We propose the meshfree-based physics-informed neural networks for solving the unsteady Oseen equations.Firstly,based on the ideas of meshfree and small sample learning,we only randomly select a small number of spatio...We propose the meshfree-based physics-informed neural networks for solving the unsteady Oseen equations.Firstly,based on the ideas of meshfree and small sample learning,we only randomly select a small number of spatiotemporal points to train the neural network instead of forming a mesh.Specifically,we optimize the neural network by minimizing the loss function to satisfy the differential operators,initial condition and boundary condition.Then,we prove the convergence of the loss function and the convergence of the neural network.In addition,the feasibility and effectiveness of the method are verified by the results of numerical experiments,and the theoretical derivation is verified by the relative error between the neural network solution and the analytical solution.展开更多
A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction c...A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction conditions,and excellent functional-group tolerance,allowing the facile synthesis of structurally diverse perfluoroalkylated allenes from readily available fluoroalkyl halides,1,3-enynes and TMscN in a one-pot manner.A reasonable mechanism has been proposed according to a series of control experiments.展开更多
基金Project supported in part by the National Natural Science Foundation of China(Grant No.11771259)Shaanxi Provincial Joint Laboratory of Artificial Intelligence(GrantNo.2022JCSYS05)+1 种基金Innovative Team Project of Shaanxi Provincial Department of Education(Grant No.21JP013)Shaanxi Provincial Social Science Fund Annual Project(Grant No.2022D332)。
文摘We propose the meshfree-based physics-informed neural networks for solving the unsteady Oseen equations.Firstly,based on the ideas of meshfree and small sample learning,we only randomly select a small number of spatiotemporal points to train the neural network instead of forming a mesh.Specifically,we optimize the neural network by minimizing the loss function to satisfy the differential operators,initial condition and boundary condition.Then,we prove the convergence of the loss function and the convergence of the neural network.In addition,the feasibility and effectiveness of the method are verified by the results of numerical experiments,and the theoretical derivation is verified by the relative error between the neural network solution and the analytical solution.
基金supported by the National Natural Science Foundation of China(Nos.22301256 and 22271244)the Hunan Provincial Natural Science Foundation of China(2023JJ40618)+1 种基金the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2022c02)the Hunan Provincial Innovation Foundation for Postgraduate(CX20230644,XDCX2023Y162)
文摘A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction conditions,and excellent functional-group tolerance,allowing the facile synthesis of structurally diverse perfluoroalkylated allenes from readily available fluoroalkyl halides,1,3-enynes and TMscN in a one-pot manner.A reasonable mechanism has been proposed according to a series of control experiments.
