A model to calculate the concentration of organic pollutant in the water column is presented. The inflow, outflow, adsorption of pollutant to the suspended particles and settling of particles, diffusion across the s...A model to calculate the concentration of organic pollutant in the water column is presented. The inflow, outflow, adsorption of pollutant to the suspended particles and settling of particles, diffusion across the sediment water interface, and volatilization to the atmosphere were considered in this model. Dynamic simulation experiment of pentachlorophenol(PCP) has been made in the laboratory. The model parameters were also estimated with experimental data(diffusion mass transfer coefficient, 0.00112m/d; net settling velocity of particles, 0.323 m.d -1 ; volatilization rate constant, 1.94×10 -4 d -1 ). There are little differences between calculated values and measured values. Adsorption of pollutant to the particles and settling of particles are very important mechanisms for removal of organic pollutant from the water. The principles and methods of this model are also applicable to the prediction of the concentration of other trace elements and organic constituents in aquatic systems.展开更多
The hydrolysis kinetics of atrazine in distilled water and leaching water from soil, and they influence factors were studied by incubation at 35degreesC and HPLC analysis method. The kinetic process of atrazine hydrol...The hydrolysis kinetics of atrazine in distilled water and leaching water from soil, and they influence factors were studied by incubation at 35degreesC and HPLC analysis method. The kinetic process of atrazine hydrolysis can be described by the first-order reaction law. The results showed that the hydrolysis rate constants k in leaching water and distilled water were 1.606 x 10(-3)/d and 1.055 x 10(-3)/d, respectively; the half-life of atrazine hydrolysis in distilled water at pH 3, pH 4.5 and pH 8 were 373 days, 522 days and 657 days respectively. The results also showed that the proton in reaction solution can catalyze the atrazine hydrolysis; humic acid and NH4+ etc. substances in aqueous solution can facilitate atrazine hydrolysis; rate constants of atrazine hydrolysis with humic acid and NH4NO3 were 2.431 X 10(-3)/d and 1.498 X 10(-3)/d respectively which were 2.3 and 1.42 times of control(1.055 X 10(-3)/d); anion NO3- can inhibit catalysis of humic acid to atrazine hydrolysis.展开更多
文摘A model to calculate the concentration of organic pollutant in the water column is presented. The inflow, outflow, adsorption of pollutant to the suspended particles and settling of particles, diffusion across the sediment water interface, and volatilization to the atmosphere were considered in this model. Dynamic simulation experiment of pentachlorophenol(PCP) has been made in the laboratory. The model parameters were also estimated with experimental data(diffusion mass transfer coefficient, 0.00112m/d; net settling velocity of particles, 0.323 m.d -1 ; volatilization rate constant, 1.94×10 -4 d -1 ). There are little differences between calculated values and measured values. Adsorption of pollutant to the particles and settling of particles are very important mechanisms for removal of organic pollutant from the water. The principles and methods of this model are also applicable to the prediction of the concentration of other trace elements and organic constituents in aquatic systems.
基金the National Natural Science Foundation of China(No.29777026)the Major Project Foundation of the Chinese Academy of Sciences(KZ951-B1-209-01)
文摘The hydrolysis kinetics of atrazine in distilled water and leaching water from soil, and they influence factors were studied by incubation at 35degreesC and HPLC analysis method. The kinetic process of atrazine hydrolysis can be described by the first-order reaction law. The results showed that the hydrolysis rate constants k in leaching water and distilled water were 1.606 x 10(-3)/d and 1.055 x 10(-3)/d, respectively; the half-life of atrazine hydrolysis in distilled water at pH 3, pH 4.5 and pH 8 were 373 days, 522 days and 657 days respectively. The results also showed that the proton in reaction solution can catalyze the atrazine hydrolysis; humic acid and NH4+ etc. substances in aqueous solution can facilitate atrazine hydrolysis; rate constants of atrazine hydrolysis with humic acid and NH4NO3 were 2.431 X 10(-3)/d and 1.498 X 10(-3)/d respectively which were 2.3 and 1.42 times of control(1.055 X 10(-3)/d); anion NO3- can inhibit catalysis of humic acid to atrazine hydrolysis.
