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A Novel Analytical Method for Structural Characteristics of Gene Networks and its Application
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作者 Shudong Wang Yuanyuan Zhang +1 位作者 kaikai li Dazhi Meng 《Computational Molecular Bioscience》 2012年第3期92-101,共10页
Analyzing gene network structure is an important way to discover and understand some unknown relevant functions and regulatory mechanisms of organism at the molecular level. In this work, mutual information networks a... Analyzing gene network structure is an important way to discover and understand some unknown relevant functions and regulatory mechanisms of organism at the molecular level. In this work, mutual information networks and Boolean logic networks are constructed using the methods of reverse modeling based on gene expression profiles in lung tissues with and without cancer. The comparison of these network structures shows that average degree, the proportion of non-isolated nodes, average betweenness and average coreness can distinguish the networks corresponding to the lung tissues with and without cancer. According to the difference of degree, betweenness and coreness of each gene in these networks, nine structural key genes are obtained. Seven of them which are related to lung cancer are supported by literatures. The remaining two genes AKT1 and RBL may have important roles in the formation, development and metastasis of lung cancer. Furthermore, the contrast of these logic networks suggests that the distributions of logic types are obviously different. The structural differences can help us to understand the mechanism of formation and development of lung cancer. 展开更多
关键词 Systems BIOLOGY Gene NETWORK LOGIC NETWORK STRUCTURAL PARAMETER LUNG Cancer
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猪伪狂犬病的流行病学、临床症状及防控措施 被引量:7
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作者 崔煜坤 李相安 +5 位作者 李克鑫 佟庆东 李开凯 张平 牛绪东 刘建柱 《猪业科学》 2021年第2期101-104,共4页
猪伪狂犬病由伪狂犬病毒引起,临床上以妊娠母猪流产、产死胎,新生仔猪出现共济失调、神经症状,并造成仔猪大量死亡为特征。自伪狂犬病毒毒株变异以来,病猪数量不断增加,严重威胁了养猪业健康发展,并造成巨大的经济损失。文章将从流行病... 猪伪狂犬病由伪狂犬病毒引起,临床上以妊娠母猪流产、产死胎,新生仔猪出现共济失调、神经症状,并造成仔猪大量死亡为特征。自伪狂犬病毒毒株变异以来,病猪数量不断增加,严重威胁了养猪业健康发展,并造成巨大的经济损失。文章将从流行病学、临床症状、病理变化、鉴别诊断、防控措施等几个方面对猪伪狂犬病进行概述,希望能够对猪伪狂犬病的防控、净化提供帮助。 展开更多
关键词 猪伪狂犬病 妊娠母猪流产 伪狂犬病毒 流行病学 神经症状 养猪业 防控措施 新生仔猪
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Parallel Implementation of the Non-Overlapping Template Matching Test Using CUDA
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作者 kaikai li Jianguo Zhang +2 位作者 Pu li Anbang Wang Yuncai Wang 《China Communications》 SCIE CSCD 2020年第8期234-241,共8页
NIST(National Institute of Standards and Technology) statistical test recognized as the most authoritative is widely used in verifying the randomness of binary sequences. The Non-overlapping Template Matching Test as ... NIST(National Institute of Standards and Technology) statistical test recognized as the most authoritative is widely used in verifying the randomness of binary sequences. The Non-overlapping Template Matching Test as the 7 th test of the NIST Test Suit is remarkably time consuming and the slow performance is one of the major hurdles in the testing process. In this paper, we present an efficient bit-parallel matching algorithm and segmented scan-based strategy for execution on Graphics Processing Unit(GPU) using NVIDIA Compute Unified Device Architecture(CUDA). Experimental results show the significant performance improvement of the parallelized Non-overlapping Template Matching Test, the running speed is 483 times faster than the original NIST implementation without attenuating the test result accuracy. 展开更多
关键词 random numbers CUDA non-overlapping template matching test parallel implementation NIST test
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Fabrication of hierarchical MXene-based AuNPs-containing core-shell nanocomposites for high efficient catalysts
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作者 kaikai li Tifeng Jiao +5 位作者 Ruirui Xing Guodong Zou Qianran Zhao Jingxin Zhou Lexin Zhang Qiuming Peng 《Green Energy & Environment》 SCIE 2018年第2期147-155,共9页
MXene is a new type of layered two-dimensional transition metal carbide materials differing from graphene, demonstrating intriguing chemical/physical properties. Here the chemical modification of MXene and next fabric... MXene is a new type of layered two-dimensional transition metal carbide materials differing from graphene, demonstrating intriguing chemical/physical properties. Here the chemical modification of MXene and next fabrication of core-shell MXene-COOH@(PEI/PAA)_n composites have been investigated. The obtained MXene-based composites were treated with gold nanoparticles to form MXene—COOH@(PEI/PAA)_n@AuNPs nanocomposites, and their catalytic properties for nitro-compounds were studied. The prepared nanocomposites demonstrated good catalytic activity and reproducibility, showing potential applications in composite catalysts and environmental fields. 展开更多
关键词 MXene Core-shell composite NITRO-COMPOUNDS Gold nanoparticle Catalytic activity
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Superhydrophobic Purple Orchid Leaves:Variation in Surface Morphology During the Vegetation Stages Leading to Diversity in Wettability
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作者 Longsheng Lu Guoxiang Jiang +2 位作者 kaikai li Yingxi Xie Jiao Gao 《Journal of Bionic Engineering》 SCIE EI CSCD 2023年第6期2774-2785,共12页
Learning hydrophobic phenomena from nature is always a promising approach to design the superhydrophobic surface.Purple orchid leaf which processes superhydrophobicity is an ideal plant model,and through mimicking its... Learning hydrophobic phenomena from nature is always a promising approach to design the superhydrophobic surface.Purple orchid leaf which processes superhydrophobicity is an ideal plant model,and through mimicking its structure,the surface with excellent hydrophobicity is able to be obtained.However,the unclear of the diversity in wettability during the different vegetation stages and the absence of its relation to the surface morphology limits the further enhancement of the inspired structure.Here,we analyze the wettability difference as the leaf grows from tender to mature and then to senescent.Combining with the variation of surface morphology and chemical composition,the well-developed micro-scale basic unit bumps with dense nano-scale waxy layer on the surface are proven to be responsible for the best hydrophobicity of the mature leaf.The presence of the undeveloped or damaged micro-nano hierarchical structure reduces the formation of air pockets at the interface,leading to the decrease of the wettability for leaves at other stages.Moreover,by fabricating artificial leaves,the nano-waxy layer is proved to be more effective than that of the micro-bumps on the surface wettability.The results of study are of a great significance for guiding the design and fabrication of plant-inspired bionic superhydrophobic surface. 展开更多
关键词 SUPERHYDROPHOBICITY Surface morphology Micro-nano hierarchical structure Purple orchid leaf BIONIC
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Chemical Strain of Graphite-Based Anode during Lithiation and Delithiation at Various Temperatures
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作者 Zeyu Xu Xiuling Shi +4 位作者 Xiaoqiang Zhuang Zihan Wang Sheng Sun kaikai li Tong-Yi Zhang 《Research》 SCIE EI CAS CSCD 2021年第1期1255-1265,共11页
Electrochemical lithiation/delithiation of electrodes induces chemical strain cycling that causes fatigue and other harmful influences on lithium-ion batteries.In this work,a homemade in situ measurement device was us... Electrochemical lithiation/delithiation of electrodes induces chemical strain cycling that causes fatigue and other harmful influences on lithium-ion batteries.In this work,a homemade in situ measurement device was used to characterize simultaneously chemical strain and nominal state of charge,especially residual chemical strain and residual nominal state of charge,in graphite-based electrodes at various temperatures.The measurements indicate that raising the testing temperature from 20℃ to 60℃ decreases the chemical strain at the same nominal state of charge during cycling,while residual chemical strain and residual nominal state of charge increase with the increase of temperature.Furthermore,a novel electrochemicalmechanical model is developed to evaluate quantitatively the chemical strain caused by a solid electrolyte interface(SEI)and the partial molar volume of Li in the SEI at different temperatures.The present study will definitely stimulate future investigations on the electro-chemo-mechanics coupling behaviors in lithium-ion batteries. 展开更多
关键词 NOMINAL CYCLING lithium
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Chemical Strain of Graphite-Based Anode during Lithiation and Delithiation at Various Temperatures
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作者 Zeyu Xu Xiuling Shi +4 位作者 Xiaoqiang Zhuang Zihan Wang Sheng Sun kaikai li Tong-Yi Zhang 《Research》 EI CAS CSCD 2022年第1期185-195,共11页
Electrochemical lithiation/delithiation of electrodes induces chemical strain cycling that causes fatigue and other harmful influences on lithium-ion batteries.In this work,a homemade in situ measurement device was us... Electrochemical lithiation/delithiation of electrodes induces chemical strain cycling that causes fatigue and other harmful influences on lithium-ion batteries.In this work,a homemade in situ measurement device was used to characterize simultaneously chemical strain and nominal state of charge,especially residual chemical strain and residual nominal state of charge,in graphite-based electrodes at various temperatures.The measurements indicate that raising the testing temperature from 20℃ to 60℃ decreases the chemical strain at the same nominal state of charge during cycling,while residual chemical strain and residual nominal state of charge increase with the increase of temperature.Furthermore,a novel electrochemicalmechanical model is developed to evaluate quantitatively the chemical strain caused by a solid electrolyte interface(SEI)and the partial molar volume of Li in the SEI at different temperatures.The present study will definitely stimulate future investigations on the electro-chemo-mechanics coupling behaviors in lithium-ion batteries. 展开更多
关键词 NOMINAL CYCLING lithium
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毛乌素沙地不同类型生物结皮细菌群落差异及其驱动因子
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作者 张雅丽 张丙昌 +2 位作者 赵康 李凯凯 刘燕晋 《生物多样性》 CAS CSCD 北大核心 2023年第8期79-89,共11页
生物结皮在干旱半干旱区具有极为重要的生态功能,细菌是生物结皮中的重要微生物类群,在生物结皮形成、养分循环与调控过程中发挥着关键作用。然而,对于毛乌素沙地生物结皮演替过程中细菌群落多样性和关键环境因子的认识尚不清楚。因此,... 生物结皮在干旱半干旱区具有极为重要的生态功能,细菌是生物结皮中的重要微生物类群,在生物结皮形成、养分循环与调控过程中发挥着关键作用。然而,对于毛乌素沙地生物结皮演替过程中细菌群落多样性和关键环境因子的认识尚不清楚。因此,本文通过q PCR和高通量测序方法调查了毛乌素沙地裸地、藻结皮、地衣结皮和藓结皮之间的细菌丰度和群落多样性,并探究了生物结皮中细菌群落及其与关键环境因子之间的关系。结果表明,随着生物结皮的演替,细菌16S rRNA基因丰度呈显著上升趋势,细菌Chao1、Shannon指数和系统发育多样性呈先降低后增加的模式。生物结皮不同阶段的细菌门、目和属的相对丰度均存在显著差异,在裸地阶段优势细菌类群是拟杆菌门的噬几丁质菌目、放线菌门的红色杆菌目和变形菌门的根瘤菌目;藻结皮和地衣结皮中均以蓝藻门的颤藻目占绝对优势;藓结皮的细菌以拟杆菌门的噬几丁质菌目和变形菌门的根瘤菌目占优势。全磷、全氮、pH和总有机碳是影响土壤细菌群落的关键环境因子。综上所述,生物结皮的演替通过改变土壤理化特性,为细菌群落提供了不同生态位,其中,土壤养分和pH等环境因子对毛乌素沙地生物结皮细菌物种筛选和群落塑造发挥着重要作用。 展开更多
关键词 生物结皮 演替 细菌群落多样性 环境因子 毛乌素沙地
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Cutting performance of surgical electrodes by constructing bionic microstriped structures
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作者 kaikai li Longsheng LU +4 位作者 Huaping CHEN Guoxiang JIANG Huanwen DING Min YU Yingxi XIE 《Frontiers of Mechanical Engineering》 SCIE CSCD 2023年第1期163-178,共16页
Surgical electrodes rely on thermal effect of high-frequency current and are a widely used medical tool for cutting and coagulating biological tissue.However,tissue adhesion on the electrode surface and thermal injury... Surgical electrodes rely on thermal effect of high-frequency current and are a widely used medical tool for cutting and coagulating biological tissue.However,tissue adhesion on the electrode surface and thermal injury to adjacent tissue are serious problems in surgery that can affect cutting performance.A bionic microstriped structure mimicking a banana leaf was constructed on the electrode via nanosecond laser surface texturing,followed by silanization treatment,to enhance lyophobicity.The effect of initial,simple grid-textured,and bionic electrodes with different wettabilities on tissue adhesion and thermal injury were investigated using horizontal and vertical cutting modes.Results showed that the bionic electrode with high lyophobicity can effectively reduce tissue adhesion mass and thermal injury depth/area compared with the initial electrode.The formation mechanism of adhered tissue was discussed in terms of morphological features,and the potential mechanism for antiadhesion and heat dissipation of the bionic electrode was revealed.Furthermore,we evaluated the influence of groove depth on tissue adhesion and thermal injury and then verified the antiadhesion stability of the bionic electrode.This study demonstrates a promising approach for improving the cutting performance of surgical electrodes. 展开更多
关键词 surgical electrodes tissue adhesion thermal injury bionic structures cutting performance medical tools
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Fast and stable K-ion storage enabled by synergistic interlayer and pore-structure engineering 被引量:1
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作者 Deping li Qing Sun +6 位作者 Yamin Zhang Xinyue Dai Fengjun Ji kaikai li Qunhui Yuan Xingjun liu lijie Ci 《Nano Research》 SCIE EI CSCD 2021年第12期4502-4511,共10页
Carbon-based material has been regarded as one of the most promising electrode materials for potassium-ion batteries(PIBs).However,the battery performance based on reported porous carbon electrodes is still unsatisfac... Carbon-based material has been regarded as one of the most promising electrode materials for potassium-ion batteries(PIBs).However,the battery performance based on reported porous carbon electrodes is still unsatisfactory,while the in-depth K-ion storage mechanism remains relatively ambiguous.Herein,we propose a facile“in situ self-template bubbling”method for synthesizing interlayer-tuned hierarchically porous carbon with different metallic ions,which delivers superior K-ion storage performance,especially the high reversible capacity(360.6 mAh·g^(−1)@0.05 A·g^(−1)),excellent rate capability(158.6 mAh·g^(−1)@10.0 A·g^(−1))and ultralong high-rate cycling stability(82.8%capacity retention after 2,000 cycles at 5.0 A·g^(−1)).Theoretical simulation reveals the correlations between interlayer distance and K-ion diffusion kinetics.Experimentally,deliberately designed consecutive cyclic voltammetry(CV)measurements,ex situ Raman tests,galvanostatic intermittent titration technique(GITT)method decipher the origin of the excellent rate performance by disentangling the synergistic effect of interlayer and pore-structure engineering.Considering the facile preparation strategy,superior electrochemical performance and insightful mechanism investigations,this work may deepen the fundamental understandings of carbon-based PIBs and related energy storage devices like sodium-ion batteries,aluminum-ion batteries,electrochemical capacitors,and dual-ion batteries. 展开更多
关键词 potassium-ion batteries synergistic interlayer and pore-structure engineering theoretical calculations carbonaceous electrode ex situ Raman technique
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Discovery of SPICE and carbon isotope stratigraphic correlation of the Cambrian Furongian Series in Tarim Craton, NW China 被引量:1
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作者 Yongquan CHEN Yanqiu ZHANG +3 位作者 Yasheng WU Peng ZHOU kaikai li Xiaoxue WANG 《Science China Earth Sciences》 SCIE EI CAS CSCD 2020年第9期1330-1338,共9页
The Furongian Series of the Cambrian in the Tarim Craton(NW China)is mainly composed of crystalline dolostones,and is an important target for oil and gas exploration.The chronostratigraphic framework of the Furongian ... The Furongian Series of the Cambrian in the Tarim Craton(NW China)is mainly composed of crystalline dolostones,and is an important target for oil and gas exploration.The chronostratigraphic framework of the Furongian Series in the Tarim Craton has not yet been established due to the scarcity of fossils and the absence of the Steptoean Positive Carbon Isotope Excursion(SPICE),which is the primary global carbon isotope excursion of the Furongian Series.In this study,the SPICE was discovered by examining the carbon isotopes of the representative drilling wells in the West Platform and East Basin.A positive carbon isotope anomaly withδ13C values ranging from 1.5‰to 1.9‰(PDB),were found in the middle of the Xiaqiulitag Formation of the three drilling wells in the West Platform,and a positive excursion withδ13C values up to 4.0‰(PDB),which is correlated with the SPICE,was found in the lower limestone of the Tuershaketag Formation in the East Basin.Based on the carbon isotopic data and chemostratigraphic correlation,the chronostratigraphic framework of the Furongian Series across different facies in the Tarim Craton is preliminarily established.The basal boundary of the Furongian Series was preliminarily defined by the occurrence of the SPICE.Aweak positive anomaly ofδ13C was observed at the base of the Penglaiba Formation of the three boreholes in the West Platform and the top of the Tuershaketag Formation of Tadong-2 well.We propose that the positive anomaly of the carbon isotope above the weak negative anomaly at the base of the Penglaiba Formation and the top of the Tuershaketag Formation can be used to define the Cambrian-Ordovician boundary in the Tarim Craton. 展开更多
关键词 Tarim craton CAMBRIAN Furongian series SPICE Carbon isotope stratigraphy
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Research on the maximum power point tracking method of photovoltaic based on Newton interpolation-assisted particle swarm algorithm 被引量:1
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作者 liMing Wei kaikai li 《Clean Energy》 EI 2022年第3期496-502,共7页
Solar energy has attracted a lot of attention because it is clean and has no pollution.However,due to the partially shaded condition,the photovoltaic array cannot work uniformly at the maximum power point,resulting in... Solar energy has attracted a lot of attention because it is clean and has no pollution.However,due to the partially shaded condition,the photovoltaic array cannot work uniformly at the maximum power point,resulting in a large power loss.To improve this problem,the research of the maximum power point tracking(MPPT)algorithm is discussed by scholars.In this paper,an improved particle swarm optimization(PSO)algorithm is proposed to achieve the goal of MPPT,which uses Newton interpolation-assisted conventional PSO.After tracking to the maximum power point,the Newton interpolation method is used to calculate the maximum power point,reduce the number of iterations of the conventional PSO algorithm and reduce the steady-state oscillation.The simulation is carried out in MATLAB^(■)/Simulink^(■)and compared with conventional PSO.The results show that the improved PSO has better tracking ac-curacy and speed than the conventional algorithm,and the initial tracking speed is increased by>30%. 展开更多
关键词 photovoltaic array maximum power point tracking particle swarm optimization algorithm Newton interpolation method
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一种用于高性能聚环氧乙烷基全固态电池的新型珊瑚状石榴石
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作者 程俊 侯广梅 +8 位作者 孙卿 陈琼 李德平 李建伟 曾振 李锴锴 袁群惠 王家钧 慈立杰 《Science China Materials》 SCIE EI CAS CSCD 2022年第2期364-372,共9页
锂金属电池被认为是最有前景的下一代储能设备之一,但是锂金属电池的安全性问题以及锂枝晶生长问题严重阻碍了它的实用化进程.固态电解质可以有效解决这一安全性问题,表现出能够抑制锂枝晶生长的巨大潜力,并因此受到大家的关注.其中聚... 锂金属电池被认为是最有前景的下一代储能设备之一,但是锂金属电池的安全性问题以及锂枝晶生长问题严重阻碍了它的实用化进程.固态电解质可以有效解决这一安全性问题,表现出能够抑制锂枝晶生长的巨大潜力,并因此受到大家的关注.其中聚环氧乙烷(PEO)基固态电解质由于具有较高的安全性以及出色的柔韧性,被认为是一类非常有应用前景的固态电解质.但是,其固有的半结晶特性以及较差的力学性能导致它们在室温下的离子电导率较低,并且在高温下不能有效地抑制锂枝晶生长.为改善上述问题,本文设计并合成了一种新型的珊瑚状Li_(6.25)Al_(0.25)La_(3)Zr_(2)O_(12)(C-LALZO)活性陶瓷填料来增强PEO聚合物电解质,制备得到的复合固态电解质(PLC)表现出更高的离子电导率和机械强度,保证了锂金属的均匀沉积/剥离.采用PLC的锂对称电池在60℃下循环1500小时不发生短路.组装得到的LiFePO_(4)/PLC/Li全固态电池在60和50℃时均有出色的循环稳定性.这项工作表明,通过调节填料的微观结构(如C-LALZO结构),可以有效地改善复合电解质的电化学性能. 展开更多
关键词 固态电解质 聚合物电解质 全固态电池 复合电解质 离子电导率 储能设备 聚环氧乙烷 电化学性能
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Influence of sedimentation and diagenesis on reservoir physical properties:a case study of the Funing Formation,Subei Basin,eastern China
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作者 Jinkai WANG Yuxiang FU +4 位作者 Zhaoxun YAN Jialin FU Jun XEE kaikai li Yongfu ZHAO 《Frontiers of Earth Science》 SCIE CSCD 2021年第4期892-908,共17页
The sandstone of the third member of the Funing Formation(E1f3)in the northern slope zone of the Gaoyou Sag has the typical characteristics of high porosity and ultralow permeability,which makes it difficult for oil t... The sandstone of the third member of the Funing Formation(E1f3)in the northern slope zone of the Gaoyou Sag has the typical characteristics of high porosity and ultralow permeability,which makes it difficult for oil to flow.In this study,the lithological characteristics,sedimentary facies,diagenetic characteristics,pore struc-ture,and seepage ability of this sandstone are characterized in detail.Correlation analysis is used to reveal the reason for the sandstone high porosity-low permeability phenom-enon in the study area.The results indicate that this phenomenon is controlled mainly by the following three factors:1)the sedimentary environment is the initial affecting factor,whereby the deposition of a large number of fine-grained materials reduces the primary pores of sandstone.2)The Funing Formation has undergone strong compaction and cementation,which have led to the removal of most of the primary pores and a reduction in size of the throat channels.3)Owing to fluid activity during the later stage of diagenesis,sandstone underwent intense dissolution and a large number of particles(feldspar and lithic debris)formed many dissolution pores(accounting for nearly 60%of the total pore space).Among these factors,dissolution has contributed the most to the development of high porosity-low permeability phenomenon.This is mainly attributed to the inhomogeneous dissolution process,whereby the degree of particle dissolution(e.g.feldspar)exceeds that of cementing minerals(clay and carbonate minerals).The secondary dissolution pores have increased the porosity of sandstone in the study area;however,the pore connectivity(permeability)has not been significantly improved,thus resulting in the special high porosity-low permeability characteristics of this sandstone. 展开更多
关键词 Gaoyou Depression constant-rate mercury injection porosity anomaly DIAGENESIS sedimentary microfacies
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1.54 μm photoluminescence enhancenment of Er^(3+) -doped ZnO films containing nc-Ge: joint effect from Er^(3+) local environment changing and energy transfer of nc-Ge
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作者 RANRAN FAN FEI LU kaikai li 《Photonics Research》 SCIE EI 2017年第6期86-89,共4页
ZnO films containing Er and Ge nanocrystals(nc-Ge) were synthesized and their photoluminescence(PL) properties were studied. Visible and near-infrared PL intensities are found to be greatly increased in nc-Ge-containi... ZnO films containing Er and Ge nanocrystals(nc-Ge) were synthesized and their photoluminescence(PL) properties were studied. Visible and near-infrared PL intensities are found to be greatly increased in nc-Ge-containing film. Er-related 1.54 μm emission has been investigated under several excitation conditions upon different kinds of Ge, Er codoped ZnO thin films. 1.54 μm PL enhancement accompanied by the appearance of nc-Ge implies a significant correlation between nc-Ge and PL emission of Er^(3+). The increased intensity of 1.54 μm in Ge:Er:ZnO film is considered to come from the joint effect of the local potential distortion around Er^(3+)and the possibleenergy transfer from nc-Ge to Er^(3+). 展开更多
关键词 local environment changing and energy transfer of nc-Ge ZNO
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Exfoliation of bulk 2H-MoS_(2)into bilayer 1T-phase nanosheets via ether-induced superlattices
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作者 Xiuling Shi Dongmei lin +9 位作者 Zhuorui Xiao Yibo Weng Hanxiang Zhou Xiaoying Long Zhiyu Ding Fuyuan liang Yan Huang Guohua Chen kaikai li Tong-Yi Zhang 《Nano Research》 SCIE EI 2024年第6期5705-5711,共7页
The exfoliation of bulk 2H-molybdenum disulfide(2H-MoS_(2))into few-layer nanosheets with 1T-phase and controlled layers represents a daunting challenge towards the device applications of MoS_(2).Conventional ion inte... The exfoliation of bulk 2H-molybdenum disulfide(2H-MoS_(2))into few-layer nanosheets with 1T-phase and controlled layers represents a daunting challenge towards the device applications of MoS_(2).Conventional ion intercalation assisted exfoliation needs the use of hazardous n-butyllithium and/or elaborate control of the intercalation potential to avoid the decomposition of the MoS_(2).This work reports a facile strategy by intercalating Li ions electrochemically with ether-based electrolyte into the van der Waals(vdW)channels of MoS_(2),which successfully avoids the decomposition of MoS_(2)at low potentials.The co-intercalation of Li+and the ether solvent into MoS_(2)makes a first-order phase transformation,forming a superlattice phase,which preserves the layered structure and hence enables the exfoliation of bulk 2H-MoS_(2)into bilayer nanosheets with 1T-phase.Compared with the pristine 2H-MoS_(2),the bilayer 1T-MoS_(2)nanosheets exhibit better electrocatalytic performance for the hydrogen evolution reaction(HER).This facile method should be easily extended to the exfoliation of various transition metal dichalcogenides(TMDs). 展开更多
关键词 exfoliation of MoS_(2) phase transformations superlattices ether electrolyte hydrogen evolution reaction(HER)
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