craton.展开更多
This study reports major, trace, rare earth and platinum group element compositions of lava flows from the Vempalle Formation of Cuddapah Basin through an integrated petrological and geochemical approach to address ma...This study reports major, trace, rare earth and platinum group element compositions of lava flows from the Vempalle Formation of Cuddapah Basin through an integrated petrological and geochemical approach to address mantle conditions, magma generation processes and tectonic regimes involved in their formation. Six flows have been identified on the basis of morphological features and systematic three-tier arrangement of vesicular-entablature-colonnade zones. Petrographically, the studied flows are porphyritic basalts with plagioclase and clinopyroxene representing dominant phenocrystal phases.Major and trace element characteristics reflect moderate magmatic differentiation and fractional crystallization of tholeiitic magmas. Chondrite-normalized REE patterns corroborate pronounced LREE/HREE fractionation with LREE enrichment over MREE and HREE. Primitive mantle normalized trace element abundances are marked by LILE-LREE enrichment with relative HFSE depletion collectively conforming to intraplate magmatism with contributions from sub-continental lithospheric mantle(SCLM) and extensive melt-crust interaction. PGE compositions of Vempalle lavas attest to early sulphur-saturated nature of magmas with pronounced sulphide fractionation, while PPGE enrichment over IPGE and higher Pd/Ir ratios accord to the role of a metasomatized lithospheric mantle in the genesis of the lava flows. HFSEREE-PGE systematics invoke heterogeneous mantle sources comprising depleted asthenospheric MORB type components combined with plume type melts. HFSE-REE variations account for polybaric melting at variable depths ranging from garnet to spinel lherzolite compositional domains of mantle. Intraplate tectonic setting for the Vempalle flows with P-MORB affinity is further substantiated by(i) their origin from a rising mantle plume trapping depleted asthenospheric MORB mantle during ascent,(ii) interaction between plume-derived melts and SCLM,(iii) their rift-controlled intrabasinal emplacement through Archeane Proterozoic cratonic blocks in a subduction-unrelated ocean-continent transition zone(OCTZ). The present study is significant in light of the evolution of Cuddapah basin in the global tectonic framework in terms of its association with Antarctica, plume incubation, lithospheric melting and thinning, asthenospheric infiltration collectively affecting the rifted margin of eastern Dharwar Craton and serving as precursors to supercontinent disintegration.展开更多
Oldest rocks are sparsely distributed within the Dharwar Craton and little is known about their involvement in the sedimentary sequences which are present in the Archean greenstone successions and the Proterozoic Cudd...Oldest rocks are sparsely distributed within the Dharwar Craton and little is known about their involvement in the sedimentary sequences which are present in the Archean greenstone successions and the Proterozoic Cuddapah basin.Stromatolitic carbonates are well preserved in the Neoarchean greenstone belts of Dharwar Craton and Cuddapah Basin of Peninsular India displaying varied morphological and geochemical characteristics.In this study,we report results from U-Pb geochronology and trace element composition of the detrital zircons from stromatolitic carbonates present within the Dharwar Craton and Cuddapah basin to understand the provenance and time of accretion and deposition.The UPb ages of the detrital zircons from the Bhimasamudra and Marikanve stromatolites of the Chitradurga greenstone belt of Dharwar Craton display ages of 3426±26 Ma to 2650±38 Ma whereas the Sandur stromatolites gave an age of 3508±29 Ma to 2926±36 Ma suggesting Paleo-to Neoarchean provenance.The U-Pb detrital zircons of the Tadpatri stromatolites gave an age of 2761±31 Ma to1672±38 Ma suggesting Neoarchean to Mesoproterozoic provenance.The Rare Earth Element(REE)patterns of the studied detrital zircons from Archean Dharwar Craton and Proterozoic Cuddapah basin display depletion in light rare earth elements(LREE)and enrichment in heavy rare earth elements(HREE)with pronounced positive Ce and negative Eu anomalies,typical of magmatic zircons.The trace element composition and their relationship collectively indicate a mixed granitoid and mafic source for both the Dharwar and Cuddapah stromatolites.The 3508±29 Ma age of the detrital zircons support the existence of 3.5 Ga crust in the Western Dharwar Craton.The overall detrital zircon ages(3.5-2.7 Ga)obtained from the stromatolitic carbonates of Archean greenstone belts and Proterozoic Cuddapah basin(2.7-1.6 Ga)collectively reflect on^800-900 Ma duration for the Precambrian stromatolite deposition in the Dharwar Craton.展开更多
The Neoarchean Bundelkhand greenstone sequences at Mauranipur and Babina areas within the Bundelkhand Gneissic Complex preserve a variety of magmatic rocks such as komatiitic basalts, basalts,felsic volcanic rocks and...The Neoarchean Bundelkhand greenstone sequences at Mauranipur and Babina areas within the Bundelkhand Gneissic Complex preserve a variety of magmatic rocks such as komatiitic basalts, basalts,felsic volcanic rocks and high-Mg andesites belonging to the Baragaon, Raspahari and Koti Formations.The intrusive and extrusive komatiitic basalts are characterized by low SiO_2(39-53 wt.%), high MgO(18-25 wt.%).moderately high Fe_2O_3(7.1-11.6 wt.%), Al_2O_3(4.5-12.0 wt.%), and TiO_2(0.4-1.23 wt.%)with super to subchondritic(Gd/Yb)N ratios indicating garnet control on the melts. The intrusive komatiitic suite of Ti-enriched and Al-depleted type possesses predominant negative Eu and positive Nb, Ti and Y anomalies. The chemical composition of basalts classifies them into three types with varying SiO_2, TiO_2, MgO, Fe_2O_3, Al_2O_3 and CaO. At similar SiO_2 content of type Ⅰ and Ⅲ basalts, the type II basalts show slightly high Al_2O_3 and Fe_2O_3 contents. Significant negative anomalies of Nb, Zr, Hf and Ti, slightly enriched LREE with relatively flat HREE and low ∑REE contents are observed in type Ⅰ and Ⅱ basalts. TypeⅢ basalts show high Zr/Nb ratios(9.8-10.4), TiO_2(1.97-2.04 wt.%), but possess strikingly flat Zr, Hf, Y and Yb and are uncontaminated. Andesites from Agar and Koti have high SiO_2(55-64 wt.%), moderate TiO_2(0.4-0.7 wt.%), slightly low Al_2O_3(7-11.9 wt.%), medium to high MgO(3-8 wt.%) and CaO contents(10-17 wt.%). Anomalously high Cr, Co and Ni contents are observed in the Koti rhyolites. Tholeiitic to calc alkaline affinity of mafic-felsic volcanic rocks and basalt-andesite dacite-rhyolite differentiation indicate a mature arc and thickened crust during the advanced stage of the evolution of Neoarchean Bundelkhand greenstone belt in a convergent tectonic setting where the melts were derived from partial melting of thick basaltic crust metamorphosed to amphibolite-eclogite facies. The trace element systematics suggest the presence of arc-back arc association with varying magnitudes of crust-mantle interaction. La/Sm, La/Ta,Nb/Th, high MgO contents(>20 wt.%), CaO/Al_2O_3 and(Gd/Yb)_N > 1 along with the positive Nb anomalies of the komatiite basalts reflect a mantle plume source for their origin contaminated by subductionmetasomatized mantle lithosphere. The overall geochemical signatures of the ultramafic-mafic and felsic volcanic rocks endorse the Neoarchean plume-arc accretion tectonics in the Bundelkhand greenstone belt.展开更多
Magmatic pulses in intraplate sedimentary basins are windows to understand the tectonomagmatic evolution and paleaoposition of the Basin.The present study reports the U-Pb zircon ages of mafic flows from the Cuddapah ...Magmatic pulses in intraplate sedimentary basins are windows to understand the tectonomagmatic evolution and paleaoposition of the Basin.The present study reports the U-Pb zircon ages of mafic flows from the Cuddapah Basin and link these magmatic events with the Pangean evolution during late Carboniferous-Triassic/Phanerozoic timeframe.Zircon U-Pb geochronology for the basaltic lava flows from Vempalle Formation,Cuddapah Basin suggests two distinct Phanerozoic magmatic events coinciding with the amalgamation and dispersal stages of Pangea at 300 Ma(Late Carboniferous)and 227 Ma(Triassic).Further,these flows are characterized by analogous geochemical and geochronological signatures with Phanerozoic counterparts from Siberian,Panjal Traps,Emeishan and Tarim LIPs possibly suggesting their coeval and cogenetic nature.During the Phanerozoic Eon,the Indian subcontinent including the Cuddapah Basin was juxtaposed with the Pangean LIPs which led to the emplacement of these pulses of magmatism in the Basin coinciding with the assemblage of Pangea and its subsequent breakup between 400 Ma and 200 Ma.展开更多
Cratonic stabilization was a critical crustal process during the Hadean to Archean for the formation of cratons.The understanding of how and where this process took place is significant to evaluate the architecture of...Cratonic stabilization was a critical crustal process during the Hadean to Archean for the formation of cratons.The understanding of how and where this process took place is significant to evaluate the architecture of continents.The Singhbhum Craton of eastern India has well preserved Precambrian volcanosedimentary sequences.The Simlipal volcano-sedimentary complex of Singhbhum Craton consists of circular bands of mafic volcanic rocks interlayered with quartzites/shales/phyllites.In the present study,we report petrographic and geochemical characteristics of quartzites from Simlipal Complex coupled with U–Pb ages of detrital zircons and zircon geochemistry to understand the provenance and depositional conditions and its connection with the crustal stabilization in the Singhbhum Craton.The quartzites are texturally mature with sub-angular to sub-rounded quartz grains followed by feldspars embedded in a silty matrix.Based on modal compositions and major element ratios,these quartzites are categorized as quartz arenite and sub-lithic arenites.Trace element abundances normalized to Archean Upper Continental Crust(AUCC)display positive anomalies at U,Zr,Hf and negative anomalies at Nb.REE patterns are characterized by negative Eu anomalies(Eu/Eu^(*)=0.47–0.97)and flat HREE suggesting felsic provenance.These quartzites show depletion of LILE,enrichment of HFSE and transition metals relative to AUCC.High weathering indices such as CIA,PIA,and ICV are suggestive of moderate to intense chemical weathering.Low trace element ratios such as Th/Cr,Th/Sc,La/Sc,La/Co and Th/Co indicate a predominantly felsic source for these rocks.The overall geochemical signatures indicate passive margin deposition for these quartzites.Detrital zircons from the Simlipal quartzites yield U–Pb ages 3156±31 Ma suggesting Mesoarchean crustal heritage.The trace element geochemistry of detrital zircons suggests that the zircons are magmatic in origin and possibly derived from the 3.1 Ga anorogenic granite/granitoid provenance of Singhbhum Craton.These observations collectively indicate the Mayurbhanj Granite and Singhbhum Granite(SBG-III)provenance for these quartzites,thereby tracking the stabilization of the eastern Indian Shield/Singhbhum Craton back to Mesoarchean.展开更多
文摘Opencast coal mining produces trash of soil and rock containing various minerals,that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drainage(AMD)through oxidation pyrite minerals.The current study entailed assessing the potential production of AMD from an opencast coal mining region in Northeast part of India.In order to have a comprehensive overview of the AMD problem in Makum coalfield,the physico-chemical,geochemical,and petrological characteristics of the coal and overburden(OB)samples collected from the Makum coalfield(Northeast India)were thoroughly investigated.The maceral compositions reveal that coal features all three groups of macerals(liptinite,vitrinite,and inertinite),with a high concentration of liptinite indicating the coal of perhydrous,thereby rendering it more reactive.Pyrite(FeS_(2))oxidation kinetics were studied by conducting the aqueous leaching experiments of coal and(OB)samples to interpret the chemical weathering under controlled laboratory conditions of various temperature and time periods,and to replicate the actual mine site leaching.Inductively coupled plasma-optical emission spectroscopy(ICP-OES)was operated to detect the disposal of some precarious elements from coal and OB samples to the leachates during our controlled leaching experiment.The Rare earth element(REE)enrichment in the samples shows the anthropogenic incorporation of the REE in the coal and OB.These experiments reveal the change in conductivity,acid producing tendency,total dissolved solid(TDS),total Iron(Fe)and dissolved Sulfate(SO_(4)^(2−))ions on progress of the leaching experiments.Moreover,the discharge of FeS_(2) via atmospheric oxidation in laboratory condition undergoes a significant growth with the rise of temperature of the reaction systems in the environment and follows pseudo first order kinetics.A bio-remediative strategies is also reported in this paper to mitigate AMD water by employing size-segregated powdered limestone and water hyacinth plant in an indigenously developed site-specific prototype station.Apart from neutralisation of AMD water,this eco-friendly AMD remediation strategy demonstrates a reduction in PHEs concentrations in the treated AMD water.
基金funds MLP 6406-28(MRM)of CSIR-NGRIGH acknowledges DSTINSPIRE for PhD Fellowship(No.DST/INSPIRE/03/2021/001295)+1 种基金CM acknowledges the CSIR Emeritus Project funds。
文摘Meso-Neoarchean fuchsite quartzites are present in different stratigraphic positions of Dharwar Craton including the oldest(~3.3 Ga)Sargur Group of western Dharwar Craton.The present study deals with the petro-graphic and geochemical characteristics of the fuchsite quartzites from the Ghattihosahalli belt to evaluate their genesis,depositional setting and the enigma involved in the ancient sedimentation history.Their major mineral assemblages include quartz,fuchsite,and feldspars along with accessory kyanite and rutile.The geochemical com-positions are characterized by high SiO_(2),Al_(2)O_(3),low MgO,CaO,strongly enriched Cr(1326–6899 ppm),Ba(1165–3653 ppm),Sr(46–210 ppm),V(107–868 ppm)and Zn(11–158 ppm)contents compared to the upper continental crust(UCC).The UCC normalized rare earth element(REE)patterns are characterized by depleted light REE[(La/Sm)UCC=0.33–0.95]compared to heavy REE[(Gd/Yb)_(UCC)=0.42–1.65]with conspicuous positive Eu-anomalies(Eu/Eu^(*)=1.35–18.27)characteristic of hydrothermal solutions evidenced through the interlayered barites.The overall major and trace element systematics reflect a combined mafic-felsic provenance and suggest their deposition at a passive continental margin environ-ment.The comprehensivefield,petrographic,and geo-chemical studies indicate that these quartzites are infiltrated by Cr-richfluids released during high-grade metamorphism of associated ultramafic rocks.The Sargur and the subse-quent Dharwar orogeny amalgamated diverse lithounits from different tectonic settings,possibly leading to the release of Cr-richfluids and the formation of fuchsite quartzite during or after the orogeny.Thesefindings sug-gest a pre-existing stable crust prior to the Sargur Group and the link between orogenic events and various mineral deposits in the Dharwar Craton.
基金the funds from Council of Scientific and Industrial Research(CSIR)to National Geophysical Research Institute through the project of MLP 6604-28(CM)Ministry of Earth Sciences(No:MoES/PO(Geosci)/8/2014)
文摘This study reports major, trace, rare earth and platinum group element compositions of lava flows from the Vempalle Formation of Cuddapah Basin through an integrated petrological and geochemical approach to address mantle conditions, magma generation processes and tectonic regimes involved in their formation. Six flows have been identified on the basis of morphological features and systematic three-tier arrangement of vesicular-entablature-colonnade zones. Petrographically, the studied flows are porphyritic basalts with plagioclase and clinopyroxene representing dominant phenocrystal phases.Major and trace element characteristics reflect moderate magmatic differentiation and fractional crystallization of tholeiitic magmas. Chondrite-normalized REE patterns corroborate pronounced LREE/HREE fractionation with LREE enrichment over MREE and HREE. Primitive mantle normalized trace element abundances are marked by LILE-LREE enrichment with relative HFSE depletion collectively conforming to intraplate magmatism with contributions from sub-continental lithospheric mantle(SCLM) and extensive melt-crust interaction. PGE compositions of Vempalle lavas attest to early sulphur-saturated nature of magmas with pronounced sulphide fractionation, while PPGE enrichment over IPGE and higher Pd/Ir ratios accord to the role of a metasomatized lithospheric mantle in the genesis of the lava flows. HFSEREE-PGE systematics invoke heterogeneous mantle sources comprising depleted asthenospheric MORB type components combined with plume type melts. HFSE-REE variations account for polybaric melting at variable depths ranging from garnet to spinel lherzolite compositional domains of mantle. Intraplate tectonic setting for the Vempalle flows with P-MORB affinity is further substantiated by(i) their origin from a rising mantle plume trapping depleted asthenospheric MORB mantle during ascent,(ii) interaction between plume-derived melts and SCLM,(iii) their rift-controlled intrabasinal emplacement through Archeane Proterozoic cratonic blocks in a subduction-unrelated ocean-continent transition zone(OCTZ). The present study is significant in light of the evolution of Cuddapah basin in the global tectonic framework in terms of its association with Antarctica, plume incubation, lithospheric melting and thinning, asthenospheric infiltration collectively affecting the rifted margin of eastern Dharwar Craton and serving as precursors to supercontinent disintegration.
基金funds provided from Council of Scientific and Industrial Research (CSIR) to National Geophysical Research Institute,Hyderabad through the projects of Ministry of Earth Sciences (No:MoES/PO(Geosci)/8/ 2014) and MLP 6406-28 (CM)
文摘Oldest rocks are sparsely distributed within the Dharwar Craton and little is known about their involvement in the sedimentary sequences which are present in the Archean greenstone successions and the Proterozoic Cuddapah basin.Stromatolitic carbonates are well preserved in the Neoarchean greenstone belts of Dharwar Craton and Cuddapah Basin of Peninsular India displaying varied morphological and geochemical characteristics.In this study,we report results from U-Pb geochronology and trace element composition of the detrital zircons from stromatolitic carbonates present within the Dharwar Craton and Cuddapah basin to understand the provenance and time of accretion and deposition.The UPb ages of the detrital zircons from the Bhimasamudra and Marikanve stromatolites of the Chitradurga greenstone belt of Dharwar Craton display ages of 3426±26 Ma to 2650±38 Ma whereas the Sandur stromatolites gave an age of 3508±29 Ma to 2926±36 Ma suggesting Paleo-to Neoarchean provenance.The U-Pb detrital zircons of the Tadpatri stromatolites gave an age of 2761±31 Ma to1672±38 Ma suggesting Neoarchean to Mesoproterozoic provenance.The Rare Earth Element(REE)patterns of the studied detrital zircons from Archean Dharwar Craton and Proterozoic Cuddapah basin display depletion in light rare earth elements(LREE)and enrichment in heavy rare earth elements(HREE)with pronounced positive Ce and negative Eu anomalies,typical of magmatic zircons.The trace element composition and their relationship collectively indicate a mixed granitoid and mafic source for both the Dharwar and Cuddapah stromatolites.The 3508±29 Ma age of the detrital zircons support the existence of 3.5 Ga crust in the Western Dharwar Craton.The overall detrital zircon ages(3.5-2.7 Ga)obtained from the stromatolitic carbonates of Archean greenstone belts and Proterozoic Cuddapah basin(2.7-1.6 Ga)collectively reflect on^800-900 Ma duration for the Precambrian stromatolite deposition in the Dharwar Craton.
基金the funds from Council of Scientific and Industrial Research (CSIR)Ministry of Earth Sciences, Government of India for the financial support(MoES/P.O.(Geosci)/4/2013)
文摘The Neoarchean Bundelkhand greenstone sequences at Mauranipur and Babina areas within the Bundelkhand Gneissic Complex preserve a variety of magmatic rocks such as komatiitic basalts, basalts,felsic volcanic rocks and high-Mg andesites belonging to the Baragaon, Raspahari and Koti Formations.The intrusive and extrusive komatiitic basalts are characterized by low SiO_2(39-53 wt.%), high MgO(18-25 wt.%).moderately high Fe_2O_3(7.1-11.6 wt.%), Al_2O_3(4.5-12.0 wt.%), and TiO_2(0.4-1.23 wt.%)with super to subchondritic(Gd/Yb)N ratios indicating garnet control on the melts. The intrusive komatiitic suite of Ti-enriched and Al-depleted type possesses predominant negative Eu and positive Nb, Ti and Y anomalies. The chemical composition of basalts classifies them into three types with varying SiO_2, TiO_2, MgO, Fe_2O_3, Al_2O_3 and CaO. At similar SiO_2 content of type Ⅰ and Ⅲ basalts, the type II basalts show slightly high Al_2O_3 and Fe_2O_3 contents. Significant negative anomalies of Nb, Zr, Hf and Ti, slightly enriched LREE with relatively flat HREE and low ∑REE contents are observed in type Ⅰ and Ⅱ basalts. TypeⅢ basalts show high Zr/Nb ratios(9.8-10.4), TiO_2(1.97-2.04 wt.%), but possess strikingly flat Zr, Hf, Y and Yb and are uncontaminated. Andesites from Agar and Koti have high SiO_2(55-64 wt.%), moderate TiO_2(0.4-0.7 wt.%), slightly low Al_2O_3(7-11.9 wt.%), medium to high MgO(3-8 wt.%) and CaO contents(10-17 wt.%). Anomalously high Cr, Co and Ni contents are observed in the Koti rhyolites. Tholeiitic to calc alkaline affinity of mafic-felsic volcanic rocks and basalt-andesite dacite-rhyolite differentiation indicate a mature arc and thickened crust during the advanced stage of the evolution of Neoarchean Bundelkhand greenstone belt in a convergent tectonic setting where the melts were derived from partial melting of thick basaltic crust metamorphosed to amphibolite-eclogite facies. The trace element systematics suggest the presence of arc-back arc association with varying magnitudes of crust-mantle interaction. La/Sm, La/Ta,Nb/Th, high MgO contents(>20 wt.%), CaO/Al_2O_3 and(Gd/Yb)_N > 1 along with the positive Nb anomalies of the komatiite basalts reflect a mantle plume source for their origin contaminated by subductionmetasomatized mantle lithosphere. The overall geochemical signatures of the ultramafic-mafic and felsic volcanic rocks endorse the Neoarchean plume-arc accretion tectonics in the Bundelkhand greenstone belt.
基金the funds from Ministry of Earth Sciences(No:MoES/PO(Geosci)/8/2014)to NGRI and MLP 6406-28(CM)INSPIRE Faculty Project [IFA14-EAS-25] funded by DST,New Delhi
文摘Magmatic pulses in intraplate sedimentary basins are windows to understand the tectonomagmatic evolution and paleaoposition of the Basin.The present study reports the U-Pb zircon ages of mafic flows from the Cuddapah Basin and link these magmatic events with the Pangean evolution during late Carboniferous-Triassic/Phanerozoic timeframe.Zircon U-Pb geochronology for the basaltic lava flows from Vempalle Formation,Cuddapah Basin suggests two distinct Phanerozoic magmatic events coinciding with the amalgamation and dispersal stages of Pangea at 300 Ma(Late Carboniferous)and 227 Ma(Triassic).Further,these flows are characterized by analogous geochemical and geochronological signatures with Phanerozoic counterparts from Siberian,Panjal Traps,Emeishan and Tarim LIPs possibly suggesting their coeval and cogenetic nature.During the Phanerozoic Eon,the Indian subcontinent including the Cuddapah Basin was juxtaposed with the Pangean LIPs which led to the emplacement of these pulses of magmatism in the Basin coinciding with the assemblage of Pangea and its subsequent breakup between 400 Ma and 200 Ma.
基金the funds provided from Council of Scientific and Industrial Research(CSIR)to National Geophysical Research Institute,Hyderabad through the projects MLP-0002-28-FBR-2(Geo Met)and Emeritus scientist。
文摘Cratonic stabilization was a critical crustal process during the Hadean to Archean for the formation of cratons.The understanding of how and where this process took place is significant to evaluate the architecture of continents.The Singhbhum Craton of eastern India has well preserved Precambrian volcanosedimentary sequences.The Simlipal volcano-sedimentary complex of Singhbhum Craton consists of circular bands of mafic volcanic rocks interlayered with quartzites/shales/phyllites.In the present study,we report petrographic and geochemical characteristics of quartzites from Simlipal Complex coupled with U–Pb ages of detrital zircons and zircon geochemistry to understand the provenance and depositional conditions and its connection with the crustal stabilization in the Singhbhum Craton.The quartzites are texturally mature with sub-angular to sub-rounded quartz grains followed by feldspars embedded in a silty matrix.Based on modal compositions and major element ratios,these quartzites are categorized as quartz arenite and sub-lithic arenites.Trace element abundances normalized to Archean Upper Continental Crust(AUCC)display positive anomalies at U,Zr,Hf and negative anomalies at Nb.REE patterns are characterized by negative Eu anomalies(Eu/Eu^(*)=0.47–0.97)and flat HREE suggesting felsic provenance.These quartzites show depletion of LILE,enrichment of HFSE and transition metals relative to AUCC.High weathering indices such as CIA,PIA,and ICV are suggestive of moderate to intense chemical weathering.Low trace element ratios such as Th/Cr,Th/Sc,La/Sc,La/Co and Th/Co indicate a predominantly felsic source for these rocks.The overall geochemical signatures indicate passive margin deposition for these quartzites.Detrital zircons from the Simlipal quartzites yield U–Pb ages 3156±31 Ma suggesting Mesoarchean crustal heritage.The trace element geochemistry of detrital zircons suggests that the zircons are magmatic in origin and possibly derived from the 3.1 Ga anorogenic granite/granitoid provenance of Singhbhum Craton.These observations collectively indicate the Mayurbhanj Granite and Singhbhum Granite(SBG-III)provenance for these quartzites,thereby tracking the stabilization of the eastern Indian Shield/Singhbhum Craton back to Mesoarchean.
