In order to obtain highly conductive polymer gel electrolytes for electrochemical devices, Poly (vinylidene fluoride) (PVdF) based gel electrolytes namely (100–x)PVdF + xNH4SCN electrolyte system has been synthesized...In order to obtain highly conductive polymer gel electrolytes for electrochemical devices, Poly (vinylidene fluoride) (PVdF) based gel electrolytes namely (100–x)PVdF + xNH4SCN electrolyte system has been synthesized by solution cast technique and characterized by XRD, DSC, IR, SEM and electrical measurements. IR study of gel electrolytes shows interaction of PVdF matrix and dopant salt with prominence of α-phase. This result is also well supported by XRD and DSC studies. The electrolytes are electrochemically stable within ± 1.5 V. The optimum bulk electrical conductivity for 90PVdF + 10NH4SCN electrolyte has been found to be ~ 2.5 × 10–2 S●cm–1. Dielectric relaxation behavior shows low frequency dispersion and αc-related relaxation peak is observed in loss spectra. Polarization behavior of gel electrolyte shows ionic nature of charge transport (Tion. > 0.90). The temperature dependent conductivity shows VTF behavior.展开更多
To develop the green polymeric membrane electrolyte,-Polycaprolactone(PCL)was used as a host and the Ionic liquid(IL)(1-Ethyl-3-methylimidazolium tosylate)as a dopant.The IL is a source of mobile charges in the polyme...To develop the green polymeric membrane electrolyte,-Polycaprolactone(PCL)was used as a host and the Ionic liquid(IL)(1-Ethyl-3-methylimidazolium tosylate)as a dopant.The IL is a source of mobile charges in the polymer electrolyte system.The composite membrane has been prepared by Hot Press method and then we characterised this membrane for ionic transportation.Formation of nanocomposite system has been ascertained from their XRD pattern.Interaction phenomenon was studied by ATR based FTIR and Laser Raman spectroscopic technique.Variation of conductivity with composition and temperature was studied with the aid of impedance spectroscopy data.展开更多
文摘In order to obtain highly conductive polymer gel electrolytes for electrochemical devices, Poly (vinylidene fluoride) (PVdF) based gel electrolytes namely (100–x)PVdF + xNH4SCN electrolyte system has been synthesized by solution cast technique and characterized by XRD, DSC, IR, SEM and electrical measurements. IR study of gel electrolytes shows interaction of PVdF matrix and dopant salt with prominence of α-phase. This result is also well supported by XRD and DSC studies. The electrolytes are electrochemically stable within ± 1.5 V. The optimum bulk electrical conductivity for 90PVdF + 10NH4SCN electrolyte has been found to be ~ 2.5 × 10–2 S●cm–1. Dielectric relaxation behavior shows low frequency dispersion and αc-related relaxation peak is observed in loss spectra. Polarization behavior of gel electrolyte shows ionic nature of charge transport (Tion. > 0.90). The temperature dependent conductivity shows VTF behavior.
文摘To develop the green polymeric membrane electrolyte,-Polycaprolactone(PCL)was used as a host and the Ionic liquid(IL)(1-Ethyl-3-methylimidazolium tosylate)as a dopant.The IL is a source of mobile charges in the polymer electrolyte system.The composite membrane has been prepared by Hot Press method and then we characterised this membrane for ionic transportation.Formation of nanocomposite system has been ascertained from their XRD pattern.Interaction phenomenon was studied by ATR based FTIR and Laser Raman spectroscopic technique.Variation of conductivity with composition and temperature was studied with the aid of impedance spectroscopy data.
