Parking in a small parking lot within limited space poses a difficult task. It often leads to deviations between the final parking posture and the target posture. These deviations can lead to partial occupancy of adja...Parking in a small parking lot within limited space poses a difficult task. It often leads to deviations between the final parking posture and the target posture. These deviations can lead to partial occupancy of adjacent parking lots, which poses a safety threat to vehicles parked in these parking lots. However, previous studies have not addressed this issue. In this paper, we aim to evaluate the impact of parking deviation of existing vehicles next to the target parking lot(PDEVNTPL) on the automatic ego vehicle(AEV) parking, in terms of safety, comfort, accuracy, and efficiency of parking. A segmented parking training framework(SPTF) based on soft actor-critic(SAC) is proposed to improve parking performance. In the proposed method, the SAC algorithm incorporates strategy entropy into the objective function, to enable the AEV to learn parking strategies based on a more comprehensive understanding of the environment. Additionally, the SPTF simplifies complex parking tasks to maintain the high performance of deep reinforcement learning(DRL). The experimental results reveal that the PDEVNTPL has a detrimental influence on the AEV parking in terms of safety, accuracy, and comfort, leading to reductions of more than 27%, 54%, and 26%respectively. However, the SAC-based SPTF effectively mitigates this impact, resulting in a considerable increase in the parking success rate from 71% to 93%. Furthermore, the heading angle deviation is significantly reduced from 2.25 degrees to 0.43degrees.展开更多
At present,metal-organic framework(MOF)-derived nano-micro architectures are actively explored for electromagnetic(EM)wave absorption owing to their flexible composition and structural manipulation that enhance dielec...At present,metal-organic framework(MOF)-derived nano-micro architectures are actively explored for electromagnetic(EM)wave absorption owing to their flexible composition and structural manipulation that enhance dielectric and magnetic attenuations.However,the basic design principles in MOF-derived microwave absorption materials have not been summarized.This review is devoted to analyzing design principles in MOF-derived microwave absorption materials from the following perspectives:diverse monomers(ligands and ions of MOFs),topologies,chemical states,and physical properties.The derived essential information regarding the EM wave absorption mechanism and the structural-functional dependency is also comprehensively summarized.Finally,a clear insight into the challenges and perspectives of the industrial revolution upgrading in this promising field is proposed.展开更多
As the need for high-energy–density batteries continues to grow, lithium-sulfur(Li–S) batteries have become a highly promising next-generation energy solution due to their low cost and exceptional energy density com...As the need for high-energy–density batteries continues to grow, lithium-sulfur(Li–S) batteries have become a highly promising next-generation energy solution due to their low cost and exceptional energy density compared to commercially available Li-ion batteries. Research into carbon-based sulfur hosts for Li–S batteries has been ongoing for over two decades, leading to a significant number of publications and patents.However, the commercialization of Li–S batteries has yet to be realized. This can be attributed, in part, to the instability of the Li metal anode. However, even when considering just the cathode side, there is still no consensus on whether carbon-based hosts will prove to be the best sulfur hosts for the industrialization of Li–S batteries. Recently, there has been controversy surrounding the use of carbon-based materials as the ideal sulfur hosts for practical applications of Li–S batteries under high sulfur loading and lean electrolyte conditions. To address this question, it is important to review the results of research into carbon-based hosts, assess their strengths and weaknesses, and provide a clear perspective. This review systematically evaluates the merits and mechanisms of various strategies for developing carbon-based host materials for high sulfur loading and lean electrolyte conditions. The review covers structural design and functional optimization strategies in detail, providing a comprehensive understanding of the development of sulfur hosts. The review also describes the use of efficient machine learning methods for investigating Li–S batteries. Finally, the outlook section lists and discusses current trends, challenges, and uncertainties surrounding carbon-based hosts, and concludes by presenting our standpoint and perspective on the subject.展开更多
Background:Chronic ankle instability(CAI) is a common sequela following an acute lateral ankle sprain(LAS).To treat an acture LAS more effectively and efficiently,it is important to identify patients at substantial ri...Background:Chronic ankle instability(CAI) is a common sequela following an acute lateral ankle sprain(LAS).To treat an acture LAS more effectively and efficiently,it is important to identify patients at substantial risk for developing CAI.This study identifies magnetic resonance imaging(MRI) manifestations for predicting CAI development after a first episode of LAS and explores appropriate clinical indications for ordering MRI scans for these patients.Methods:All patients with a first-episode LAS who received plain radiograph and MRI scanning within the first 2 weeks after LAS from December 1,2017 to December 1,2019 were identified.Data were collected using the Cumberland Ankle Instability Tool at final follow-up.Demographic and other related clinical variables,including age,sex,body mass index,and treatment were also recorded.Univariable and multivariable analyses were performed successively to identify risk factors for CAI after first-episode LAS.Results:A total 131 out of 362 patients with a mean follow-up of 3.0± 0.6 years(mean ± SD;2.0—4.1 years) developed CAI after first-episode LAS.According to multivariable regression,development of CAI after first-episode LAS was associated with 5 prognostic factors:age(odds ratio(OR)=0.96,95% confidence interval(95%CI):0.93-1.00,p=0.032);body mass index(OR=1.09,95%CI:1.02-1.17,p=0.009);posterior talofibular ligament injury(OR=2.17,95%CI:1.05-4.48,p=0.035);large bone marrow lesion of the talus(OR=2.69,95%CI:1.30-5.58,p=0.008),and Grade 2 effusion of the tibiotalar joint(OR=2.61,95%CI:1.39-4.89,p=0.003).When patients had at least 1 positive clinical finding in the 10-m walk test,anterior drawer test,or inversion tilt test,they had a 90.2% sensitivity and 77.4% specificity in terms of detecting at least 1 prognostic factor by MRI.Conclusion:MRI scanning is valuable in predicting CAI after first-episode LAS for those patients with at least 1 positive clinical finding in the10-m walk test,anterior drawer test,and inversion tilt test.Further prospective and large-scale studies are necessary for validation.展开更多
Research has indicated that introducing Aralia elata into larch plantations forms an agroforestry system which could provide economic benefi ts for local farmers and improve degraded soils.However,the impact of litter...Research has indicated that introducing Aralia elata into larch plantations forms an agroforestry system which could provide economic benefi ts for local farmers and improve degraded soils.However,the impact of litter mixtures on soil chemical and microbial properties in this agroforestry system are unclear,which limits effi cient management of the agroforestry system.A 365-d incubation experiment examined the eff ect of litter mixtures of diff erent proportions of larch(L)and A.elata(A)on soil chemical and microbial properties.The results show that levels of mineral N,available P,microbial biomass carbon and nitrogen,cumulative C mineralization,and activities of hydrolases and oxidases increased with an increase of A.elata in the litter mixtures.Concentration of total soil carbon,nitrogen,and phosphorous did not change(except for total nitrogen).Compared with larch litter alone,levels of mineral N,available P,microbial biomass carbon and nitrogen,cumulative C mineralization,and the activities of hydrolases and oxidases increased by 7.6–433.5%.Most chemical and microbial properties were positively correlated with mixed litter proportions and the initial levels of N,P,K,Ca,Mg,Mn,Zn and Cu in the litter,while negatively correlated with the initial concentrations of C,Fe and lignin,C/N and lignin/N ratios.The results indicate that A.elata litter can improve degraded larch soil and the degree depends on the proportion of A.elata litter in the litter mixtures.展开更多
Garnet-structured ceramic electrolyte Li_(6.75)La_(3)Zr_(1.75)Ta_(0.25)O_(12)(LLZTO)attracts significant consideration in solid-state Li metal batteries due to its wide electrochemical window and favorable compatibili...Garnet-structured ceramic electrolyte Li_(6.75)La_(3)Zr_(1.75)Ta_(0.25)O_(12)(LLZTO)attracts significant consideration in solid-state Li metal batteries due to its wide electrochemical window and favorable compatibility with Li metal.However,the deployment of LLZTO is severely hampered by poor contact between LLZTO and Li metal anode.In this paper,an ultra-thin Al-Si interface buffer layer(10 nm)is constructed on LLZTO by a magnetron sputtering method,which allows superior wetting of Li onto the LLZTO surface due to the alloying reaction between the Al-Si layer and Li metal.The resulting Li/Al-Si coated LLZTO(ASL)/Li symmetrical cell delivers an interfacial resistance of 15.0Ωcm^(-2),which is much lower than that of 1140.3Ωcm^(-2)for the bare LLZTO symmetrical cell.Moreover,the Li/ASL/Li symmetrical cells exhibit stable plating/striping performance(800 h)with small voltage hysteresis at 1.0 mA cm^(-2).Besides,the full cell with LiFePO_(4)cathode reveals a high capacity of 124.1 mA h g^(-1)after 600 cycles at 0.5C with a lowcapacity decay of 0.032%per cycle.We believe this work will facilitate the development of solid-state rechargeable batteries.展开更多
Molybdenum trioxide(MoO_(3))has recently attracted wide attention as a typical conversion-type anode of Li-ion batteries(LIBs).Nevertheless,the inferior intrinsic conductivity and rapid capacity fading during charge/d...Molybdenum trioxide(MoO_(3))has recently attracted wide attention as a typical conversion-type anode of Li-ion batteries(LIBs).Nevertheless,the inferior intrinsic conductivity and rapid capacity fading during charge/discharge process seriously limit large-scale commercial application of MoO_(3).Herein,the density function theory(DFT)calculations show that electron-proton co-doping preferentially bonds symmetric oxygen to form unstable HxMoO_(3).When the-OH-group in HxMoO_(3) is released into the solution in the form of H_(2)O,it is going to form MoO_(3-x)with lower binding energy.By the means of both electron-proton co-doping and high-energy nanosizing,oxygen vacancies and nanoflower structure are introduced into MoO_(3) to accelerate the ion and electronic diffusion/transport kinetics.Benefitting from the promotion of ion diffusion kinetics related to nanostructures,as well as both the augmentation of active sites and the improvement of electrical conductivity induced by oxygen vacancies,the MoO_(3-x)/nanoflower structures show excellent lithium-ion storage performance.The prepared specimen has a high lithium-ion storage capacity of 1261 mA h g^(-1)at 0.1 A g^(-1)and cyclic stability(450 cycle),remarkably higher than those of previously reported MoO_(3)-based anode materials.展开更多
Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as ra...Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as rapid tool wear,high specific cutting force,and poor surface integrity.Instead,a promising method for solving these problems is laser-induced oxidation-assisted milling(LOAM):under laser irradiation,the local workpiece material reacts with oxygen,thus forming loose and porous oxides that are easily removed.In the present work,the oxidation mechanism of SiCp/Al irradiated by a nanosecond pulsed laser is studied to better understand the laser-induced oxidation behavior and control the characteristics of the oxides,with laser irradiation experiments performed on a 65%SiCp/Al composite with various laser parameters and auxiliary gases(oxygen,nitrogen,and argon).With increasing laser pulse energy density,both the ablated groove depth and the width of the heat-affected zone increase.When oxygen is used as the auxiliary gas,an oxide layer composed of SiO_(2)and Al2O3 forms,and CO_(2)is produced and escapes from the material,thereby forming pores in the oxides.However,when nitrogen or argon is used as the auxiliary gas,a recast layer is produced that is relatively difficult to remove.Under laser irradiation,the sputtered material reacts with oxygen to form oxides on both sides of the ablated groove,and as the laser scanning path advances,the produced oxides accumulate to form an oxide layer.LOAM and conventional milling are compared using the same milling parameters,and LOAM is found to be better for reduced milling force and tool wear and improved machined surface quality.展开更多
Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency,high production,environmental friendliness,and low cost.The uniform distribution of gra...Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency,high production,environmental friendliness,and low cost.The uniform distribution of grains can effectively inhibit the aggregation of active materials,improving lithium storage performance.In this work,natural graphite is modified by polyvinylpyrrolidone to obtain modified graphite with reduced size and better dispersion.Natural pyrite composite polyvinylpyrrolidone-modified graphite(pyrite/PG)material with uniform particle distribution is obtained by the ball milling process.The subsequent calcination process converts pyrite/PG into Fe_(1-x)Scompounded with polyvinylpyrrolidone-modified graphite(Fe_(1-x)S/PG).The homogeneous grain distributions of active material can facilitate the faster transfer of electrons and promote the efficient utilization of active materials.The as-prepared Fe_(1-x)S/PG electrode exhibits a remarkably reversible specific capacity of 613.0 mAh·g^(-1)at 0.2 A·g^(-1)after 80 cycles and an excellent rate capability of 523.0 mAh·g^(-1)at 5 A·g^(-1).Even at a higher current density of 10 A·g^(-1),it can deliver a specific capacity of 348.0 mAh·g^(-1).Moreover,the dominant pseudocapacitance in redox reactions accounts for the impressive rate and cycling stability.This work provides a low-cost and facile method to fabricate natural mineral-based anode materials and apprise readers about the impact of uniform particle distribution on lithium storage performance.展开更多
Traditional inspection methods cannot quickly and accurately monitor tree barriers and safeguard the transmission lines.To solve these problems,in this study,we proposed a rapid canopy height information extraction me...Traditional inspection methods cannot quickly and accurately monitor tree barriers and safeguard the transmission lines.To solve these problems,in this study,we proposed a rapid canopy height information extraction method using optical remote sensing and LiDAR,and used UAV optical imagery with LiDAR to monitor the height of trees in a university and a high-voltage transmission line corridor in the Ningxia region.The results showed that the relative error of tree height extraction using UAV optical images was less than 5%,and the lowest relative error was 0.11%.The determination coefficient R^(2) between the optical image tree height extraction results and the measured tree height was 0.97,thus indicating a high correlation for both.In the field of tree barrier monitoring,the determination coefficient R^(2) of tree height extracted using airborne LiDAR point cloud,and canopy height model(CHM)and of the measured tree height were 0.947 and 0.931,respectively.The maximum and minimum relative error in tree height extraction performed using point cloud was 2.91%and 0.2%,respectively,with an extraction accuracy of over 95%.The experimental results demonstrated that it is feasible to use UAV optical remote sensing and LiDAR in monitoring tree barriers and tree height information extraction quickly and accurately,which is of great significance for the risk assessment and early warning of tree barriers in transmission-line corridors.展开更多
Commercialization of Zn-metal anodes with low cost and high theoretical capacity is hindered by the poor reversibility caused by dendrites growth,side reactions,and the slow Zn^(2+)-transport and reaction kinetics.Her...Commercialization of Zn-metal anodes with low cost and high theoretical capacity is hindered by the poor reversibility caused by dendrites growth,side reactions,and the slow Zn^(2+)-transport and reaction kinetics.Herein,a reversible heterogeneous electrode of Zn-nanocrystallites/polyvinylphosphonic acrylamide(Zn/PPAm)with fast electrochemical kinetics is designed for the first time:phosphonic acid groups with strong polarity and chelation effect ensure structural reversibility and stability of the threedimensional Zn-storage-host PPAm network and the Zn/PPAm hybrid;hydrophobic carbon chains suppress side reactions such as hydrogen evolution and corrosion;weak electron-donating amide groups constitute Zn^(2+)-transport channels and promote“desolvation”and“solvation”effects of Zn^(2+)by dragging the PPAm network on the Zn-metal surface to compress/stretch during Zn plating/stripping,respectively;and the heterostructure and Zn nanocrystallites suppress dendrite growth and enhance electrochemical reactivity,respectively.Thus,the Zn/PPAm electrode shows cycle reversibility of over 6000 h with a hysteresis voltage as low as 31 mV in symmetrical cells and excellent durability and flexibility in fiber-shaped batteries.展开更多
Nitrogen-doped carbon-coated transition-metal sulfides(TMS@NCs)have been considered as efficient anodes for sodium-ion batteries.However,the uncontrollable morphology and weak core-shell binding forces significantly l...Nitrogen-doped carbon-coated transition-metal sulfides(TMS@NCs)have been considered as efficient anodes for sodium-ion batteries.However,the uncontrollable morphology and weak core-shell binding forces significantly limit the sodium storage performance and life.Herein,based on the reversible ring-opening reaction of the epoxy group of the tertiary amino group-rich epoxide cationic polyacrylamide(ECP)at the beginning of hydrothermal process(acidic environment)and the irreversible ring-opening(cross-linking reactions)at the late hydrothermal period(alkaline environment),47 nm-sized ZnS@NCs were prepared via a one-pot hydrothermal process.During this process,the covalent bonds formed between the ZnS core and elastic carbon shell significantly improved the mechanical and chemical stabilities of ZnS@NC.Benefiting from the nanosize,fast ion/electron transfer,and high stability,ZnS@NC exhibited a high reversible capacity of 421.9 mAh g^(−1) at a current density of 0.1 A g^(−1) after 1000 cycles and a superior rate capability of 273.8 mAh g^(−1) at a current density of 5 A g^(−1).Moreover,via this universal synthesis strategy,a series of TMS@NCs,such as MoS_(2)@NC,NiS@NC,and CuS@NC were developed with excellent capacity and cyclability.展开更多
Receptor tyrosine kinase-like orphan receptor 2(ROR2)has a vital role in osteogenesis.However,the mechanism underlying the regulation of ROR2 in osteogenic differentiation is still poorly comprehended.A previous study...Receptor tyrosine kinase-like orphan receptor 2(ROR2)has a vital role in osteogenesis.However,the mechanism underlying the regulation of ROR2 in osteogenic differentiation is still poorly comprehended.A previous study by our research group showed that a novel compound heterozygous ROR2 variation accounted for the autosomal recessive Robinow syndrome(ARRS).This study attempted to explore the impact of the ROR2:c.904C>T variant specifically on the osteogenic differentiation of BMSCs.Methods:Coimmunoprecipitation(CoIP)-western blotting was carried out to identify the interaction between ROR2 and Wnt5a.Double-immunofluorescence staining was used for determining the expressions and co-localization of ROR2 and Wnt5a in bone marrow mesenchymal stem cells(BMSCs).Western blot(WB)analysis and quantitative reverse transcription polymerase chain reaction(RT-qPCR)were conducted to identify the expression levels of ROR2 in the BMSCs transfected with LV-shROR2 or LV-ROR2-c.904C>T.The alkaline phosphatase(ALP)activity was detected,and Alizarin Red S staining was done for evaluating the osteogenic differentiation of BMSCs.RT-qPCR was employed to identify the expression of the sphingomyelin synthase 1(SMS1)mRNA in the BMSCs transfected with LV-shROR2 or LV-ROR2-c.904C>T and the mRNA expression levels of Runt-related transcription factor 2(RUNX2),osteocalcin(OCN),and osteopontin(OPN).WB was performed to confirm the protein expressions of extracellular regulated protein kinases1(ERK),P-ERK,Smad family member1/5/8(Smad1/5/8),P-Smad1/5/8,P-P38,P38,RUNX2,OCN,and OPN in the BMSCs transfected with LV-shROR2/LV-ROR2-c.904C>T and sphingomyelin(SM).Results:The ROR2:c.904C>T mutant altered the subcellular localization of the ROR2 protein,which caused an impaired interaction between ROR2 and Wnt5a.The depletion of ROR2 restricted the osteogenic differentiation capability of BMSCs and downregulated the expression of SMS1.SM treatment could reverse the inhibition of osteoblastic differentiation in ROR2-depleted BMSCs.Conclusion:The findings of this work revealed that the ROR2:c.904C>T variant led to the loss of function of ROR2,which impaired the interaction between ROR2 and Wnt5a and also controlled the osteogenic differentiation capability of BMSCs.Furthermore,SM was revealed to be engaged in the osteoblastic differentiation of BMSCs regulated by ROR2,which renders SM a potential target in the therapy for ARRS.展开更多
Correction to:J.For.Res.https://doi.org/10.1007/s11676-022-01526-w The article“The amelioration of degraded larch(Larix olgensis)soil depends on the proportion of Aralia elata litter in larch-A.elata agroforestry sys...Correction to:J.For.Res.https://doi.org/10.1007/s11676-022-01526-w The article“The amelioration of degraded larch(Larix olgensis)soil depends on the proportion of Aralia elata litter in larch-A.elata agroforestry systems”,written by Pingzhen Gao·Jiaojun Zhu·Qiaoling Yan·Kai Yang and Jinxin Zhang was originally published Online First without Open Access.展开更多
BACKGROUND We report a rare case of full neurological recovery from severe nonexertional heat stroke in a 67-year-old woman with an initial Glasgow Coma Scale of 3.This report raises awareness among doctors that when ...BACKGROUND We report a rare case of full neurological recovery from severe nonexertional heat stroke in a 67-year-old woman with an initial Glasgow Coma Scale of 3.This report raises awareness among doctors that when heatstroke is diagnosed,comprehensive treatment should be implemented as soon as possible.Moreover,targeted temperature management,combination therapy with hemodialysis and hemoperfusion,and hyperbaric oxygen therapy may alleviate multiorgan failure and prevent neurological sequelae caused by heatstroke.CASE SUMMARY A previously healthy 67-year-old woman with an initial Glasgow Coma Scale of 3 was found lying prone on the road at noon on a summer day.Laboratory tests revealed multiorgan failure.As soon as heatstroke was diagnosed,comprehensive treatment was implemented.On hospital Day 3,the patient was extubated.Her initial Sequential Organ Failure Assessment score at hospitalization was 14 and decreased to 2 on hospital Day 4.On the seventh day following hospital admission,as the patient’s general condition improved,the levels of laboratory test findings decreased rapidly.Finally,the patient gradually recovered with no other neurological symptoms(the Glasgow Coma Scale at discharge was 15,and her ability to walk independently was restored).CONCLUSION This case demonstrated that targeted temperature management,combination therapy with hemodialysis and hemoperfusion,and hyperbaric oxygen therapy may alleviate multiorgan failure and prevent neurological sequelae caused by heatstroke.展开更多
With the rapid development of sports,the number of sports images has increased dramatically.Intelligent and automatic processing and analysis of moving images are significant,which can not only facilitate users to qui...With the rapid development of sports,the number of sports images has increased dramatically.Intelligent and automatic processing and analysis of moving images are significant,which can not only facilitate users to quickly search and access moving images but also facilitate staff to store and manage moving image data and contribute to the intellectual development of the sports industry.In this paper,a method of table tennis identification and positioning based on a convolutional neural network is proposed,which solves the problem that the identification and positioning method based on color features and contour features is not adaptable in various environments.At the same time,the learning methods and techniques of table tennis detection,positioning,and trajectory prediction are studied.A deep learning framework for recognition learning of rotating flying table tennis is put forward.The mechanism and methods of positioning,trajectory prediction,and intelligent automatic processing of moving images are studied,and the self-built data sets are trained and verified.展开更多
基金supported by National Natural Science Foundation of China(52222215, 52272420, 52072051)。
文摘Parking in a small parking lot within limited space poses a difficult task. It often leads to deviations between the final parking posture and the target posture. These deviations can lead to partial occupancy of adjacent parking lots, which poses a safety threat to vehicles parked in these parking lots. However, previous studies have not addressed this issue. In this paper, we aim to evaluate the impact of parking deviation of existing vehicles next to the target parking lot(PDEVNTPL) on the automatic ego vehicle(AEV) parking, in terms of safety, comfort, accuracy, and efficiency of parking. A segmented parking training framework(SPTF) based on soft actor-critic(SAC) is proposed to improve parking performance. In the proposed method, the SAC algorithm incorporates strategy entropy into the objective function, to enable the AEV to learn parking strategies based on a more comprehensive understanding of the environment. Additionally, the SPTF simplifies complex parking tasks to maintain the high performance of deep reinforcement learning(DRL). The experimental results reveal that the PDEVNTPL has a detrimental influence on the AEV parking in terms of safety, accuracy, and comfort, leading to reductions of more than 27%, 54%, and 26%respectively. However, the SAC-based SPTF effectively mitigates this impact, resulting in a considerable increase in the parking success rate from 71% to 93%. Furthermore, the heading angle deviation is significantly reduced from 2.25 degrees to 0.43degrees.
基金supported by the National Natural Science Foundation of China(Nos.51872238,21806129,and 52074227)Fundamental Research Funds for the Central Universities(Nos.3102018zy045 and3102019AX11)the Natural Science Basic Research Plan in Shaanxi Province of China(Nos.2020JM-118 and2017JQ5116)。
文摘At present,metal-organic framework(MOF)-derived nano-micro architectures are actively explored for electromagnetic(EM)wave absorption owing to their flexible composition and structural manipulation that enhance dielectric and magnetic attenuations.However,the basic design principles in MOF-derived microwave absorption materials have not been summarized.This review is devoted to analyzing design principles in MOF-derived microwave absorption materials from the following perspectives:diverse monomers(ligands and ions of MOFs),topologies,chemical states,and physical properties.The derived essential information regarding the EM wave absorption mechanism and the structural-functional dependency is also comprehensively summarized.Finally,a clear insight into the challenges and perspectives of the industrial revolution upgrading in this promising field is proposed.
基金support from EPSRC-New Investigator Award 2020 (EP/V002260/1)The Faraday Institute-Battery Study and Seed Research Project (FIRG052)+2 种基金The Royal Society-International Exchanges 2021 Cost Share (NSFC)(IECNSFC211074)the China Scholarship Council (CSC, No. 201806130168)the International Postdoctoral Exchange Fellowship Program (Grant No. PC2022020)
文摘As the need for high-energy–density batteries continues to grow, lithium-sulfur(Li–S) batteries have become a highly promising next-generation energy solution due to their low cost and exceptional energy density compared to commercially available Li-ion batteries. Research into carbon-based sulfur hosts for Li–S batteries has been ongoing for over two decades, leading to a significant number of publications and patents.However, the commercialization of Li–S batteries has yet to be realized. This can be attributed, in part, to the instability of the Li metal anode. However, even when considering just the cathode side, there is still no consensus on whether carbon-based hosts will prove to be the best sulfur hosts for the industrialization of Li–S batteries. Recently, there has been controversy surrounding the use of carbon-based materials as the ideal sulfur hosts for practical applications of Li–S batteries under high sulfur loading and lean electrolyte conditions. To address this question, it is important to review the results of research into carbon-based hosts, assess their strengths and weaknesses, and provide a clear perspective. This review systematically evaluates the merits and mechanisms of various strategies for developing carbon-based host materials for high sulfur loading and lean electrolyte conditions. The review covers structural design and functional optimization strategies in detail, providing a comprehensive understanding of the development of sulfur hosts. The review also describes the use of efficient machine learning methods for investigating Li–S batteries. Finally, the outlook section lists and discusses current trends, challenges, and uncertainties surrounding carbon-based hosts, and concludes by presenting our standpoint and perspective on the subject.
基金supported by the Biomedicine Supporting Program of Shanghai "Science and Technology Innovation Plan" (19441902400)the Ningxia Hui Autonomous Region Key R&D program (2020BCH01001)+1 种基金the Shanghai "Science and Technology Innovation Action Plan" Domestic Science and Technology Cooperation Project (20025800200)the Clinical Research Program of Shanghai Municipal Health Commission (201940367)。
文摘Background:Chronic ankle instability(CAI) is a common sequela following an acute lateral ankle sprain(LAS).To treat an acture LAS more effectively and efficiently,it is important to identify patients at substantial risk for developing CAI.This study identifies magnetic resonance imaging(MRI) manifestations for predicting CAI development after a first episode of LAS and explores appropriate clinical indications for ordering MRI scans for these patients.Methods:All patients with a first-episode LAS who received plain radiograph and MRI scanning within the first 2 weeks after LAS from December 1,2017 to December 1,2019 were identified.Data were collected using the Cumberland Ankle Instability Tool at final follow-up.Demographic and other related clinical variables,including age,sex,body mass index,and treatment were also recorded.Univariable and multivariable analyses were performed successively to identify risk factors for CAI after first-episode LAS.Results:A total 131 out of 362 patients with a mean follow-up of 3.0± 0.6 years(mean ± SD;2.0—4.1 years) developed CAI after first-episode LAS.According to multivariable regression,development of CAI after first-episode LAS was associated with 5 prognostic factors:age(odds ratio(OR)=0.96,95% confidence interval(95%CI):0.93-1.00,p=0.032);body mass index(OR=1.09,95%CI:1.02-1.17,p=0.009);posterior talofibular ligament injury(OR=2.17,95%CI:1.05-4.48,p=0.035);large bone marrow lesion of the talus(OR=2.69,95%CI:1.30-5.58,p=0.008),and Grade 2 effusion of the tibiotalar joint(OR=2.61,95%CI:1.39-4.89,p=0.003).When patients had at least 1 positive clinical finding in the 10-m walk test,anterior drawer test,or inversion tilt test,they had a 90.2% sensitivity and 77.4% specificity in terms of detecting at least 1 prognostic factor by MRI.Conclusion:MRI scanning is valuable in predicting CAI after first-episode LAS for those patients with at least 1 positive clinical finding in the10-m walk test,anterior drawer test,and inversion tilt test.Further prospective and large-scale studies are necessary for validation.
基金supported fi nancially by the National Natural Science Foundation of China(U1808201).
文摘Research has indicated that introducing Aralia elata into larch plantations forms an agroforestry system which could provide economic benefi ts for local farmers and improve degraded soils.However,the impact of litter mixtures on soil chemical and microbial properties in this agroforestry system are unclear,which limits effi cient management of the agroforestry system.A 365-d incubation experiment examined the eff ect of litter mixtures of diff erent proportions of larch(L)and A.elata(A)on soil chemical and microbial properties.The results show that levels of mineral N,available P,microbial biomass carbon and nitrogen,cumulative C mineralization,and activities of hydrolases and oxidases increased with an increase of A.elata in the litter mixtures.Concentration of total soil carbon,nitrogen,and phosphorous did not change(except for total nitrogen).Compared with larch litter alone,levels of mineral N,available P,microbial biomass carbon and nitrogen,cumulative C mineralization,and the activities of hydrolases and oxidases increased by 7.6–433.5%.Most chemical and microbial properties were positively correlated with mixed litter proportions and the initial levels of N,P,K,Ca,Mg,Mn,Zn and Cu in the litter,while negatively correlated with the initial concentrations of C,Fe and lignin,C/N and lignin/N ratios.The results indicate that A.elata litter can improve degraded larch soil and the degree depends on the proportion of A.elata litter in the litter mixtures.
基金supported by the National Natural Science Foundation of China(22209140,52072328,and 52175192)the Incubation Program of Youth Innovation in Shandong Province and Natural Science Foundation of Shandong Province(ZR2022QE059)。
文摘Garnet-structured ceramic electrolyte Li_(6.75)La_(3)Zr_(1.75)Ta_(0.25)O_(12)(LLZTO)attracts significant consideration in solid-state Li metal batteries due to its wide electrochemical window and favorable compatibility with Li metal.However,the deployment of LLZTO is severely hampered by poor contact between LLZTO and Li metal anode.In this paper,an ultra-thin Al-Si interface buffer layer(10 nm)is constructed on LLZTO by a magnetron sputtering method,which allows superior wetting of Li onto the LLZTO surface due to the alloying reaction between the Al-Si layer and Li metal.The resulting Li/Al-Si coated LLZTO(ASL)/Li symmetrical cell delivers an interfacial resistance of 15.0Ωcm^(-2),which is much lower than that of 1140.3Ωcm^(-2)for the bare LLZTO symmetrical cell.Moreover,the Li/ASL/Li symmetrical cells exhibit stable plating/striping performance(800 h)with small voltage hysteresis at 1.0 mA cm^(-2).Besides,the full cell with LiFePO_(4)cathode reveals a high capacity of 124.1 mA h g^(-1)after 600 cycles at 0.5C with a lowcapacity decay of 0.032%per cycle.We believe this work will facilitate the development of solid-state rechargeable batteries.
基金financially supported by the National Natural Science Foundation of China(Key Program: 52034011,51974219General Program: 51974219)。
文摘Molybdenum trioxide(MoO_(3))has recently attracted wide attention as a typical conversion-type anode of Li-ion batteries(LIBs).Nevertheless,the inferior intrinsic conductivity and rapid capacity fading during charge/discharge process seriously limit large-scale commercial application of MoO_(3).Herein,the density function theory(DFT)calculations show that electron-proton co-doping preferentially bonds symmetric oxygen to form unstable HxMoO_(3).When the-OH-group in HxMoO_(3) is released into the solution in the form of H_(2)O,it is going to form MoO_(3-x)with lower binding energy.By the means of both electron-proton co-doping and high-energy nanosizing,oxygen vacancies and nanoflower structure are introduced into MoO_(3) to accelerate the ion and electronic diffusion/transport kinetics.Benefitting from the promotion of ion diffusion kinetics related to nanostructures,as well as both the augmentation of active sites and the improvement of electrical conductivity induced by oxygen vacancies,the MoO_(3-x)/nanoflower structures show excellent lithium-ion storage performance.The prepared specimen has a high lithium-ion storage capacity of 1261 mA h g^(-1)at 0.1 A g^(-1)and cyclic stability(450 cycle),remarkably higher than those of previously reported MoO_(3)-based anode materials.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.NT2021020)。
文摘Conventional mechanical machining of a composite material comprising an aluminum matrix reinforced with a high volume fraction of SiC particles(hereinafter referred to as an SiCp/Al composite)faces problems such as rapid tool wear,high specific cutting force,and poor surface integrity.Instead,a promising method for solving these problems is laser-induced oxidation-assisted milling(LOAM):under laser irradiation,the local workpiece material reacts with oxygen,thus forming loose and porous oxides that are easily removed.In the present work,the oxidation mechanism of SiCp/Al irradiated by a nanosecond pulsed laser is studied to better understand the laser-induced oxidation behavior and control the characteristics of the oxides,with laser irradiation experiments performed on a 65%SiCp/Al composite with various laser parameters and auxiliary gases(oxygen,nitrogen,and argon).With increasing laser pulse energy density,both the ablated groove depth and the width of the heat-affected zone increase.When oxygen is used as the auxiliary gas,an oxide layer composed of SiO_(2)and Al2O3 forms,and CO_(2)is produced and escapes from the material,thereby forming pores in the oxides.However,when nitrogen or argon is used as the auxiliary gas,a recast layer is produced that is relatively difficult to remove.Under laser irradiation,the sputtered material reacts with oxygen to form oxides on both sides of the ablated groove,and as the laser scanning path advances,the produced oxides accumulate to form an oxide layer.LOAM and conventional milling are compared using the same milling parameters,and LOAM is found to be better for reduced milling force and tool wear and improved machined surface quality.
基金financially supported by the National Natural Science Foundation of China (Nos.51974222 and 52034011)。
文摘Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency,high production,environmental friendliness,and low cost.The uniform distribution of grains can effectively inhibit the aggregation of active materials,improving lithium storage performance.In this work,natural graphite is modified by polyvinylpyrrolidone to obtain modified graphite with reduced size and better dispersion.Natural pyrite composite polyvinylpyrrolidone-modified graphite(pyrite/PG)material with uniform particle distribution is obtained by the ball milling process.The subsequent calcination process converts pyrite/PG into Fe_(1-x)Scompounded with polyvinylpyrrolidone-modified graphite(Fe_(1-x)S/PG).The homogeneous grain distributions of active material can facilitate the faster transfer of electrons and promote the efficient utilization of active materials.The as-prepared Fe_(1-x)S/PG electrode exhibits a remarkably reversible specific capacity of 613.0 mAh·g^(-1)at 0.2 A·g^(-1)after 80 cycles and an excellent rate capability of 523.0 mAh·g^(-1)at 5 A·g^(-1).Even at a higher current density of 10 A·g^(-1),it can deliver a specific capacity of 348.0 mAh·g^(-1).Moreover,the dominant pseudocapacitance in redox reactions accounts for the impressive rate and cycling stability.This work provides a low-cost and facile method to fabricate natural mineral-based anode materials and apprise readers about the impact of uniform particle distribution on lithium storage performance.
基金funded by Key R&D project of Ningxia Hui Autonomous Region(2021BDE931027)Science and technology project of State Grid Ningxia Electric Power Co.Ltd.(229DK2004P).
文摘Traditional inspection methods cannot quickly and accurately monitor tree barriers and safeguard the transmission lines.To solve these problems,in this study,we proposed a rapid canopy height information extraction method using optical remote sensing and LiDAR,and used UAV optical imagery with LiDAR to monitor the height of trees in a university and a high-voltage transmission line corridor in the Ningxia region.The results showed that the relative error of tree height extraction using UAV optical images was less than 5%,and the lowest relative error was 0.11%.The determination coefficient R^(2) between the optical image tree height extraction results and the measured tree height was 0.97,thus indicating a high correlation for both.In the field of tree barrier monitoring,the determination coefficient R^(2) of tree height extracted using airborne LiDAR point cloud,and canopy height model(CHM)and of the measured tree height were 0.947 and 0.931,respectively.The maximum and minimum relative error in tree height extraction performed using point cloud was 2.91%and 0.2%,respectively,with an extraction accuracy of over 95%.The experimental results demonstrated that it is feasible to use UAV optical remote sensing and LiDAR in monitoring tree barriers and tree height information extraction quickly and accurately,which is of great significance for the risk assessment and early warning of tree barriers in transmission-line corridors.
基金National Research Foundation of Korea,Grant/Award Numbers:2022R1F1A1074441,2022R1F1A1074707KIST Institutional Program,Grant/Award Numbers:2V09480,2E32582。
文摘Commercialization of Zn-metal anodes with low cost and high theoretical capacity is hindered by the poor reversibility caused by dendrites growth,side reactions,and the slow Zn^(2+)-transport and reaction kinetics.Herein,a reversible heterogeneous electrode of Zn-nanocrystallites/polyvinylphosphonic acrylamide(Zn/PPAm)with fast electrochemical kinetics is designed for the first time:phosphonic acid groups with strong polarity and chelation effect ensure structural reversibility and stability of the threedimensional Zn-storage-host PPAm network and the Zn/PPAm hybrid;hydrophobic carbon chains suppress side reactions such as hydrogen evolution and corrosion;weak electron-donating amide groups constitute Zn^(2+)-transport channels and promote“desolvation”and“solvation”effects of Zn^(2+)by dragging the PPAm network on the Zn-metal surface to compress/stretch during Zn plating/stripping,respectively;and the heterostructure and Zn nanocrystallites suppress dendrite growth and enhance electrochemical reactivity,respectively.Thus,the Zn/PPAm electrode shows cycle reversibility of over 6000 h with a hysteresis voltage as low as 31 mV in symmetrical cells and excellent durability and flexibility in fiber-shaped batteries.
基金supported by research grants from the National Research Foundation of Korea(Nos.2020R1I1A1A01072996,2021K2A9A2A06044652,and 2019H1D3A1A01069779)KIST Institutional Program(2E331863)funded by the government of the Republic of Korea.
文摘Nitrogen-doped carbon-coated transition-metal sulfides(TMS@NCs)have been considered as efficient anodes for sodium-ion batteries.However,the uncontrollable morphology and weak core-shell binding forces significantly limit the sodium storage performance and life.Herein,based on the reversible ring-opening reaction of the epoxy group of the tertiary amino group-rich epoxide cationic polyacrylamide(ECP)at the beginning of hydrothermal process(acidic environment)and the irreversible ring-opening(cross-linking reactions)at the late hydrothermal period(alkaline environment),47 nm-sized ZnS@NCs were prepared via a one-pot hydrothermal process.During this process,the covalent bonds formed between the ZnS core and elastic carbon shell significantly improved the mechanical and chemical stabilities of ZnS@NC.Benefiting from the nanosize,fast ion/electron transfer,and high stability,ZnS@NC exhibited a high reversible capacity of 421.9 mAh g^(−1) at a current density of 0.1 A g^(−1) after 1000 cycles and a superior rate capability of 273.8 mAh g^(−1) at a current density of 5 A g^(−1).Moreover,via this universal synthesis strategy,a series of TMS@NCs,such as MoS_(2)@NC,NiS@NC,and CuS@NC were developed with excellent capacity and cyclability.
基金funded by the Project Funded by China Postdoctoral Science Foundation(No.2022T150445)the Beijing Hospitals Authority Youth Programme(No.QML20211401)+1 种基金the Young Talent Foundation of PLA General Hospital(2019-YQPY-002)Beijing Nova Program(Z201100006820057).
文摘Receptor tyrosine kinase-like orphan receptor 2(ROR2)has a vital role in osteogenesis.However,the mechanism underlying the regulation of ROR2 in osteogenic differentiation is still poorly comprehended.A previous study by our research group showed that a novel compound heterozygous ROR2 variation accounted for the autosomal recessive Robinow syndrome(ARRS).This study attempted to explore the impact of the ROR2:c.904C>T variant specifically on the osteogenic differentiation of BMSCs.Methods:Coimmunoprecipitation(CoIP)-western blotting was carried out to identify the interaction between ROR2 and Wnt5a.Double-immunofluorescence staining was used for determining the expressions and co-localization of ROR2 and Wnt5a in bone marrow mesenchymal stem cells(BMSCs).Western blot(WB)analysis and quantitative reverse transcription polymerase chain reaction(RT-qPCR)were conducted to identify the expression levels of ROR2 in the BMSCs transfected with LV-shROR2 or LV-ROR2-c.904C>T.The alkaline phosphatase(ALP)activity was detected,and Alizarin Red S staining was done for evaluating the osteogenic differentiation of BMSCs.RT-qPCR was employed to identify the expression of the sphingomyelin synthase 1(SMS1)mRNA in the BMSCs transfected with LV-shROR2 or LV-ROR2-c.904C>T and the mRNA expression levels of Runt-related transcription factor 2(RUNX2),osteocalcin(OCN),and osteopontin(OPN).WB was performed to confirm the protein expressions of extracellular regulated protein kinases1(ERK),P-ERK,Smad family member1/5/8(Smad1/5/8),P-Smad1/5/8,P-P38,P38,RUNX2,OCN,and OPN in the BMSCs transfected with LV-shROR2/LV-ROR2-c.904C>T and sphingomyelin(SM).Results:The ROR2:c.904C>T mutant altered the subcellular localization of the ROR2 protein,which caused an impaired interaction between ROR2 and Wnt5a.The depletion of ROR2 restricted the osteogenic differentiation capability of BMSCs and downregulated the expression of SMS1.SM treatment could reverse the inhibition of osteoblastic differentiation in ROR2-depleted BMSCs.Conclusion:The findings of this work revealed that the ROR2:c.904C>T variant led to the loss of function of ROR2,which impaired the interaction between ROR2 and Wnt5a and also controlled the osteogenic differentiation capability of BMSCs.Furthermore,SM was revealed to be engaged in the osteoblastic differentiation of BMSCs regulated by ROR2,which renders SM a potential target in the therapy for ARRS.
文摘Correction to:J.For.Res.https://doi.org/10.1007/s11676-022-01526-w The article“The amelioration of degraded larch(Larix olgensis)soil depends on the proportion of Aralia elata litter in larch-A.elata agroforestry systems”,written by Pingzhen Gao·Jiaojun Zhu·Qiaoling Yan·Kai Yang and Jinxin Zhang was originally published Online First without Open Access.
文摘BACKGROUND We report a rare case of full neurological recovery from severe nonexertional heat stroke in a 67-year-old woman with an initial Glasgow Coma Scale of 3.This report raises awareness among doctors that when heatstroke is diagnosed,comprehensive treatment should be implemented as soon as possible.Moreover,targeted temperature management,combination therapy with hemodialysis and hemoperfusion,and hyperbaric oxygen therapy may alleviate multiorgan failure and prevent neurological sequelae caused by heatstroke.CASE SUMMARY A previously healthy 67-year-old woman with an initial Glasgow Coma Scale of 3 was found lying prone on the road at noon on a summer day.Laboratory tests revealed multiorgan failure.As soon as heatstroke was diagnosed,comprehensive treatment was implemented.On hospital Day 3,the patient was extubated.Her initial Sequential Organ Failure Assessment score at hospitalization was 14 and decreased to 2 on hospital Day 4.On the seventh day following hospital admission,as the patient’s general condition improved,the levels of laboratory test findings decreased rapidly.Finally,the patient gradually recovered with no other neurological symptoms(the Glasgow Coma Scale at discharge was 15,and her ability to walk independently was restored).CONCLUSION This case demonstrated that targeted temperature management,combination therapy with hemodialysis and hemoperfusion,and hyperbaric oxygen therapy may alleviate multiorgan failure and prevent neurological sequelae caused by heatstroke.
文摘With the rapid development of sports,the number of sports images has increased dramatically.Intelligent and automatic processing and analysis of moving images are significant,which can not only facilitate users to quickly search and access moving images but also facilitate staff to store and manage moving image data and contribute to the intellectual development of the sports industry.In this paper,a method of table tennis identification and positioning based on a convolutional neural network is proposed,which solves the problem that the identification and positioning method based on color features and contour features is not adaptable in various environments.At the same time,the learning methods and techniques of table tennis detection,positioning,and trajectory prediction are studied.A deep learning framework for recognition learning of rotating flying table tennis is put forward.The mechanism and methods of positioning,trajectory prediction,and intelligent automatic processing of moving images are studied,and the self-built data sets are trained and verified.
